Diffusive and total oxygen uptake of deep-sea sediments in the eastern South Atlantic Ocean:in situ and laboratory measurements

Total O₂ uptake rates were measured by the benthic flux chamber lander ELINOR, and O₂ microprofiles were measured by the profiling lander PROFILUR in the eastern South Atlantic. Diffusive O₂ fluxes through the diffusive boundary layer and the depth distribution of O₂ consumption rates within the sediment were calculated from the obtained microprofiles. The depth integrated O₂ consumption rate agreed closely with the diffusive O₂ uptake at all stations. Total O₂ uptake was 1.2–4.2 times the diffusive O₂ uptake, and the difference correlated with the abundance of macrofauna in the sediment. Diffusive O₂ uptake and O₂-penetration depths correlated with the organic content of the sediments and exhibited an inverse correlation with water depth. Total and diffusive rates of in situ O₂ uptake were higher than previously published data for shelf and abyssal sediments in the Atlantic, but were comparable to rates from upwelling areas in the eastern Pacific. Laboratory measurements on recovered sediment cores showed lower O₂ penetration depths and higher diffusive uptake rates than in situ measurements. The differences increased with increasing water depth. We primarily ascribe this compression of O₂ profiles to a transiently increased temperature during recovery and enhanced microbial activity in decompressed sediment cores. Total O₂ uptake rates measured in the laboratory on macrofauna-rich stations were, in contrast, lower than those measured in situ because of underrepresentation and disturbance of the macrofauna.     

Calculated diffusion coefficients and the growth rate of olivine in a basalt magma

Concentration gradients in glass adjacent to skeletal olivines in a DSDP basalt have been examined by electron probe. The glass is depleted in Mg, Fe, and Cr and enriched in Si, Al, Na, and Ca relative to that far from olivine. Ionic diffusion coefficients for the glass compositions are calculated from temperature, ionic radius and melt viscosity, using the Stokes-Einstein relation. At 1170°C, the diffusion coefficient of Mg²⁺ ions in the basalt is 4·5.10^?9 cm²/s. Comparison with measured diffusion coefficients in a mugearite suggests this value may be 16 times too small. The concentration gradient data and the diffusion coefficients are used to calculate instantaneous olivine growth rates of 2–6.10^?7 cm/s. This is too slow for olivine to have grown in situ during quenching. Growth necessarily preceded emplacement such that the composition of the crystals plus the enclosing glass need not be that of a melt. The computed olivine growth rates are compatible with the rate of crystallization deduced for the Skaegaard intrusion.     

Archaean quartz arenites in the Canadian Shield: examples from the Superior and Churchill Provinces

Units of remarkably pure Archaean quartz arenite occur in the northwestern part of the Superior Province and in the northern terrane of the Western Churchill Province (Rae Province) of the Canadian Shield. In the Superior Province, silica-cemented quartz arenites of Archaean age are well preserved in several greenstone belts. The example from the Keeyask Lake sedimentary assemblage displays tabular–planar and trough cross-beds, ripple marks, reactivation surfaces and pebble lag deposits. In spite of penetrative deformation and greenschist-grade metamorphism, primary textures are extremely well preserved, showing framework grains to be very well rounded and sorted. The succession of Keeyask Lake quartz-arenite beds is overlain by siltstones containing small-scale stratiform, domal and columnar stromatolites. A shallow-marine environment of deposition is inferred. Detrital heavy minerals include pyrite, magnetite, zircon, tourmaline, apatite, sphene and topaz. In the northern part of the Western Churchill Province (Rae Province), Archaean quartz arenites occur in northeasterly trending belts where intense structural deformation has in most places obscured or obliterated primary textures and structures. This has led to speculation that some of these units are metachert or recrystallized vein quartz, but local preservation of primary textures and structures provides clear evidence of epiclastic origin. In the example described herein, quartz arenites of the Woodburn Lake Group display sparse occurrences of trough and tabular–planar cross-beds, channels, ripple marks and pebble lag deposits. Probable environments of deposition for these quartz arenites include fluvial systems and shallow-marine shelf settings. The occurrence of unequivocal quartz-arenite clasts in beds of intercalated conglomerate provides direct evidence of at least two episodes of accumulation of almost pure quartz sand. Thin sections and polished slabs reveal frameworks of clastic quartz grains with little to no matrix (now mainly muscovite), and rare detrital grains of accessory heavy minerals, predominantly zircon and opaque iron oxides. Pyrite and other sulphides have been introduced along fractures, but some intergranular sulphide grains may be of detrital origin. The principal source for the quartz arenites in both areas must have been quartz-rich granitoid rocks. Conditions of intense chemical weathering are indicated. The widespread occurrence of extremely mature quartz arenites throughout Archaean terranes of the Canadian Shield, and in other shields of the world, are suggestive of crustal stability during early Earth history. The association of quartz arenites and ultramafic rocks, uncharacteristic of younger terranes, is now recognized in many Archaean greenstone belts of the Canadian Shield.     

