Calibrating a Salt Water Intrusion Model with Time‐Domain Electromagnetic Data

Salt water intrusion models are commonly used to support groundwater resource management in coastal aquifers. Concentration data used for model calibration are often sparse and limited in spatial extent. With airborne and ground‐based electromagnetic surveys, electrical resistivity models can be obtained to provide high‐resolution three‐dimensional models of subsurface resistivity variations that can be related to geology and salt concentrations on a regional scale. Several previous studies have calibrated salt water intrusion models with geophysical data, but are typically limited to the use of the inverted electrical resistivity models without considering the measured geophysical data directly. This induces a number of errors related to inconsistent scales between the geophysical and hydrologic models and the applied regularization constraints in the geophysical inversion. To overcome these errors, we perform a coupled hydrogeophysical inversion (CHI) in which we use a salt water intrusion model to interpret the geophysical data and guide the geophysical inversion. We refer to this methodology as a Coupled Hydrogeophysical Inversion‐State (CHI‐S), in which simulated salt concentrations are transformed to an electrical resistivity model, after which a geophysical forward response is calculated and compared with the measured geophysical data. This approach was applied for a field site in Santa Cruz County, California, where a time‐domain electromagnetic (TDEM) dataset was collected. For this location, a simple two‐dimensional cross‐sectional salt water intrusion model was developed, for which we estimated five uniform aquifer properties, incorporating the porosity that was also part of the employed petrophysical relationship. In addition, one geophysical parameter was estimated. The six parameters could be resolved well by fitting more than 300 apparent resistivities that were comprised by the TDEM dataset. Except for three sounding locations, all the TDEM data could be fitted close to a root‐mean‐square error of 1. Possible explanations for the poor fit of these soundings are the assumption of spatial uniformity, fixed boundary conditions and the neglecting of 3D effects in the groundwater model and the TDEM forward responses.     

Evaluation of infiltration‐based stormwater management to restore hydrological processes in urban headwater streams

Urbanization threatens headwater stream ecosystems globally. Watershed restoration practices, such as infiltration‐based stormwater management, are implemented to mitigate the detrimental effects of urbanization on aquatic ecosystems. However, their effectiveness for restoring hydrologic processes and watershed storage remains poorly understood. Our study used a comparative hydrology approach to quantify the effects of urban watershed restoration on watershed hydrologic function in headwater streams within the Coastal Plain of Maryland, USA. We selected 11 headwater streams that spanned an urbanization–restoration gradient (4 forested, 4 urban‐degraded, and 3 urban‐degraded) to evaluate changes in watershed hydrologic function from both urbanization and watershed restoration. Discrete discharge and continuous, high‐frequency rainfall‐stage monitoring were conducted in each watershed. These datasets were used to develop 6 hydrologic metrics describing changes in watershed storage, flowpath connectivity, or the resultant stream flow regime. The hydrological effects of urbanization were clearly observed in all metrics, but only 1 of the 3 restored watersheds exhibited partially restored hydrologic function. At this site, a larger minimum runoff threshold was observed relative to the urban‐degraded watersheds, suggesting enhanced infiltration of stormwater runoff within the restoration structure. However, baseflow in the stream draining this watershed remained low compared to the forested reference streams, suggesting that enhanced infiltration of stormwater runoff did not recharge subsurface storage zones contributing to stream baseflow. The highly variable responses among the 3 restored watersheds were likely due to the spatial heterogeneity of urban development, including the level of impervious cover and extent of the storm sewer network. This study yielded important knowledge on how restoration strategies, such as infiltration‐based stormwater management, modulated—or failed to modulate—hydrological processes affected by urbanization, which will help improve the design of future urban watershed management strategies. More broadly, we highlighted a multimetric approach that can be used to monitor the restoration of headwater stream ecosystems in disturbed landscapes.     

Dispersive Liquid–Liquid Microextraction for Preconcentration and Determination of Nickel in Water

A method for the determination of nickel in water was developed. The procedure involves preconcentration of nickel by using dispersive liquid–liquid microextraction. The Ni(II) ions were extracted in chloroform in the form of complex with the reagent 2‐(2′‐benzothiazolylazo)‐p‐cresol. Ethanol was used as the disperser solvent. After injection of the extracting mixture in a solution of nickel, a cloudy mixture was observed. A quick centrifugation induces phase separation and thus the settling of rich phase. The nickel content in the rich phase is measured by flame atomic absorption spectrometry. Under optimal conditions, the limit of detection and quantification obtained were 1.4 and 4.7 µg L^?1, respectively. Some parameters used to characterize preconcentration systems, such as enrichment factor and consumption index were calculated and resulted in 29 and 0.34 mL, respectively. After optimization of variables and determination of analytical characteristics, the method was used for the analysis of certified reference materials (BCR‐713: wastewater, effluent and BCR‐414: plankton) and real water samples.     

