High-resolution ion-microprobe measurement of lead isotopes: Variations within single zircons from Lac Seul,northwestern Ontario

Selected-area measurements of lead-isotope ratios in zircons have been made at high mass resolution using a modified A.E.I. IM20 ion-microprobe. At a working resolution of 3200 it is shown that the important interfering molecular peaks generated from the zircon matrix may be separated from atomic lead peaks. Corrections for overlapping peaks, which are necessary in measurements of lead isotopes at low mass resolution, are then only required for ²⁰⁸Pb.Measurements on N.B.S. standards show no isotope discrimination within counting statistics. Determination of ²⁰⁷Pb/²⁰⁶Pb on 29 single zircon grains from a tonalite gneiss and a granite from Lac Seul, northwestern Ontario, give very variable ratios with mean values close to those of bulk separates. Peaks in the distribution of 207/206 ratios obtained from the tonalite gneiss may be interpreted as evidence for two stages of lead loss. High 207/206 ratios are shown to be significant for at least two zircons and probably record a minimum age of formation of 3.3 ± 0.1 b.y. for the gneiss.     

Surface temperature differences between minerals in crystalline rocks: Implications for granular disaggregation of granites through thermal fatigue

Thermal expansion differences between minerals within rocks under insolation have previously been assumed to drive breakdown by means of granular disaggregation. However, there have been no definitive demonstrations of the efficacy of this weathering mechanism. Different surface temperatures between minerals should magnify thermal expansion differences, and thus subject adjacent minerals to repeated stresses that might cause breakdown through fatigue failure. This work confirms the existence of surface temperature differences between minerals in granitic rocks under simulated short-term temperature fluctuations so as to discriminate their potential for initiating granular disaggregation. The influence of colour, as a surrogate for albedo, and crystal size, as a function of thermal mass are specifically identified because of their ease of quantification. Four rock types with a range of these properties were examined, and subjected to repeated short-term temperature cycles by radiative heating and cooling under laboratory conditions. Results show that while albedo is the main control for overall and individual maximum temperatures, crystal size is the main factor controlling higher temperature differences between minerals. Thus, stones with large differences of mineral sizes can undergo magnified stresses due to thermal expansion differences.     

Growth, ionic and osmotic relations of an Allenrolfea occidentalis population in an inland salt playa of the Great Basin Desert

Variation in growth, physiology and ionic relations patterns of Allenrolfea occidentalis, a perennial halophyte of dry habitats, was studied under field conditions from May 1996 to November 1997. An A. occidentalis community has a characteristic soil pH of 7·3–8·3. During the two years, the population was exposed to great variations in soil salinity, from 29 to 146 dS m⁻¹, and soil moisture, ranging from drought (9·2%) to wet (19%). The salt concentrations were significantly higher in the surface soil layers than in the subsurface layers. Seasonal changes in dry weight are directly related to soil salinity stress. Allenrolfea occidentalis had greater growth and biomass production under saline conditions. Na⁺and Cl⁻ions were accumulated in plant tissues in much greater amounts than K⁺, Ca²⁺, and Mg²⁺. Soil salinities were significantly reduced at the end of the growing season. Water potentials of the shoots decreased significantly with increasing salinity. The plant (F_v/F_mratio) was more affected by salinity and irradiation levels during the summer period.     

RHESSI Microflares: II. Implications for Loop Structure and Evolution

We present simple analytic models which predict the peak X-ray emission measure and temperature attained in flares in which the chromospheric evaporation process takes place either in a single ‘monolithic’ loop or in a loop consisting of several filaments that are created successively as the energy release process proceeds in time. As possible mechanisms driving chromospheric evaporation we consider both classical heat conduction from the loop top and non-thermal electron beams. The model predictions are tested for a set of 18 well studied RHESSI microflares. The results suggest beam driven evaporation in filamented loops as being capable of accounting for the observed emission measures and temperatures though there are issues with the very high beam densities needed. On the other hand, estimates of the emission measures achieved by conductive evaporation which are derived by using the Rosner – Tucker – Vaiana (RTV) scaling law are much larger than the observed ones. Possible reasons for this discrepancy are discussed.     

