High-pressure transformations of ilmenite to perovskite, and lithium niobate to perovskite in zinc germanate

In-situ X-ray powder diffraction measurements conducted under high pressure confirmed the existence of an unquenchable orthorhombic perovskite in ZnGeO₃. ZnGeO₃ ilmenite transformed into perovskite at 30.0 GPa and 1300±150 K in a laser-heated diamond anvil cell. After releasing the pressure, the lithium niobate phase was recovered as a quenched product. The perovskite was also obtained by recompression of the lithium niobate phase at room temperature under a lower pressure than the equilibrium phase boundary of the ilmenite–perovskite transition. Bulk moduli of ilmenite, lithium niobate, and perovskite phases were calculated on the basis of the refined X-ray diffraction data. The structural relations among these phases are considered in terms of the rotation of GeO₆ octahedra. A slight rotation of the octahedra plays an important role for the transition from lithium niobate to perovskite at ambient temperature. On the other hand, high temperature is needed to rearrange GeO₆ octahedra in the ilmenite–perovskite transition. The correlation of quenchability with rotation angle of GeO₆ octahedra for other germanate perovskites is also discussed.     

Observation of shear zone development in ring-shear apparatus with a transparent shear box

Using a new ring-shear apparatus with a transparent shear box and video image analysis system, drained and undrained speed-controlled tests were conducted on coarse-grained silica sands to study the shear-zone formation process in granular materials. Velocity distribution profiles of grains under shear at various stages in the ring shear tests were observed through processing the video image by the Particle Image Velocimetry (PIV) program. Shear-zone thickness and type of shear mode (slide-like or flow-like) during shear were observed. Before reaching peak strength in low-speed and drained condition test, a comparatively major part of the sample in the upper shear box showed a velocity distribution profile of structural deformation and dilatancy behavior. After peak strength, the velocity profile changed into a slide-like mode and thereafter showed almost no change. In higher speed tests with drained and undrained conditions, an almost slide-like mode was observed, compared to low-speed test. Apparent shear-zone thicknesses of high-speed tests are thinner than low-speed tests. Unexpectedly, almost no difference was observed in the shear-zone thickness and mode of shear (slide or flow-like) between drained and undrained tests. This study was conducted as part of the International Programme on Landslides (IPL) M101 “Areal prediction of earthquake and rain induced rapid and long-traveling flow phenomena (APERITIF)” of the International Consortium on Landslides (ICL). These results will contribute to understanding the mechanism of shear-zone development in granular materials as a basic knowledge for disaster risk mitigation of rapid long run-out landslides.     

日本SELENE月球探测计划和卫星间多普勒跟踪的数学模型

日本月球探测计划（SELENE）定于2004年夏季利用HIIa火箭发射一组共3颗绕月人造卫星。他们是主卫星、跟踪中断卫星和空间VLBI电波源。其主要科学目标之一是利用对绕月卫星的多普勒跟踪数据精确测定月球重力场,研究月球的起源与演化。SELENE计划中实现这个科学目标的关键技术是引入中继卫星,目的在于当处于低轨道的主卫星飞行到月球背面地面观测站无法观测时,采用卫星间跟踪方法（SST）,建立地面站与主卫星之间的联系,以得到月球背面重力场的直接测量数据。介绍了几种典型的四程卫星间多普勒跟踪模式和相应的数学模型,并针对SELENE计划中采用的特殊四程多普勒跟踪模式建立了卫星相对观测站速度与跟踪信号多普勒频移之间的转换关系。提出了利用GEODYNⅡ定轨分析软件处理SELENE多普勒跟踪数据的流程。     

The influence of multiple diffraction on the space group determination of orthopyroxene,spodumene, low omphacite and pigeonite

Forbidden reflections of some pyroxenes described as having a lower symmetry than Pbca or C2/c have been examined, mainly using the detailed ψ-scanning method of the four-circle automated diffractometer. All reflections violating the systematic absences of Pbca orthopyroxene, C2/c spodumene, P2/n omphacite and P2₁/c pigeonite were found to be due to the Umweganregung process of multiple diffraction; the Umweganregung peaks observed for the ψ azimuth were indexed in terms of a four-circle geometry. Thus, the space groups of orthopyroxene, α spodumene, low omphacite and low pigeonite were confirmed to be Pbca, C2/c, P2/n and P2₁/c, respectively.     

