Spatiotemporal changes in CO<Subscript>2</Subscript> emissions during the second ZERT injection,August–September 2008

This study reports the first field test of a multi-channel, auto-dilution, steady-state, soil–CO₂ flux monitoring system being developed to help understand the pathways by which fugitive CO₂ from a geologic sequestration site migrates to the surface. The test was conducted from late August through mid-October 2008 at the Zero Emissions Research and Technology project site located in Bozeman, MT. Twenty steady-state and five non-steady-state flux chambers were installed in a 10 × 15 m area, one boundary of which was directly above a shallow (2-m depth) horizontal injection well located 0.5 m below the water table. A total flux of 52 kg CO₂ day⁻¹ was injected into the well for 13 days and the efflux from the soil was monitored by the chambers before, during, and for 33 days after the injection. The results showed a rapid increase in soil efflux once injection started, with maximal values reached within 3–7 days in most chambers. Efflux returned to background levels within a similar time period after injection ceased. A radial efflux pattern was observed to at least 2 m from the injection well, and evidence for movement of the CO₂ plume during the injection, presumably due to groundwater flow, was seen. The steady-state chambers yielded very stable data, but threefold to fivefold higher fluxes than the non-steady-state chambers. The higher fluxes were attributed to vacuum induced in the steady-state chambers by narrow vent tubes. High winds resulted in significant decreases in measured soil CO₂ efflux, presumably by enhancing efflux from soil outside the chambers.     

Studies of ultracompact H II regions – III. Near-infrared survey of selected regions

A survey towards a selection of 35 methanol maser and/or ultracompact (UC) H  ii regions, reported in Papers I and II and by Norris et al., has been conducted in the near-infrared (NIR). Out of 25 methanol maser sites surveyed, 12 are associated with a NIR counterpart. Out of 18 UC H  ii regions (8 of which overlap with maser emission), 12 are associated with a NIR counterpart. Counterparts can be confidently identified not only by the positional agreements, but also by their unusually red colours. Spectral types for the embedded stars can be unambiguously determined for six sources, all of which imply massive, ionizing stars. One of these infrared sources has methanol maser emission, but no UC H  ii region. It is possible that the maser emission associated with this source arises from a pre-UC H  ii phase of massive stellar evolution or it could be that nearly all the ultraviolet photons are absorbed by dust within the UC H  ii region. We have modelled the spectral energy distributions (SEDs) for some sources and find that a single blackbody can be used to estimate the stellar luminosity, but cannot represent the whole infrared SED. A two-component blackbody model and a radiative transfer model were also used to derive essential parameters of the infrared sources. The radiative transfer model also indicates which infrared sources are relatively young and which are older. Both models show that silicate absorption at 9.7 μm must be a dominant feature of these SEDs.     

Structural evolution and the partitioning of deformation during basin growth and inversion: A case study from the Mizen Basin Celtic Sea,offshore Ireland

The Celtic Sea basins lie on the continental shelf between Ireland and northwest France and consist of a series of ENE–WSW trending elongate basins that extend from St George’s Channel Basin in the east to the Fastnet Basin in the west. The basins, which contain Triassic to Neogene stratigraphic sequences, evolved through a complex geological history that includes multiple Mesozoic rift stages and later Cenozoic inversion. The Mizen Basin represents the NW termination of the Celtic Sea basins and consists of two NE–SW-trending half-grabens developed as a result of the reactivation of Palaeozoic (Caledonian, Lower Carboniferous and Variscan) faults. The faults bounding the Mizen Basin were active as normal faults from Early Triassic to Late Cretaceous times. Most of the fault displacement took place during Berriasian to Hauterivian (Early Cretaceous) times, with a NW–SE direction of extension. A later phase of Aptian to Cenomanian (Early to Late Cretaceous) N–S-oriented extension gave rise to E–W-striking minor normal faults and reactivation of the pre-existing basin bounding faults that propagated upwards as left-stepping arrays of segmented normal faults. In common with most of the Celtic Sea basins, the Mizen Basin experienced a period of major erosion, attributed to tectonic uplift, during the Paleocene. Approximately N–S Alpine regional compression-causing basin inversion is dated as Middle Eocene to Miocene by a well-preserved syn-inversion stratigraphy. Reverse reactivation of the basin bounding faults was broadly synchronous with the formation of a set of near-orthogonal NW–SE dextral strike-slip faults so that compression was partitioned onto two fault sets, the geometrical configuration of which is partly inherited from Palaeozoic basement structure. The segmented character of the fault forming the southern boundary of the Mizen Basin was preserved during Alpine inversion so that Cenozoic reverse displacement distribution on syn-inversion horizons mirrors the earlier extensional displacements. Segmentation of normal faults therefore controls the geometry and location of inversion structures, including inversion anticlines and the back rotation of earlier relay ramps.     

