Gravimetric and magnetic fabric study of the Sintra Igneous complex: laccolith-plug emplacement in the Western Iberian passive margin

International Journal of Earth Sciences - The geometry and emplacement of the ~ 96 km2, Late Cretaceous Sintra Igneous complex (SIC, ca. 80 Ma) into the West Iberian passive...     

Wind-Driven Dissolved Organic Matter Dynamics in a Chesapeake Bay Tidal Marsh-Estuary System

Controls on organic matter cycling across the tidal wetland-estuary interface have proved elusive, but high-resolution observations coupled with process-based modeling can be a powerful methodology to address shortcomings in either methodology alone. In this study, detailed observations and three-dimensional hydrodynamic modeling are used to examine biogeochemical exchanges in the marsh-estuary system of the Rhode River, MD, USA. Analysis of observations near the marsh in 2015 reveals a strong relationship between marsh creek salinity and dissolved organic matter fluorescence (fDOM), with wind velocity indirectly driving large amplitude variation of both salinity and fDOM at certain times of the year. Three-dimensional model results from the Finite Volume Community Ocean Model implemented for the wetland system with a new marsh grass drag module are consistent with observations, simulating sub-tidal variability of marsh creek salinity. The model results exhibit an interaction between wind-driven variation in surface elevation and flow velocity at the marsh creek, with northerly winds driving increased freshwater signal and discharge out of the modeled wetland during precipitation events. Wind setup of a water surface elevation gradient axially along the estuary drives the modeled local sub-tidal flow and thus salinity variability. On sub-tidal time scales (>36 h, <1 week), wind is important in mediating dissolved organic matter releases from the Kirkpatrick Marsh into the Rhode River.     

Impact of drilling mud on chemistry and microbiology of an Upper Triassic groundwater after drilling and testing an exploration well for aquifer thermal energy storage in Berlin (Germany)

After completion of an exploration well, sandstones of the Exter Formation were hydraulically tested to determine the hydraulic properties and to evaluate chemical and microbial processes caused by drilling and water production. The aim was to determine the suitability of the formation as a reservoir for aquifer thermal energy storage. The tests revealed a hydraulic conductivity of 1–2 E-5 m/s of the reservoir, resulting in a productivity index of 0.6–1 m³/h/bar. A hydraulic connection of the Exter Formation to the overlaying, artesian “Rupelbasissand” cannot be excluded. Water samples were collected for chemical and microbiological analyses. The water was similarly composed as sea water with a maximum salinity of 24.9 g/L, dominated by NaCl (15.6 g/L Cl and 7.8 g/L Na). Until the end of the tests, the water was affected by drilling mud as indicated by the high pH (8.9) and high bicarbonate concentration (359 mg/L) that both resulted from the impact of sodium carbonate (Na₂CO₃) additives. The high amount of dissolved organic matter (>?58 mg/L) and its molecular-weight distribution pattern indicated that residues of cellulose, an ingredient of the drilling mud, were still present at the end of the tests. Clear evidence of this contamination gave the measured uranine that was added as a tracer into the drilling mud. During fluid production, the microbial community structure and abundance changed and correlated with the content of drilling mud. Eight taxa of sulfate-reducing bacteria, key organisms in processes like bio-corrosion and bio-clogging, were identified. It can be assumed that their activity will be affected during usage of the reservoir.     

Ecotoxicological evaluation of dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro State,Brazil) using bioassays with earthworms and collembolans

The toxicity and metal bioavailability were studied in dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro, RJ, Brazil) using acute and avoidance tests with Eisenia andrei, and reproduction tests with Folsomia candida. The sediment was mixed with an artificial soil, and two natural soils (ferralsol and chernosol—representative Brazilian tropical soils) to obtain the following doses: 1, 3, 6, 12, 18, 24 and 30%. Total metal concentrations were determined in the sediment to support the interpretation of ecotoxicological data. Metal concentrations in the mixtures were in agreement with the threshold limits established by Brazilian law. However, significant avoidance responses were found on doses ≥?3% and were the most sensitive endpoint. Earthworm mortality found in artificial soil mixtures (LC50?=?3.9) suggests higher toxicity levels than those obtained in ferralsol (LC50?=?7.6%) and chernosol (11.0%) treatments. Earthworm mortality, avoidance responses and collembolan reproduction levels found in ferralsol mixtures (LC50?=?9.2; avoidance EC50?=?2.3%; reproduction EC50?=?2.8%) were higher compared to chernosol treatments (LC50?=?11.0%; avoidance EC50?=?4.3%; reproduction EC50?=?4.9%). The reduction of toxicity levels in chernosol mixtures is probably due to the abundance of expansive clay minerals in chernosols with capacity of adsorbing metals and other xenobiotic substances from soil pore water, decreasing metal bioavailability. Finally, threshold limits defined by Brazilian legislation for soil quality and land disposal of dredged sediments are not sufficient to prevent noxious effects on soil fauna and should be complemented with a preliminary ecotoxicological evaluation.     