Impact of Gas Adsorption Induced Coal Matrix Damage on the Evolution of Coal Permeability

It has been widely reported that coal permeability can change from reduction to enhancement due to gas adsorption even under the constant effective stress condition, which is apparently inconsistent with the classic theoretical solutions. This study addresses this inconsistency through explicit simulations of the dynamic interactions between coal matrix swelling/shrinking induced damage and fracture aperture alteration, and translations of these interactions to permeability evolution under the constant effective stress condition. We develop a coupled coal–gas interaction model that incorporates the material heterogeneity and damage evolution of coal, which allows us to couple the progressive development of damage zone with gas adsorption processes within the coal matrix. For the case of constant effective stress, coal permeability changes from reduction to enhancement while the damage zone within the coal matrix develops from the fracture wall to further inside the matrix. As the peak Langmuir strain is approached, the decrease of permeability halts and permeability increases with pressure. The transition of permeability reduction to permeability enhancement during gas adsorption, which may be closely related to the damage zone development in coal matrix, is controlled by coal heterogeneity, external boundary condition, and adsorption-induced swelling.     

Record of Late Pleistocene Glaciation and Deglaciation in the Southern Cascade Range. I. Petrological Evidence from Lacustrine Sediment in Upper Klamath Lake, Southern Oregon

Petrological and textural properties of lacustrine sediments from Upper Klamath Lake, Oregon, reflect changing input volumes of glacial flour and thus reveal a detailed glacial history for the southern Cascade Range between about 37 and 15 ka. Magnetic properties vary as a result of mixing different amounts of the highly magnetic, glacially generated detritus with less magnetic, more weathered detritus derived from unglaciated parts of the large catchment. Evidence that the magnetic properties record glacial flour input is based mainly on the strong correlation between bulk sediment particle size and parameters that measure the magnetite content and magnetic mineral freshness. High magnetization corresponds to relatively fine particle size and lower magnetization to coarser particle size. This relation is not found in the Buck Lake core in a nearby, unglaciated catchment. Angular silt-sized volcanic rock fragments containing unaltered magnetite dominate the magnetic fraction in the late Pleistocene sediments but are absent in younger, low magnetization sediments. The finer grained, highly magnetic sediments contain high proportions of planktic diatoms indicative of cold, oligotrophic limnic conditions. Sediment with lower magnetite content contains populations of diatoms indicative of warmer, eutrophic limnic conditions. During the latter part of oxygen isotope stage 3 (about 37–25 ka), the magnetic properties record millennial-scale variations in glacial-flour content. The input of glacial flour was uniformly high during the Last Glacial Maximum, between about 21 and 16 ka. At about 16 ka, magnetite input, both absolute and relative to hematite, decreased abruptly, reflecting a rapid decline in glacially derived detritus. The decrease in magnetite transport into the lake preceded declines in pollen from both grass and sagebrush. A more gradual decrease in heavy mineral content over this interval records sediment starvation with the growth of marshes at the margins of the lake and dilution of detrital material by biogenic silica and other organic matter.     

Simulating the moderating effect of a lake on downwind temperatures

A steady-state, two-dimensional numerical model is used to simulate air temperatures and humidity downwind of a lake at night. Thermal effects of the lake were modelled for the case of moderate and low surface winds under the cold-air advective conditions that occur following the passage of a cold front. Surface temperatures were found to be in good agreement with observations. A comparison of model results with thermal imagery indicated the model successfully predicts the downwind distance for which thermal effects due to the lake are significant.     

The measurement and extraction of the <nu>6 atmospheric emission band of CFC-12 from interfering emission features

Ground-based thermal emission measurements of the zenith sky have been made at Peterborough, Ontario since January 1993. In this paper, the measurement of the ₆ band of atmospheric CFC-12, an important greenhouse gas, is presented for a cold, clear day in January 1994. A spectrum of the non-CFC-12 emission features has been simulated using the FASCD3P radiation code and measured radiosonde profiles of temperature, pressure and humidity. This has enabled a satisfactory subtraction of the interfering emission features from the CFC-12 emission spectrum. A comparison of the observed and simulated ₆-bands of CFC-12 shows good agreement at all frequencies of emission. From these spectra the total downward greenhouse radiative flux from the CFC-12 ₆ emission based for a very cold day has been estimated to be 0.27 W m⁻²±10%.