Influence of Wind-Driven Inundation and Coastal Geomorphology on Sedimentation in Two Microtidal Marshes, Pamlico River Estuary, NC

Marsh sediment accumulation is predominately a combination of in situ organic accumulation and mineral sediment input during inundation. Within the Pamlico River Estuary (PRE), marsh inundation is dependent upon event (e.g., storms) and seasonal wind patterns due to minimal astronomical tides (<10 cm). A better understanding of the processes controlling sediment deposition and, ultimately, marsh accretion is needed to forecast marsh sustainability with changing land usage, climate, and sea level rise. This study examines marsh topography, inundation depth, duration of inundation, and wind velocity to identify relationships between short-term deposition (tile-based) and long-term accumulation (²¹⁰Pb and ¹³⁷Cs) recorded within and adjacent to the PRE. The results of this study indicate (1) similar sedimentation patterns between the interior marsh and shore-side marsh at different sites regardless of elevation, (2) increased sedimentation (one to two orders of magnitude, 0.04–4.54 g m^?2 day^?1) within the interior marsh when the water levels exceeded the adjacent topography (e.g., storm berm), and (3) that short-term sea level changes can have direct effects on sediment delivery to interior marshes in wind-driven estuarine systems.     

Geochemistry of hydrothermal fluids from the PACMANUS, Northeast Pual and Vienna Woods hydrothermal fields, Manus Basin, Papua New Guinea

Processes controlling the composition of seafloor hydrothermal fluids in silicic back-arc or near-arc crustal settings remain poorly constrained despite growing evidence for extensive magmatic-hydrothermal activity in such environments. We conducted a survey of vent fluid compositions from two contrasting sites in the Manus back-arc basin, Papua New Guinea, to examine the influence of variations in host rock composition and magmatic inputs (both a function of arc proximity) on hydrothermal fluid chemistry. Fluid samples were collected from felsic-hosted hydrothermal vent fields located on Pual Ridge (PACMANUS and Northeast (NE) Pual) near the active New Britain Arc and a basalt-hosted vent field (Vienna Woods) located farther from the arc on the Manus Spreading Center. Vienna Woods fluids were characterized by relatively uniform endmember temperatures (273-285 °C) and major element compositions, low dissolved CO₂ concentrations (4.4 mmol/kg) and high measured pH (4.2-4.9 at 25 °C). Temperatures and compositions were highly variable at PACMANUS/NE Pual and a large, newly discovered vent area (Fenway) was observed to be vigorously venting boiling (358 °C) fluid. All PACMANUS fluids are characterized by negative δD_H2O values, in contrast to positive values at Vienna Woods, suggesting substantial magmatic water input to circulating fluids at Pual Ridge. Low measured pH (25 °C) values (∼2.6-2.7), high endmember CO₂ (up to 274 mmol/kg) and negative δ³⁴S_H2S values (down to −2.7‰) in some vent fluids are also consistent with degassing of acid-volatile species from evolved magma. Dissolved CO₂ at PACMANUS is more enriched in ¹³C (−4.1‰ to −2.3‰) than Vienna Woods (−5.2‰ to −5.7‰), suggesting a contribution of slab-derived carbon. The mobile elements (e.g. Li, K, Rb, Cs and B) are also greatly enriched in PACMANUS fluids reflecting increased abundances in the crust there relative to the Manus Spreading Center. Variations in alkali and dissolved gas abundances with Cl at PACMANUS and NE Pual suggest that phase separation has affected fluid chemistry despite the low temperatures of many vents. In further contrast to Vienna Woods, substantial modification of PACMANUS/NE Pual fluids has taken place as a result of seawater ingress into the upflow zone. Consistently high measured Mg concentrations as well as trends of increasingly non-conservative SO₄ behavior, decreasing endmember Ca/Cl and Sr/Cl ratios with increased Mg indicate extensive subsurface anhydrite deposition is occurring as a result of subsurface seawater entrainment. Decreased pH and endmember Fe/Mn ratios in higher Mg fluids indicate that the associated mixing/cooling gives rise to sulfide deposition and secondary acidity production. Several low temperature (?80 °C) fluids at PACMANUS/NE Pual also show evidence for anhydrite dissolution and water-rock interaction (fixation of B) subsequent to seawater entrainment. Hence, the evolution of fluid compositions at Pual Ridge reflects the cumulative effects of water/rock interaction, admixing and reaction of fluids exsolved from silicic magma, phase separation/segregation and seawater ingress into upflow zones.     

