A preliminary methods comparison for measurement of dissolved organic nitrogen in seawater

Routine determination of dissolved organic nitrogen (DON) is performed in numerous laboratories around the world using one of three families of methods: UV oxidation (UV), persulfate oxidation (PO), or high temperature combustion (HTC). Essentially all routine methods measure total dissolved nitrogen (TDN) and calculate DON by subtracting the dissolved inorganic nitrogen (DIN). While there is currently no strong suggestion that any of these methods is inadequate, there are continuing suspicions of slight inaccuracy by UV methods.This is a report of a broad community methods comparison where 29 sets (7 UV, 13 PO, and 9 HTC) of TDN analyses were performed on five samples with varying TDN and DIN concentrations. Analyses were done in a “blind” procedure with results sent to the first author. With editing out one set of extreme outliers (representing 5 out of 145 ampoules analyzed), the community comparability for analyzing the TDN samples was in the 8–28% range (coefficient of variation representing one standard deviation for the five individual samples by 28 analyses). When DIN concentrations were subtracted uniformly (single DIN value for each sample), the comparability was obviously worse (19–46% cv). This comparison represents a larger and more diverse set of analyses, but the overall comparability is only marginally better than that of the Seattle workshop of a decade ago. Grouping methods, little difference was seen other than inconclusive evidence that the UV methods gave TDN values for several of the samples higher than HTC methods. Since there was much scatter for each of the groups of methods and for all analyses when grouped, it is thought that more uniformity in procedures is probably needed. An important unplanned observation is that variability in DIN analyses (used in determining the final analyte in most UV and PO methods) is essentially as large as the variability in the TDN analyses.This exercise should not be viewed as a qualification exercise for the analysts, but should instead be considered a broad preliminary test of the comparison of the families of methods being used in various laboratories around the world. Based on many independent analyses here, none of the routinely used methods appears to be grossly inaccurate, thus, most routine TDN analyses being reported in the literature are apparently accurate. However, it is not reassuring that the ability of the international community to determine DON in deep oceanic waters continues to be poor. It is suggested that as an outgrowth of this paper, analysts using UV and PO methods experiment and look more carefully at the completeness of DIN conversion to the final analyte and also at the accuracy of their analysis of the final analyte. HTC methods appear to be relatively easy and convenient and have potential for routine adoption. Several of the authors of this paper are currently working together on an interlaboratory comparison on HTC methodology.     

An Assessment of Snow Avalanche Paths and Forest Dynamics Using Ikonos Satellite Data

Abstract

Ikonos panchromatic and multispectral satellite data were acquired in October 2000 and August 2002 for a test area along US Highway 2, the southern border of Glacier National Park (GNP), Montana, USA. The research goals were to map snow avalanche paths and to characterize vegetation patterns in selected paths for longitudinal (i.e., source, track, and runout) and transverse (i.e., inner, flanking, outer) zones as part of a study of forest dynamics and nutrient flux from paths into terrestrial and aquatic systems. In some valleys, as much as 50 percent of the area may be covered by snow avalanche paths, and as such, serve as an important carbon source servicing terrestrial and aquatic ecosystems. Snow avalanches move woody debris down‐slope by snapping, tipping, trimming, and excavating branches, limbs, and trees, and by injuring and scaring trees that remain in‐place. Further, snow avalanches alter the vegetation structure on paths through secondary plant succession of disturbed areas. Contrast and edge enhancements, Normalized Difference Vegetation Index (NDVI), and the Tasseled Cap greenness and wetness transformations were used to examine vegetation patterns in selected paths that were affected by high magnitude snow avalanches during the winter of 2001-2002. Using image transects organized in longitudinal patterns in paths and in forests, and transects arranged in transverse patterns across the sampled paths, the Tasseled Cap transforms (and NDVI values) were plotted and assessed. Preliminary results suggest that NDVI patterns are different for paths and forests, and Tasseled Cap greenness and wetness patterns are different for longitudinal and transverse zones that describe the morphology of snow avalanche paths. The differentiation of paths from the background forest and the characterization of paths by morphometric zones through remote sensing has implications for mapping forest disturbances and dynamics over time and for large geographic areas and for modeling nutrient flux in terrestrial and aquatic systems.     

JAMSTEC-IARC international collaboration enhancing understanding of the Arctic climate system

Collaborations amongst researchers from the Japan Agency for Marine-Earth Science and Technology (JAMSTEC), Japan and the International Arctic research Center (IARC), University of Alaska Fairbanks (UAF), U.S., have been on-going since 1998 and resulted in a great number and magnitude of accomplishments that could not have been achieved without this close partnership. The Arctic represents an important region for Japan, the U.S. and the world, and many opportunities and challenges press for immediate understanding to enable wise decisions and policy making. We have many common interests and our countries face many common problems and goals. Addressing the tremendous scientific challenges of the Arctic requires such massive investment of manpower and resources that sharing efforts, data and working together on expeditions are in our mutual best interests.This issue presents a compilation of selected results on recent analyses conducted in the five-year (2009–2014) research term related to observational studies, model development and remote sensing applications of the Arctic Ocean, adjacent marginal seas, and the surrounding terrestrial regions. All of these studies are intended to provide a better understanding of how individual components and processes interact to form a complex and dynamic arctic system. Through these collaborations, Japanese and UAF Arctic researchers can achieve our goals of developing a quantitative understanding of the Arctic System.     

