Variability of the gas transfer velocity of CO<Subscript>2</Subscript> in a macrotidal estuary (the Scheldt)

We report a large set of 295 interfacial carbon dioxide (CO₂) flux measurements obtained in the Scheldt estuary in November 2002 and April 2003, using the floating chamber method. From concomitant measurements of the air-water CO₂ gradient, we computed the gas transfer velocity of CO₂. The gas transfer velocity is well correlated to wind speed and a simple linear regression function gives the most consistent fit to the data. Based on water current measurements, we estimated the contribution of water current induced turbulence to the gas transfer velocity, using the conceptual relationship of O'Connor and Dobbins (1958). This allowed us to construct an empirical relationship to compute the gas transfer velocity of CO₂ that accounts for the contribution of wind and water current. Based on this relationship, the spatial and temporal variability of the gas transfer velocity in the Scheldt estuary was investigated. Water currents contribute significantly to the gas transfer velocity, but the spatial and temporal variability (from daily to seasonal scales) is mainly related to wind speed variability.     

Planktonic and whole system metabolism in a nutrient-rich estuary (the Scheldt estuary)

Planktonic gross primary production (GPP), community respiration (CR), and nitrification (NIT) were measured monthly in the Scheldt estuary by the oxygen incubation method in 2003. No significant evolution of planktonic GPP was observed since the 1990s with high rates in the freshwater area (salinity 0; 97±65 mmol C m⁻² d⁻¹) decreasing seaward (22–37 mmol C m⁻² d⁻¹). A significant decrease of NIT was observed with regard to previous investigations although this process still represents up to 20% of total organic matter production in the inner estuary. Planktonic CR was highest in the inner estuary and seemed to be mainly controlled by external organic matter inputs. Planktonic net community production was negative most of the time in the estuary with values ranging from −300 to 165 mmol C m⁻² d⁻¹. Whole estuary net ecosystem production (NEP) was investigated on an annual scale using the results mentioned above and published benthic metabolic rates. A NEP of −39±8 mmol C m⁻² d⁻¹ was estimated, which confirms the strong heterotrophic status of this highly nutrified estuary. NEP rates were computed from June to December 2003 to compare with results derived from the Land-Ocean Interaction in the Coastal Zone budgeting procedure applied to dissolved inorganic phosphorus and carbon (DIP and DIC). DIP budgets failed to provide realistic estimates in the inner estuary where abiotic processes account for more than 50% of the nonconservative DIP flux. DIC budgets predicted a much lower NEP than in situ incubations (−109±31 versus −42±9 mmol C m⁻² d⁻¹) although, as each approach is associated with several critical assumptions, the source of this discrepancy remains unclear.     

The AVA (amplitude-versus-angle) signature of small-scale reflector topography

Routine amplitude‐versus‐offset or amplitude‐versus‐angle (AVA) analysis is founded on the predicted reflectivity of a planar boundary between isotropic homogeneous half‐spaces, yet many real boundaries of interest to hydrocarbon exploration may violate these assumptions. Here, we evaluate consequences of boundary roughness, i.e. small‐scale, sub‐resolution topography, on the reflecting boundary, to find whether sub‐resolution topography can deceive routine AVA analysis and produce misleading hydrocarbon indicators. We use noise‐free synthetic CMP and stacked‐section seismograms, generated with a Kirchhoff‐integral method, for offsets up to 4000 m. The reflecting boundary was at 2000 m depth below a single overburden layer, and comprised isolated mounds or channels (sinusoidal cross‐section, 5–40 m high and 100–750 m wide), and more complex roughness (simulated with seven 1.5–2 km long bathymetric profiles across modern‐day river‐beds, with dune and bar features up to approximately 20 m or 20 ms TWT vertical relief, and 10–100 m or more lateral extent). Flat‐boundary responses were taken as the ‘reference’ against which to compare waveforms and amplitudes through semblance analysis, AVA intercept A and slope B cross‐plots, and inferred Poisson's ratios. Physical properties of the media were based on shales and brine‐ or oil‐sands from an offshore UK oilfield. For the CMP centred on the topographic feature, isolated mounds and channels produced correlated excursions of A and B from the flat‐boundary response (by approximately 35–200%), simulating the familiar ‘background trend’ but sometimes oblique to it. Inferred Poisson's ratios were around 0.3, but for some channels often fell as low as 0.2, potentially interpretable as gas sand. For complex boundary topographies on a shale/brine‐sand model, AVA parameters were extracted for 29 CMPs, 100 m apart along each of seven profiles. On a cross‐plot, they spanned the flat‐boundary response on a linear trend B = (0.01 ± 0.02) – (1.72 ± 0.09)A, similar to reported real data and a realistic ‘mudrock trend’ but with outliers both above and below it that could be interpreted as ‘real’ weak anomalies. Poisson's ratios were 0.30 ± 0.01, between the expected values for brine‐ and oil‐sand. This suggests that boundary roughness may contribute to observed trends on cross‐plots and possibly small, but potentially laterally extensive, false AVA anomalies may also be induced.     

