Chemical alteration of tephra in the depositional environment: theoretical stability modelling

The study of the chemical stability of vitreous material in aqueous media is well‐established. There has to date been little consideration of the implications of variations in the chemical durability of tephra in Quaternary tephrochronology. Chemical alteration can take the form of cationic leaching from the matrix, or complete destruction of the silica network, either of which could constrain the ability to chemically identify distal tephra. Here we apply established models of vitreous durability to the published chemical analyses of a large number of Icelandic tephras in order to predict their relative durabilities under equivalent conditions. This suggests that some important tephras have relatively poor chemical stability, and that rhyolitic tephras are, in general, more stable than basaltic. We conclude that tephras should be expected to show predictable differential chemical stability in the post‐depositional environment. Copyright © 2003 John Wiley & Sons, Ltd.     

A multi‐level parallelized substructuring‐frontal solution for coupled thermo/hydro/mechanical problems in unsaturated soil

This paper proposes a multi‐level parallelized substructuring–frontal combined algorithm for the analysis of the problem of thermo/hydraulic/mechanical behaviour of unsaturated soil. Temperature, displacement, pore water pressure and pore air pressure are treated as the primary variables in a non‐linear analysis. Details are given firstly of the substructuring–frontal combined approach. The incorporation of the algorithm in a multi‐level parallel strategy is then discussed. The parallel processing can thus be carried out at different substructural levels. The method thus developed impacts, in a positive way, on both computer storage requirement and execution time. Copyright © 2003 John Wiley & Sons, Ltd.     

Multistep matched-field inversion for broad-band data from ASIAEX2001

This paper discusses the results of geoacoustic inversion carried out using explosive charge data from the Asian Seas International Acoustic Experiment (ASIAEX) East China Sea (ECS) Experiment. A multifrequency incoherent matched-field inversion processor and a genetic algorithm (GA) are used for the inversion. A multistep matched field inversion approach is presented, which makes use of the varying sensitivities of wave fields at various frequencies to reduce the inversion problem into a sequence of smaller inversions with fewer unknowns to estimate at each stage. Different parameters are estimated using data at different frequencies according to their sensitivities. Inversion results for different areas in the ECS region are summarized and compared with core data.     

Ocean-floor hydrothermal metamorphism in the Limousin ophiolites (western French Massif Central): evidence of a rare preserved Variscan oceanic marker

The Limousin ophiolite is located at the suture zone between two major thrust sheets in the western French Massif Central. This ophiolitic section comprises mantle‐harzburgite, mantle‐dunite, wehrlites, troctolites and layered gabbros. It has recorded a static metamorphic event transforming the gabbros into undeformed amphibolites and the magmatic ultramafites into serpentinites and/or pargasite‐bearing chloritites. With various thermobarometric methods, it is possible to show that the different varieties of amphibole have registered low‐P (c. 0.2 GPa) conditions with temperature ranging from high‐T, late‐magmatic conditions to greenschist–zeolite metamorphic facies. The abundance of undeformed metamorphic rocks (which is typical of the lower oceanic crust), the occurrence of Ca–Al (–Mg) metasomatism illustrated by the growth of Ca–Al silicates in veins or replacing the primary magmatic minerals, the P–T conditions of the metamorphism and the numerous similarities with oceanic crustal rocks from Ocean Drilling Program and worldwide ophiolites are the main arguments for an ocean‐floor hydrothermal metamorphism in the vicinity of a palaeo‐ridge. Among the West‐European Variscan ophiolites, the Limousin ophiolites constitute an extremely rare occurrence that has not been involved in any HP (subduction‐related) or MP (orogenic) metamorphism as observed in other ophiolite occurrences (i.e. France, Spain and Germany).     