Geology of London,UK

The population of London is around 7 million. The infrastructure to support this makes London one of the most intensively investigated areas of upper crust. However construction work in London continues to reveal the presence of unexpected ground conditions. These have been discovered in isolation and often recorded with no further work to explain them. There is a scientific, industrial and commercial need to refine the geological framework for London and its surrounding area. This paper reviews the geological setting of London as it is understood at present, and outlines the issues that current research is attempting to resolve.     

Coronal heating events in high-cadence TRACE data

On March 23rd 1999 a set of TRACE (Transition Region and Coronal Explorer) observations were taken in support of Solar and Heliospheric Observatory (SOHO) / TRACE Joint Observing Program 83. The program is designed to look for coronal heating mechanisms operating at high cadence and to observe their dynamical effects on coronal loop density, temperature and magnetic structure. We present here a study of 27 small, dynamic brightening events seen in this data. These events are seen in the quiet-Sun areas surrounding the active region. The data itself consists of 157 171 Å 512×512 arc sec images at 1 arc sec resolution and 9 second cadence, a previously unavailable combination of cadence, resolution and image size. Three classes of events are introduced: complex, intermediate and simple. All three classes share the property of being dynamic on small time and length scales but differ in the complexity of their behavior. We find that the brightenings across all classes exhibit variations as part of a distribution of time scales (90–400 s) peaked around 228 s. The brightenings are no more than 5 arc sec in diameter. Motions between brightenings occur on time scales from 9 to 90 s and on length scales no greater than 10 arc sec. These motions have velocities estimated to be in the range 89–174 km s^?1. The position of these events in the spectrum of previously observed coronal heating events is discussed.

     

Evaluation of TMPA 3B42 Precipitation Estimates during the Passage of Tropical Cyclones over New Caledonia

A deficit in precipitation may impact greatly on soil moisture, snowpack, streamflow, groundwater and reservoir storage. Among the several approaches available to investigate this phenomenon, one of the most applied is the analysis of dry spells. In this study, a non-homogeneous Poisson model has been applied to a set of high-quality daily rainfall series, recorded in southern Italy (Calabria region) during the period 1981–2010, for the stochastic analysis of dry spells. Firstly, some statistical details of the Poisson models were presented. Then, the proposed model has been applied to the analysis of long dry spells. In particular, a Monte Carlo technique was performed to reproduce the characteristics of the process. As a result, the main characteristics of the long dry spells have shown patterns clearly related to some geographical features of the study area, such as elevation and latitude. The results obtained from the stochastic modelling of the long dry spells proved that the proposed model is useful for the probability evaluation of drought, thus improving environmental planning and management.