Elasticity of superhydrous B

The adiabatic single-crystal elastic moduli of superhydrous B, Mg₁₀Si₃O₁₄(OH)₄, have been measured at ambient conditions using Brillouin spectroscopy. This material is the first hydrous phase found to be stable at the extreme conditions of 20 GPa and 1400 °C. The single-crystal moduli, in GPa, are: C ₁₁=280.0±1.5, C ₂₂=307.4±1.6, C ₃₃=293.4±1.4, C ₄₄=90.0±1.1, C ₅₅=99.2±0.8, C ₆₆=89.6±0.6, C ₁₂=66.1±2.2, C ₁₃=105.6±2.6, C ₂₃=81.8±2.6. With aggregate elastic properties of K _VRH =154.0±4.2 and μ _VRH =97.0±0.7 GPa, superhydrous B is approximately 16% suffer than forsterite and 20% softer than magnesium silicate spinel; it is also considerably more elastically isotropic than forsterite. The single-crystal moduli are compared to those of forsterite, magnesium silicate spinel and periclase, materials that are both structurally and compositionally similar to superhydrous B. The longitudinal moduli of superhydrous B and forsterite follow similar trends and appear to be dominated by the incompressibility and rotation of silicon tetrahedra. The shear and off-diagonal moduli more closely resemble those of periclase and spinel and may reflect the properties inherent to layers of magnesium octahedra.     

Diel feeding, daily food consumption and the predatory impact of whitemouth croaker (Micropogonias furnieri) in an estuarine environment

Diel feeding pattern and food consumption of whitemouth croaker (Micropogonias furnieri) were examined and related to seasonal variations in an estuarine environment. To determine diel feeding pattern whitemouth croaker were collected from the Patos Lagoon Estuary over 24 h (～3‐h intervals) and their stomach contents were examined. Food consumption of whitemouth croaker was determined from evacuation rates estimated experimentally and in the field. The results suggested that whitemouth croaker in the Patos Lagoon estuary feed all day long. However, whitemouth croaker showed higher feeding intensity and food consumption during daylight hours when the water transparency increased than in others when water transparency was low. Thus, whitemouth croaker seemed to intensify their feeding when they could see their prey. Daily food consumption was between 0.9 and 5.3% of body wet weight (these being the lowest and highest consumption rates during the winter and summer, respectively). The maximum predation impact of whitemouth croaker on their preferential prey, the tanaid Kalliapseudes schubartii, was 27indiv·m^?2·day^?1. The results suggested that the changes in water transparency seem to affect the diel feeding pattern and food consumption of whitemouth croaker. This could have important consequences for fish growth.     

Seasonal and interannual evolution of the mixed layer in the Antarctic Zone south of Tasmania