Seasonal variations in prey selection by estuarine black-headed gulls (Larus ridibundus)

The number of black-headed gulls (Larus ridibundus) in the Clyde Estuary is large. In summer the average density has reached 1350 gulls km^?2 and in winter 180 gulls km^?2. This paper compares prey selection and feeding efficiency in gulls during summer and winter on tidal flats, and considers how seasonal differences may be adaptations to cope with seasonal changes in prey availability.Gross and net rates of energy intake were highest in summer because gulls captured more of the polychaete N. diversicolor than the amphipod C. volutator. In winter, gulls selected for C. volutator and therefore an energetically less profitable diet. Throughout the year gulls selected more C. volutator relative to N. diversicolor than expected on energetic grounds and so apparently did not maximize potential net rate of energy intake.Gulls used three techniques to capture prey and made most intensive use of the ‘crouch’ technique. Crouching gulls attained a much higher net rate of energy intake than ‘upright’ or ‘paddling’ gulls.A log-linear model showed that (a) season, water depth and gull density determined feeding technique and (b) feeding technique and season independently determined foraging success and prey selection. Thus gull density and water depth acted on prey selection through imposed variations in feeding technique.Reasons for gulls selecting energetically unprofitable C. volutator and for the use of several distinct feeding techniques are discussed.     

Particulate organic matter in the coastal and estuarine waters of Goa and its relationship with phytoplankton production

In the coastal and estuarine waters of Goa, particulate organic carbon (POC) varied from 0.52 to 2.51 mg l^?1 and from 0.28 to 5.24 mg l^?1 and particulate phosphorus (PP) varied from 0.71 to 5.18 μg l^?1 and from 0.78 to 20.34 μg l^?1, respectively. The mean values of chlorophyll and primary productivity were 1.94 mg m^?3 and 938.1 mg C m^?2 day^?1 in the coastal waters and 4.3 mg m^?3 and 636.5 mg C m^?1 day^?1 in the estuarine waters, respectively.$\text{POC}\text{chl}$ ratios were low in June and October even when POC values were quite high. The POC in surface waters was linearly correlated with the chlorophyll content. Also PP increased when chlorophyll and primary productivity remained high. The results suggest that the phytoplankton was sharply increasing and contributed to POC and PP content. The percentage of detritus calculated from the intercept values of chlorophyll on POC varied from 46 to 76% depending on season. Results indicate that the major portion of POC and PP during postmonsoon (October–January) is derived from phytoplankton production while the allochthonous matter predominate during monsoon (June–September).     

Deep-ocean piezometer probe technology for geotechnical investigations

Two single-sensor piezometer probes, 8 mm in diameter, were developed for deep-ocean geotechnical investigations. These probes were tested in a hyperbaric chamber pressurized to 55 MPa (8000 psi). Testing was performed for a period of five weeks under high hydrostatic pressure with the probes inserted in reconstituted illitic marine sediment. Small differential pore-water pressures were generated in response to both mechanically and thermally generated forcing functions. During deep-ocean simulated pressure tests, the sensors exhibited excellent sensitivity and stability. These developments in piezometer-probe technology provide a quantitative means of assessing important geotechnical parameters of fine-grained seabed deposits.     

A one-dimensional model for the interaction between continental-scale ice sheets and atmospheric stationary waves

 The great continental ice sheets of the Pleistocene represented a significant topographic obstacle to the westerly winds in northern midlatitudes. This work explores how consequent changes in the atmospheric stationary wave pattern might have affected the shape and growth of the ice sheets themselves. A one dimensional (1-D) model is developed which permits an examination of the types and magnitudes of the feedbacks that might be expected. When plausible temperature perturbations are introduced at the ice-sheet margin which are proportional to the stationary wave amplitude, the equilibrium shape of the ice sheet is significantly altered, and depends on the sign of the perturbation. The proposed feedback also affects the response of the ice sheet to time-varying climate forcing. The results suggest that the evolution of a continental-scale ice sheet with a land-based margin may be significantly determined by the changes it induces in the atmospheric circulation. Received: 1 October 1999 / Accepted: 17 July 2000