Geochemical relation between gas hydrates and water venting in the seismic blanking zone on the northern Cascadia continental margin offshore Vancouver Island, Canada

The isotopic composition (δD and δ¹⁸O) and chloride concentration (Cl⁻) of pore waters from the northern Cascadia continental margin offshore Vancouver Island were measured to characterize the relations between the water flow regime and the distribution, formation and dissociation of gas hydrates. The δD values of pore waters in gas hydrate-bearing sediments are slightly higher ( 1‰) than those of seawater as the result of gas hydrate dissociation during core recovery and handling. Within the seismic blanking zone, the δD values were slightly lower (− 1‰) than values measured from sites outside the blanking area (0‰). We attribute these differences to 1) distillation of D-rich water during hydrate formation in the center of the blanking zone and 2) limited migration of pore water between inside and outside of the blanking zone due to different fluid fluxes. In contrast, the δ¹⁸O values and Cl⁻ concentrations do not show significant spatial variation due to decreased isotopic fractionation of oxygen and small fraction of chloride relative to hydrogen isotope during gas hydrate formation. The δD value of pore water, therefore, appears to be a sensitive indicator of gas hydrate occurrence. We estimate that gas hydrate occupied at least 2.0 to 6.3% of sediment pore space using δD distribution in this area.     

Effects of a physical librations of the moon caused by a liquid core,and determination of the fourth mode of a free libration

An analytical theory of lunar physical librations based on its two-layer model consisting of a non-spherical solid mantle and ellipsoidal liquid core is developed. The Moon moves on a high-precision orbit in the gravitational field of the Earth and other celestial bodies. The defined fourth mode of a free libration is caused by the influence of the liquid core, with a long period of 205.7 yr, with amplitude S = 0″0395 and with an initial phase Π₀ = ?134° (for the initial epoch 2000.0). Estimates of dynamic (meridional) oblatenesses of a liquid core of the Moon have been estimated: ?_D = 4.42 × 10^?4, μ_D = 2.83 × 10^?4 (?_D + μ_D = 7.24 × 10^?4). These results have been obtained as a result of comparison of the developed analytical theory of physical librations of the Moon with the empirical theory of librations of the Moon constructed on the basis of laser observations.     

Space weathered rims found on the surfaces of the Itokawa dust particles

On the basis of observations using Cs‐corrected STEM, we identified three types of surface modification probably formed by space weathering on the surfaces of Itokawa particles. They are (1) redeposition rims (2–3 nm), (2) composite rims (30–60 nm), and (3) composite vesicular rims (60–80 nm). These rims are characterized by a combination of three zones. Zone I occupies the outermost part of the surface modification, which contains elements that are not included in the unchanged substrate minerals, suggesting that this zone is composed of sputter deposits and/or impact vapor deposits originating from the surrounding minerals. Redeposition rims are composed only of Zone I and directly attaches to the unchanged minerals (Zone III). Zone I of composite and composite vesicular rims often contains nanophase (Fe,Mg)S. The composite rims and the composite vesicular rims have a two‐layered structure: a combination of Zone I and Zone II, below which Zone III exists. Zone II is the partially amorphized zone. Zone II of ferromagnesian silicates contains abundant nanophase Fe. Radiation‐induced segregation and in situ reduction are the most plausible mechanisms to form nanophase Fe in Zone II. Their lattice fringes indicate that they contain metallic iron, which probably causes the reddening of the reflectance spectra of Itokawa. Zone II of the composite vesicular rims contains vesicles. The vesicles in Zone II were probably formed by segregation of solar wind He implanted in this zone. The textures strongly suggest that solar wind irradiation damage and implantation are the major causes of surface modification and space weathering on Itokawa.     

Comparison of carbon cycle between the western Pacific subarctic and subtropical time-series stations: highlights of the K2S1 project

A comparative study of ecosystems and biogeochemistry at time-series stations in the subarctic gyre (K2) and subtropical region (S1) of the western North Pacific Ocean (K2S1 project) was conducted between 2010 and 2013 to collect essential data about the ecosystem and biological pump in each area and to provide a baseline of information for predicting changes in biologically mediated material cycles in the future. From seasonal chemical and biological observations, general oceanographic settings were verified and annual carbon budgets at both stations were determined. Annual mean of phytoplankton biomass and primary productivity at the oligotrophic station S1 were comparable to that at the eutrophic station K2. Based on chemical/physical observations and numerical simulations, the likely “missing nutrient source” was suggested to include regeneration, meso-scale eddy driven upwelling, meteorological events, and eolian inputs in addition to winter vertical mixing. Time-series observation of carbonate chemistry revealed that ocean acidification (OA) was ongoing at both stations, and that the rate of OA was faster at S1 than at K2 although OA at K2 is more critical for calcifying organisms.