Spectral data source effect on crop state estimation by vegetation indices

Spectral vegetation indices (VIs) are a well-known and widely used method for crop state estimation. The ability to monitor crop state by such indices is an important tool for agricultural management. Even though differences in imagery and point-based spectroscopy are obvious, their impact on crop state estimation by VIs is not well-studied. The aim of this study was to assess the performance level of the selected VIs calculated from spaceborne multispectral imagery and point-based field spectroscopy in application to crop state estimation. For this purpose, irrigated chickpea field was monitored by RapidEye satellite mission and additional measurements by field spectrometer were obtained. Estimated VIs average and coefficient of variation from each observation were compared with physical crop measurements: leaf water content, LAI and chlorophyll level. The results indicate that indices calculated from spaceborne spectral images regardless of the claimed response commonly react on phenology of the irrigated chickpea. This feature makes spaceborne spectral imagery an appropriate data source for monitoring crop development, crop water needs and yield prediction. VIs calculated from field spectrometer were sensitive for estimating pigment concentration and photosynthesis rate. Yet, a hypersensitivity of field spectral measures might lead to a very high variability (up to 69%) of the calculated values. Consequently, the high spatial variability of field spectral measurements depreciates the estimation agricultural field state by average mean only. Nevertheless, the spatial variability might have certain behavior trend, e.g., a significant increase in the active growth or stress and can be an independent feature for field state assessment.     

Hydrologic models coupled with 2D hydrodynamic model for high-resolution urban flood simulation

Natural Hazards - Floods are the most frequent natural disaster and pose a very challenging threat to many cities worldwide. Understanding the flood dynamic is essential for developing strategies...     

Methodological challenges to confirmatory latent variable models of social vulnerability

Natural Hazards - Socially vulnerable communities experience disproportionately negative outcomes following natural disasters and underscoring a need for well-validated measures to identify those...     

Testing the consistency of Holocene and Last Glacial Maximum spatial correlations in temperature proxy records

Holocene temperature proxy records are commonly used in quantitative synthesis and model-data comparisons. However, comparing correlations between time series from records collected in proximity to one another with the expected correlations based on climate model simulations indicates either regional or noisy climate signals in Holocene temperature proxy records. In this study, we evaluate the consistency of spatial correlations present in Holocene proxy records with those found in data from the Last Glacial Maximum (LGM). Specifically, we predict correlations expected in LGM proxy records if the only difference to Holocene correlations would be due to more time uncertainty and more climate variability in the LGM. We compare this simple prediction to the actual correlation structure in the LGM proxy records. We found that time series data of ice-core stable isotope records and planktonic foraminifera Mg/Ca ratios were consistent between the Holocene and LGM periods, while time series of Uk'37 proxy records were not as we found no correlation between nearby LGM records. Our results support the finding of highly regional or noisy marine proxy records in the compilation analysed here and suggest the need for further studies on the role of climate proxies and the processes of climate signal recording and preservation.     

A novel methodological approach for land subsidence prediction through data assimilation techniques

Computational Geosciences - Anthropogenic land subsidence can be evaluated and predicted by numerical models, which are often built over deterministic analyses. However, uncertainties and...     

Spatial analysis approaches for the evaluation and protection of groundwater resources in large watersheds of the Canadian Shield

This study focuses on the development of two GIS-based approaches that are used jointly to evaluate the groundwater resources associated with granular aquifers in shield environments. The first approach is a multi-criteria analysis (MCA) using an analytical hierarchic process (AHP) based on geological and hydrogeological data for ranking the probability of finding readily available groundwater resources in a specific territory. The second approach relies on GIS-based geometric calculations that were developed for evaluating the extent and volume of aquifers. The approaches are applied on a 100?×?100 m grid in a 185,000-km² area corresponding to watersheds of the James Bay area in Quebec, Canada. The MCA-AHP approach revealed that the unconfined granular aquifers that present the highest aquifer potential (AP) are sparsely distributed and mostly associated with glaciofluvial formations such as the Harricana and Sakami moraines. The geometric calculations approach allowed for estimating that the total volume of groundwater stored in the unconfined granular aquifers reaches approximately 40 km³. When used jointly, the two approaches reveal that the shallow unconfined aquifers that require increased groundwater protection account for approximately 5% of the territory. In areas of confined granular aquifers, the highest APs are located in river valleys and lowlands. A sensitivity analysis conducted on the MCA-AHP approach revealed that the grid size does not significantly affect the results. Therefore, the approach was expanded northward, to a 490,000-km² territory reaching the Ungava Bay area. The proposed method could be adapted and applied in other shield areas.