Late Cretaceous stratigraphy,sediments and structure: Gems of the Dorset and East Devon Coast World Heritage Site (Jurassic Coast), England

Extraordinary, long-distance litho-marker beds such as the Lewes and Shoreham Tubular Flints and associated marl seams and fossils, recognised in cliff exposures and cliff-fall boulders, are keys to unlocking the stratigraphy and tectonic structures in the Late Cretaceous of the Dorset and East Devon Coast World Heritage Site (Jurassic Coast). Durdle Cove is a special gem exposing the Lewes and Seaford Chalk stratigraphy where new marker beds are identified and sediments and tectonic structures provide clues to timing of movements that produced a Late Cretaceous pericline which grew into a Miocene monocline along the line of the underlying Purbeck Reverse Fault. During ‘inversion’ along this fault some Late Cretaceous Chalk formations were in part or completely ‘lost’ (e.g. Middle Turonian New Pit Chalk Formation) and others were condensed (e.g. Late Santonian and Early Campanian Newhaven Chalk Formation). Excavation of the A354 road cutting at the Lower Bincombe Farm, has greatly added to the stratigraphical records of Late Cretaceous fossils in South Dorset, especially Coniacian and Early Campanian inoceramid bivalves and the various stratigraphically specific forms of the Late Santonian to Early Campanian echinoid fossil Echinocorys scutata spp. not recorded before in this coastline. The very large bivalve fossil Platyceramus sp. provides clues to chalk sea-floor environments.     

Curricular changes in the Geology Department, University of Zimbabwe: towards a more vocational degree

Zimbabwe is a mineral-rich country with a long history of Earth Science Education. The establishment of a University Geology Department in 1960 allowed the country to produce its own earth science graduates. These graduates are readily absorbed by the mining industry and few are without work. Demand for places at the University is high and entry standards reflect this. Students enter the University after GCE A levels in three science subjects and most go on to graduate. Degree programmes include B.Sc. General in Geology (plus another science), B.Sc. Honours in Geology and M.Sc. in Exploration Geology and in Geophysics. The undergraduate curriculum is broad-based and increasingly vocationally orientated. A well-equipped building caters for relatively large student numbers and also houses analytical facilities used for research and teaching. Computers are used in teaching from the first year onwards. Staff are on average poorly qualified compared to other universities, but there is an impressive research element. The Department has good links with many overseas universities and external funding agencies play a strong supporting role. That said, financial constraints remain the greatest barrier to future development, although increasing links with the mining industry may cushion this.     

Bootstrap Calibration and Uncertainty Estimation of Downhole NMR Hydraulic Conductivity Estimates in an Unconsolidated Aquifer

Characterization of hydraulic conductivity (K) in aquifers is critical for evaluation, management, and remediation of groundwater resources. While estimates of K have been traditionally obtained using hydraulic tests over discrete intervals in wells, geophysical measurements are emerging as an alternative way to estimate this parameter. Nuclear magnetic resonance (NMR) logging, a technology once largely applied to characterization of deep consolidated rock petroleum reservoirs, is beginning to see use in near‐surface unconsolidated aquifers. Using a well‐known rock physics relationship—the Schlumberger Doll Research (SDR) equation—K and porosity can be estimated from NMR water content and relaxation time. Calibration of SDR parameters is necessary for this transformation because NMR relaxation properties are, in part, a function of magnetic mineralization and pore space geometry, which are locally variable quantities. Here, we present a statistically based method for calibrating SDR parameters that establishes a range for the estimated parameters and simultaneously estimates the uncertainty of the resulting K values. We used co‐located logging NMR and direct K measurements in an unconsolidated fluvial aquifer in Lawrence, Kansas, USA to demonstrate that K can be estimated using logging NMR to a similar level of uncertainty as with traditional direct hydraulic measurements in unconsolidated sediments under field conditions. Results of this study provide a benchmark for future calibrations of NMR to obtain K in unconsolidated sediments and suggest a method for evaluating uncertainty in both K and SDR parameter values.     

Hybrid analytical and finite element numerical modeling of mass and heat transport in fractured rocks with matrix diffusion

Quantification of mass and heat transport in fractured porous rocks is important to areas such as contaminant transport, storage and release in fractured rock aquifers, the migration and sorption of radioactive nuclides from waste depositories, and the characterization of engineered heat exchangers in the context of enhanced geothermal systems. The large difference between flow and transport characteristics in fractures and in the surrounding matrix rock means models of such systems are forced to make a number of simplifications. Analytical approaches assume a homogeneous system, numerical approaches address the scale at which a process is operating, but may lose individual important processes due to averaging considerations. Numerical stability criteria limit the contrasts possible in defining material properties. Here, a hybrid analytical–numerical method for transport modeling in fractured media is presented. This method combines a numerical model for flow and transport in a heterogeneous fracture and an analytical solution for matrix diffusion. By linking the two types of model, the advantages of both methods can be combined. The methodology as well as the mathematical background are developed, verified for simple geometries, and applied to fractures representing experimental field conditions in the Grimsel rock laboratory.