A geochemical investigation of hydrologically derived threats to rare biota: the Drummond Nature Reserve, Western Australia

The Drummond Nature Reserve (DNR), a high-value conservation area 100?km northeast of Perth, Western Australia, contains two rare freshwater claypans and a diverse range of rare and threatened vascular plants. Groundwater/surface-water interactions were investigated via isotopic (??¹⁸O and ??D) and major ion analysis. The groundwater chemical and isotope analyses combined with nutrient data allowed for the assessment of potential hydrologically derived threats to the claypans and their associated conservation values. Groundwater composition is typically Na?CCl to Na?CMg?CCl; whereas the claypan??s ephemeral fresh surface water is Na?CCl?CHCO₃. Distinct ??¹⁸O and ??D isotopic signatures for the claypan surface waters and adjoining groundwaters indicate that there currently is minimal connection between these two hydrological systems. Hence the current threat to the freshwater claypans and associated biota from rising saline and acidic groundwater is minimal. Elevated nutrient (N) levels identified in groundwaters along the reserve??s western boundary may be linked to fertiliser regimes employed in adjoining agricultural lands. The ecosystem associated with the southwest claypan is particularly vulnerable to N and P inputs via surface-water flows, which could cause algal blooms, vegetation degradation and weed infestation.     

Reproduction of secondary data in projection pursuit transformation

A challenge when working with multivariate data in a geostatistical context is that the data are rarely Gaussian. Multivariate distributions may include nonlinear features, clustering, long tails, functional boundaries, spikes, and heteroskedasticity. Multivariate transformations account for such features so that they are reproduced in geostatistical models. Projection pursuit as developed for high dimensional data exploration can also be used to transform a multivariate distribution into a multivariate Gaussian distribution with an identity covariance matrix. Its application within a geostatistical modeling context is called the projection pursuit multivariate transform (PPMT). An approach to incorporate exhaustive secondary variables in the PPMT is introduced. With this approach the PPMT can incorporate any number of secondary variables with any number of primary variables. A necessary alteration to the approach to make this numerically practical was the implementation of a continuous probability estimator that relies on Bernstein polynomials for the transformation that takes place in the projections. Stopping criteria were updated to incorporate a bootstrap t test that compares data sampled from a multivariate Gaussian distribution with the data undergoing transformation.     

Effect of seasonal flushing on nutrient export characteristics of an urbanizing,remote, ungauged coastal catchment

Urbanization is a primary driver of nutrient export in coastal catchments; however, estimating the rate of export from urbanizing, remote and ungauged communities with episodic rainfall characteristics has rarely been reported in tropical and subtropical areas. In this study, the coastal catchment of Roebuck Bay near Broome, northwestern Australia, was instrumented to elucidate the effect of seasonal flushing on nutrient export. A cost-effective framework involving temporary gauging and community participation led to a quantitative estimate of surface hydrology and nutrient dynamics from this urbanizing, remote and ungauged catchment. The contribution of nutrient export was larger from the older Broome town site sub-catchments compared to sub-catchments that have been progressively urbanized since 2000. A distinctive seasonal first flush phenomenon, with an initial 30% of runoff volume containing 40–70% of the nutrient load was a key feature. This indicates there are opportunities for storm-water management to minimize impacts through adopting water-sensitive urban design principles.     

Flow Characteristics of Cemented Paste Backfill

Cemented paste backfill (CPB) is primarily used for backfilling underground voids at George Fisher Mine (Mount Isa, Australia). The objective of this paper is to summarise the geotechnical characterisation of the tailings and the rheological properties of the CPB as determined from a laboratory testing program undertaken at James Cook University. Two binders were examined [a General Purpose cement and a slag blend cement] over a range of dosages from 0 to 6% and CPB mix solids content in the range of 72–78%. The slump tests were carried out using the standard cone (ASTM C 143) used for concrete and a cylinder with 110 mm (diameter) × 110 mm (height), whereas the yield stress was measured using a shear vane (Brookfield vane spindle V-73). The index characteristics of the tailings including the grain size distribution, liquid limit, plastic limit, specific gravity were determined as per ASTM standards. This paper will then discuss the interrelationships among the solid content, slump, saturated density and the yield stress of the CPB. It is shown that there is strong correlation between the two different slump test devices used in this study. The smaller cylindrical device appears to have good potential for slurries like mine tailings or dredged mud that have high water content for slump test. There is also strong inter-relationship among solid content, slump, yield stress, and bulk density. Increasing the solid content increases the bulk density and yield stress, but reduces the slump. While there is hardly any difference between the two binder types used in this study in terms of flow parameters, namely the yield stress and slump, the binder dosage has an effect. At any specific solid content, higher binder dosages lead to a drop in the slump and increase in the yield stress. The difference is more pronounced in dense slurries. It is also strongly believed that the trends and relationships developed in this study may be valuable for the other mining operations using CPB.     

