Dolomite-rock textures and secondary porosity development in Ellenburger Group carbonates (Lower Ordovician), west Texas and southeastern New Mexico

Pervasive early- to late-stage dolomitization of Lower Ordovician Ellenburger Group carbonates in the deep Permian Basin of west Texas and southeastern New Mexico is recorded in core samples having present-day burial depths of 1.5–7.0 km. Seven dolomite-rock textures are recognized and classified according to crystal-size distribution and crystal-boundary shape. Unimodal and polymodal planar-s (subhedral) mosaic dolomite is the most widespread type, and it replaced allochems and matrix or occurs as void-filling cement. Planar-e (euhedral) dolomite crystals line pore spaces and/or fractures, or form mosaics of medium to coarse euhedral crystals. This kind of occurrence relates to significant intercrystalline porosity. Non-planar-a (anhedral) dolomite replaced a precursor limestone/dolostone only in zones that are characterized by original high porosity and permeability. Non-planar dolomite cement (saddle dolomite) is the latest generation and is responsible for occlusion of fractures and pore space. Dolomitization is closely associated with the development of secondary porosity; dolomitization pre-and post-dates dissolution and corrosion and no secondary porosity generation is present in the associated limestones. The most common porosity types are non-fabric selective moldic and vuggy porosity and intercrystalline porosity. Up to 12% effective porosity is recorded in the deep (6477 m) Delaware basin. These porous zones are characterized by late-diagenetic coarse-crystalline dolomite, whereas the non-porous intervals are composed of dense mosaics of early-diagenetic dolomites. The distribution of dolomite rock textures indicates that porous zones were preserved as limestone until late in the diagenetic history, and were then subjected to late-stage dolomitization in a deep burial environment, resulting in coarse-crystalline porous dolomites. In addition to karst horizons at the top of the Ellenburger Group, exploration for Ellenburger Group reservoirs should consider the presence of such porous zones within other Ellenburger Group dolomites.     

CLASSIFICATION:OLDTIMERS AND NEWCOMERS

Classification and regression techniques are among the most used tools by chemometricians.Withclassification,the two classic methods are discriminant analysis and SIMCA.In this paper we discuss theconnection between these two methods and introduce two new ones of the same family:DASCO(discriminantanalysis with shrunken covariances)and RDA(regularized discriminant analysis).We demonstrate on bothsimulated and real data sets that their performance is superior to the old favorites.This is especially truein small-sample/high-dimension settings typical in chemistry.     

RACE,IMMIGRANTS, AND RESIDENCE: A NEW RACIAL GEOGRAPHY OF WASHINGTON,D.C.*

ABSTRACT. This study examines the residential patterns of immigrant newcomers within a relatively new immigrant destination, Washington, D.C. Particular attention is given to how these patterns are shaped by the newcomers' race and ethnicity. Our analysis is based primarily upon data on immigrant flows from the U.S. Immigration and Naturalization Service for the 1990–1998 period. Evidence from our study suggests a racial and ethnic hierarchy to the residential location of Africans, Asians, Europeans, and Latin Americans, providing some support for the pattern expected in the place‐stratification model. When their residential patterns are compared with those of non‐Hispanic blacks, we find that African newcomers are more likely to settle among blacks than are other regional‐origin groups. However, Africans are also found to reside in multiethnic zip codes where large numbers of newcomers are concentrated. The findings suggest that race is an important but not exclusive factor in explaining the residential choices of recent immigrants.     

Incorporation of uranium in modern corals

Uranium occurs in corals at three sites: 1, in organic matter; 2, adsorbed on the surfaces of skeletal aragonite; and 3, in the aragonite lattice. Organic matter incorporates from sea water by chelation 40–70 ppm uranium; skeletal aragonite incorporates only 3 ppm. However, as the organic fraction is low (0·1%), its high concentration of uranium does not significantly affect the total concentration of uranium in the coral. A negligible concentration of uranium, 40–60 ppb, is adsorbed on skeletal aragonite from which it is readily leached or exchanged. This low concentration of adsorbed uranium (<2% of the total uranium in skeletal aragonite) is related to the very small specific surface area (1·5–1·8 m²/g of the corals.     

Two New Carbonate Stable-Isotope Standards

Two new carbonate isotope standards have been prepared for distribution by the IAEA and NBS. The first, TS limestone, NBS #19, will substitute for PDB, while the second carbonate, NBS #18 is depleted in ¹⁸O and ¹³C compared to the first.     

Depositional environments of Upper Miocene (Messinian) evaporites of Sicily as determined from analysis of intercalated carbonates

Various workers have suggested that the Upper Miocene (Messinian) evaporites of the Sicilian Basin formed in a topographic basin of considerable relief, filled with hypersaline water. Our studies indicate that this basin contained shallow water, at least during the deposition of the carbonate rocks intercalated between the gypsum beds. We recognize four basic kinds of limestone: (1) pelletal and pisolitic limestone; (2) skeletal limestone; (3) oöitic limestone, and (4) laminated lime-stone-dolostone. Modern analogs suggest that three of these four kinds of carbonate must have formed close to or above sea level. The evidence supporting this contention includes pellets with algal coatings, pisolites, quiet-water oöids, and algal laminates. Therefore we suggest that the evaporites associated with these carbonates may likewise have formed in relatively shallow water. An alternative conclusion would be that the level of the sea, and the salinity, underwent irregular patterns of profound change.