Vesta and the HED meteorites: Mid‐infrared modeling of minerals and their abundances

Abstract— We demonstrate that the use of an established spectral deconvolution algorithm with mid‐infrared spectral libraries of mineral separates of varying grain sizes is capable of identifying the known mineral compositions and abundances of a selection of howardite, eucrite, and diogenite (HED) meteorite samples. In addition, we apply the same technique to mid‐infrared spectral emissivity measurements of Vesta that have been obtained from Cornell's Mid‐Infrared Asteroid Spectroscopy (MIDAS) Survey and the Infrared Space Observatory (ISO). Each Vesta measurement was made over a different range of longitudes. Our spectral deconvolution results to the Vesta spectra corroborate that Vesta's surface is howardite or eucrite‐like in composition and heterogeneous across its surface. The spectral fits produced by the linear deconvolution algorithm yields good results for the HED samples of known composition, thus giving us a high degree of confidence that our results for Vesta are valid.     

Causes for the recent changes in cold- and heat-related mortality in England and Wales

Cold related mortality among people aged over 50 in England and Wales has decreased at a rate of 85 deaths per million population per year over the period 1976–2005. This trend is two orders of magnitude higher than the increase in heat-related mortality observed after 1976. Long term changes in temperature-related mortality may be linked to human activity, natural climatic forcings, or to adaptation of the population to a wider range of temperatures. Here we employ optimal detection, a formal statistical methodology, to carry out an end to end attribution analysis. We find that adaptation is a major influence on changing mortality rates. We also find that adaptation has prevented a significant increase in heat-related mortality and considerably enhanced a significant decrease in cold-related mortality. Our analysis suggests that in the absence of adaptation, the human influence on climate would have been the main contributor to increases in heat-related mortality and decreases in cold-related mortality.     

Sediment distribution and evolution of tidal deltas along a tide-dominated shoreline, Wachapreague, Virginia

Borings from the barrier island/lagoon system of the Eastern Shore of Virginia penetrated an unconformity which separates Pleistocene barrier island and offshore marine sediments from the overlying Holocene tidal delta and barrier island sediments. Offshore marine sediments and deposits within the flood-tidal delta (marsh, tidal flat-bay, inlet-mouth bar complex) are recognized on the basis of sediment color, composition, grain-size changes in the vertical sequence, presence of organic matter, and faunal suite. Subsurface data, historical records, and morphology of lateral accretion on barrier islands suggest that major inlets in the vicinity of Wachapreague have been relatively stable throughout Holocene time; they appear to be located where Pleistocene stream valleys previously existed. Holocene barrier islands apparently developed on drainage divide areas following post-Wisconsin transgression of the sea.

The initial phase of tidal delta development was characterized by vertically accreting, fan-shaped, inlet-mouth bars; tidal channels stabilized after bar crests had shoaled sufficiently for marsh to form. With landward progradation across the lagoon, sand-rich deposits graded laterally away from the inlets and vertically into clayey sand and silty clay of the tidal flat-bay and marsh environments.

Ebb inlet-mouth bars developed asymmetrically southward in response to littoral drift. Flood tidal deltas also built preferentially toward the south as indicated by: (1) sand distribution of the inlet-mouth bar complex; and (2) greater development of marsh south of the inlets.