Estimating the settling velocity of bioclastic sediment using common grain‐size analysis techniques

Most techniques for estimating settling velocities of natural particles have been developed for siliciclastic sediments. Therefore, to understand how these techniques apply to bioclastic environments, measured settling velocities of bioclastic sedimentary deposits sampled from a nearshore fringing reef in Western Australia were compared with settling velocities calculated using results from several common grain‐size analysis techniques (sieve, laser diffraction and image analysis) and established models. The effects of sediment density and shape were also examined using a range of density values and three different models of settling velocity. Sediment density was found to have a significant effect on calculated settling velocity, causing a range in normalized root‐mean‐square error of up to 28%, depending upon settling velocity model and grain‐size method. Accounting for particle shape reduced errors in predicted settling velocity by 3% to 6% and removed any velocity‐dependent bias, which is particularly important for the fastest settling fractions. When shape was accounted for and measured density was used, normalized root‐mean‐square errors were 4%, 10% and 18% for laser diffraction, sieve and image analysis, respectively. The results of this study show that established models of settling velocity that account for particle shape can be used to estimate settling velocity of irregularly shaped, sand‐sized bioclastic sediments from sieve, laser diffraction, or image analysis‐derived measures of grain size with a limited amount of error. Collectively, these findings will allow for grain‐size data measured with different methods to be accurately converted to settling velocity for comparison. This will facilitate greater understanding of the hydraulic properties of bioclastic sediment which can help to increase our general knowledge of sediment dynamics in these environments.     

Spatial and temporal constraints on regional-scale groundwater flow in the Pampa del Tamarugal Basin,Atacama Desert,Chile

Aquifers within the Pampa del Tamarugal Basin (Atacama Desert, northern Chile) are the sole source of water for the coastal city of Iquique and the economically important mining industry. Despite this, the regional groundwater system remains poorly understood. Although it is widely accepted that aquifer recharge originates as precipitation in the Altiplano and Andean Cordillera to the east, there remains debate on whether recharge is driven primarily by near-surface groundwater flow in response to periodic flood events or by basal groundwater flux through deep-seated basin fractures. In addressing this debate, the present study quantifies spatial and temporal variability in regional-scale groundwater flow paths at 20.5°S latitude by combining a two-dimensional model of groundwater and heat flow with field observations and δ¹⁸O isotope values in surface water and groundwater. Results suggest that both previously proposed aquifer recharge mechanisms are likely influencing aquifers within the Pampa del Tamarugal Basin; however, each mechanism is operating on different spatial and temporal scales. Storm-driven flood events in the Altiplano readily transmit groundwater to the eastern Pampa del Tamarugal Basin through near-surface groundwater flow on short time scales, e.g., 10⁰–10¹ years, but these effects are likely isolated to aquifers in the eastern third of the basin. In addition, this study illustrates a physical mechanism for groundwater originating in the eastern highlands to recharge aquifers and salars in the western Pampa del Tamarugal Basin over timescales of 10⁴–10⁵ years.     

Trophic Resource Overlap Between Small Elasmobranchs and Sympatric Teleosts in Mid-Atlantic Bight Nearshore Habitats

Small, abundant elasmobranchs use shallow marine areas (<20 m depth) of the US Middle Atlantic coast as nurseries and adult foraging habitat, an area also used by a diverse assemblage of economically important juvenile and adult teleost species. Specimens of three small elasmobranch species (smooth dogfish Mustelus canis, clearnose skate Raja eglanteria, and bullnose ray Myliobatis freminvillii) were collected in August 2007 and 2008 from a study area of ∼150 km², extending 22 km south from Ocean City, Maryland, USA (38° 19′ N) and offshore from 5- to 20-m depth. Stomach contents indicated that fish were part of the diets of smooth dogfish and clearnose skate at a level comparable with sympatric piscivorous teleosts. However, stable isotope data suggest that piscivory is likely an opportunistic foraging behavior in this habitat. Studied elasmobranchs were secondary-tertiary consumers with diets composed primarily of decapod crustaceans, fish, and mollusks. There was significant overlap in diet composition, spatial distribution, and diel stomach fullness patterns between clearnose skate, southern kingfish Menticirrhus americanus (teleost) and, to a lesser extent, smooth dogfish. Despite this evidence for piscivory, their relatively low densities suggest that predation by these elasmobranchs is unlikely to affect teleost populations in shallow coastal ocean habitats. If shared prey were to become scarce, then competitive interactions are possible.