Seasonal and interannual variations of the mixed layer properties in the Antarctic Zone (AZ) south of Tasmania are described using 7 WOCE/SR3 CTD sections and 8 years of summertime SURVOSTRAL XBT and thermosalinograph measurements between Tasmania and Antarctica. The AZ, which extends from the Polar Front (PF) to the Southern Antarctic Circumpolar Current Front (SACCF), is characterized by a 150 m deep layer of cold Winter Water (WW) overlayed in summer by warmer, fresher water mass known as Antarctic Surface Water (AASW). South of Tasmania, two branches of the PF divide the AZ into northern and southern zones with distinct water properties and variability. In the northern AZ (between the northern and southern branches of the PF), the mixed layer depth (MLD) is fairly constant in latitude, being 150 m deep in winter and around 40–60 m in summer. In the southern AZ, the winter MLD decreases from 150 m at the S-PF to 80 m at the SACCF and from 60 to 35 m in summer. Shallower mixed layers in the AZ-S are due to the decrease in the wind speed and stronger upwelling near the Antarctic Divergence. The WW MLD oscillates by ±15 m around its mean value and modest interannual changes are driven by winter wind stress anomalies.The mixed layer is on annual average 1.7 °C warmer, 0.06 fresher and 0.2 kg m⁻³ lighter in the northern AZ than in the southern AZ. The Levitus (1998) climatology is in agreement with the observed mean summer mixed layer temperature and salinity along the SURVOSTRAL line but underestimates the MLD by 10–20 m. The winter MLD in the climatology is also closed to that observed, but is 0.15 saltier than the observations along the AZ-N of the SR3 line. MLD, temperature and density show a strong seasonal cycle through the AZ while the mixed layer salinity is nearly constant throughout the year. During winter, the AZ MLD is associated with a halocline while during summer it coincides with a thermocline.Interannual variability of the AZ summer mixed layer is partly influenced by large scale processes such as the circumpolar wave which produces a warm anomaly during the summer 1996–1997, and partly by local mechanisms such as the retroflection of the S-PF which introduces cold water across the AZ-N.     

Conditions governing the use of approximations for the Saint-Vénant equations for shallow surface water flow

The solutions of the Saint-Vénant equations are compared with those of the kinematic, diffusion and gravity wave approximations, for a range of constant Froudé and kinematic wave numbers, with two different lower boundary conditions: (1) critical flow; and (2) zero depth gradient. For each lower boundary condition, zones are defined in the F₀,k-field in which either kinematic, diffusion or gravity wave solutions may be used to approximate the full Saint-Vénant solutions.     

Geochemistry and isotopes of fluids from sulphur springs, Valles Caldera, New Mexico

Detailed geochemistry supported by geologic mapping has been used to investigate Sulphur Springs, an acid-sulfate hot spring system that issues from the western flank of the resurgent dome inside Valles Caldera. The most intense activity occurs at the intersection of faults offsetting caldera-fill deposits and post-caldera rhyolites. Three geothermal wells in the area have encountered pressures <1 MPa and temperatures of 200°C at depths of 600 to 1000 m. Hot spring and fumarole fluids may discharge at boiling temperatures with pH 1.0 and SO₄ 8000 mg/l. These conditions cause argillic alterations throughout a large area.Non-condensible gases consist of roughly 99% CO₂ with minor amounts of H₂S, H₂, and CH₄. Empirical gas geothermometry suggests a deep reservoir temperature of 215 to 280°C. Comparison of ¹³C and ¹⁸O between CaCO₃ from well cuttings and CO₂ from fumarole steam indicates a fractionation temperature between 200 and 300°C by decarbonation of hydrothermally altered Paleozoic limestone and vein calcite in the reservoir rocks. Tritium concentrations obtained from steam condensed in a mudpot and deep reservoir fluids (Baca #13, 278°C) are 2.1 and 1.0 T.U. respectively, suggesting the steam originates from a reservoir whose water is mostly >50 yrs old. Deuterium contents of fumarole steam, deep reservoir fluid, and local meteoric water are practically identical even though ¹⁸O contents range through 4‰, thus, precipitation on the resurgent dome of the caldera could recharge the hydrothermal system by slow percolation. From analysis of D and ¹⁸O values between fumarol steam and deep reservoir fluid, steam reaches the surface either (1) by vaporizing relatively shallow groundwater at 200°C or (2) by means of a two-stage boiling process through an intermediate level reservoir at roughly 200°C.Although many characteristics of known vapor-dominated geothermal systems are found at Sulphur Springs, fundamental differences exist in temperature and pressure of our postulated vapor-zone. We propose that the reservoir beneath Sulphur Springs is too small or too poorly confined to sustain a “true” vapor-dominated system and that the Sulphur Springs system may be a “dying” vapor-dominated system that has practically boiled itself dry.