Sources of sodium in the lunar exosphere: Modeling using ground-based observations of sodium emission and spacecraft data of the plasma

Observations of the equatorial lunar sodium emission are examined to quantify the effect of precipitating ions on source rates for the Moon’s exospheric volatile species. Using a model of exospheric sodium transport under lunar gravity forces, the measured emission intensity is normalized to a constant lunar phase angle to minimize the effect of different viewing geometries. Daily averages of the solar Lyman α flux and ion flux are used as the input variables for photon-stimulated desorption (PSD) and ion sputtering, respectively, while impact vaporization due to the micrometeoritic influx is assumed constant. Additionally, a proxy term proportional to both the Lyman α and to the ion flux is introduced to assess the importance of ion-enhanced diffusion and/or chemical sputtering. The combination of particle transport and constrained regression models demonstrates that, assuming sputtering yields that are typical of protons incident on lunar soils, the primary effect of ion impact on the surface of the Moon is not direct sputtering but rather an enhancement of the PSD efficiency. It is inferred that the ion-induced effects must double the PSD efficiency for flux typical of the solar wind at 1 AU. The enhancement in relative efficiency of PSD due to the bombardment of the lunar surface by the plasma sheet ions during passages through the Earth’s magnetotail is shown to be approximately two times higher than when it is due to solar wind ions. This leads to the conclusion that the priming of the surface is more efficiently carried out by the energetic plasma sheet ions.     

中国、西班牙在莱斯诺德（LANZAROTE）岛的火山与地球动力学合作研究的首期结果

本文介绍中、西双方在西班牙莱斯诺德（ＬＡＮＺＡＲＯＴＥ）火山与地球动力学地下实验室共同进行静力水准仪、水平应变伸缩仪、岩体和空气测温计等仪器的合作研究实验以及分析所得的首批成果。     

Wavelet Analysis of Solar-ENSO Imprints in Tree Ring Data from Southern Brazil in the Last Century

In order to study the imprint of solar and ENSO signals on terrestrial archives, the wavelet spectrum analysis was applied to solar-geophysical indices and tree ring data. Time series of Sunspot Number (SSN), southern oscillation index (SOI) and tree-ring indices from Southern Brazil, for the period 1876–1991, were used in this work. The 11-year solar cycle was present during the whole period in tree ring data, being more intense during 1930–1980, in agreement with an earlier study that was performed for thesame region but a different time range (1836–1996). ENSO effects on treering data from Southern Brazil were studied by the first time in this work using wavelet analysis. Short-term variations, between 2–5 years, arealso present in tree ring data. This represents the signature of ENSO events and was also observed in the SOI, as expected. The cross-wavelet spectrum analysis shows that both solar and climatic factors are recorded in tree ring data.     

地球动力学观测技术在西班牙Lanzarote火山预测中的应用研究

中国和西班牙合作在西班牙Ｌａｎｚａｒｏｔｅ火山地球动力学实验里开展了对地球动力学观测技术与仪器的研究，并对监测和长期实验结果进行了解释。用合作研究的先进仪器和观测技术监督并获取火山及地震的前兆地壳变动信息，对于探索预测火山爆发规律，推动地球动力学观测技术和仪器的发展以及深入研究对火山和地震等灾害的防御对等等，将具有十分重要的科学价值。     

Variation in chlorophylla concentrations and Margalef’s index of pigment diversity in two solar salt ponds,Aveiro, Portugal

Variations of chlorophylla and Margalef's pigment diversity index were studied in two solar salt ponds at Aveiro (Esmolas and Tanoeiras). Portugal. In the Esmolas ponds, mean chlorophyll a values varied between 2.49 and 13.33 mg m⁻³ in the non-growing season, and between 5.43 and 40.55 mg m⁻³ in the growing season. In the Tanoeiras ponds, mean chlorophylla values were between 8.12 and 14.85 mg m⁻³ in the non-growing season, and 8.65 and 21.19 mg m⁻³ in the growing season. Fluctuations of Margalef's pigment diversity index were more irregular.