Characterization of a major refractory component of marine dissolved organic matter

Refractory carboxyl-rich alicyclic molecules (CRAM) are characterized in marine dissolved organic matter (DOM) using nuclear magnetic resonance spectroscopy and ultrahigh resolution mass spectrometry. CRAM are distributed throughout the water column and are the most abundant components of deep ocean DOM ever characterized. CRAM are comprised of a complex mixture of carboxylated and fused alicyclic structures with a carboxyl-C:aliphatic-C ratio of 1:2 to 1:7. CRAM are expected to constitute a strong ligand for metal binding, and multiple coordination across cations could promote aggregation and marine gel formation thereby affecting CRAM reactivity and the bioavailability of nutrients and trace metals. It appears CRAM are ultimately derived from biomolecules with structural similarities to sterols and hopanoids. The occurrence of CRAM in freshwater and terrestrial environments seems likely, considering the global distribution of biomolecules and the similarities of biogeochemical processes among environments.     

Implications of the relationship between catchment vegetation type and the variability of annual runoff

The impact of changing catchment vegetation type on mean annual runoff has been known for some time, however, the impact on the variability of annual runoff has been established only recently. Differences in annual actual evapotranspiration between vegetation types and the potential effect of changing vegetation type on mean annual runoff and the variability of annual runoff are briefly reviewed. The magnitude of any change in the variability of annual runoff owing to a change in catchment vegetation type is related to the pre‐ and post‐change vegetation types and the seasonality of precipitation, assuming that the variability of annual precipitation remains constant throughout. Significant implications of the relationship between vegetation type and the variability of annual runoff are presented and discussed for water resource management, stream ecology and fluvial geomorphology. Copyright © 2002 John Wiley & Sons, Ltd.     

Anatomy of shelf deltas at the edge of a prograding Eocene shelf margin, Spitsbergen

Abstract Although shelf‐edge deltas are well‐imaged seismic features of Holocene and Pleistocene shelf margins, documented outcrop analogues of these important sand‐prone reservoirs are rare. The facies and stratigraphic architecture of an outcropping shelf‐edge delta system in the Eocene Battfjellet Formation, Spitsbergen, is presented here, as well as the implications of this delta system for the generation of sand‐prone, shelf‐margin clinoforms. The shelf‐edge deltas of the Battfjellet Formation on Litledalsfjellet and Høgsnyta produced a 3–5 × 15 km, shelf edge‐attached, slope apron (70 m of sandstones proximally, tapering to zero on the lower slope). The slope apron consists of distributary channel and mouth‐bar deposits in its shelf‐edge reaches, passing downslope to slope channels/chutes that fed turbiditic lobes and spillover sheets. In the transgressive phase of the slope apron, estuaries developed at the shelf edge, and these also produced minor lobes on the slope. The short‐headed mountainous rivers that drained the adjacent orogenic belt and fed the narrow shelf, and the shelf‐edge position of the discharging deltas, made an appropriate setting for the generation of hyperpycnal turbidity currents on the slope of the shelf margin. The abundance of organic matter and of coal fragments in the slope turbidites is consistent with this notion. Evidence that many of the slope turbidites were generated by sustained turbidity currents that waxed then waned includes the presence of scour surfaces and thick intervals of plane‐parallel laminae within turbidite beds in the slope channels, and thick spillover lobes with repetitive alternations of massive and flat‐laminated intervals. The examined shelf‐edge to slope system, now preserved mainly below the shelf break and dominated by sediment gravity‐flow deposits, has a threefold stratigraphic architecture: a lower, progradational part, in which the clinoforms have a slight downward‐directed trajectory; a thin aggradational zone; and an upper part in which clinoforms backstep up onto the shelf edge. A greatly increased density of erosional channels and chutes marks the regressive‐to‐transgressive turnaround within the slope apron, and this zone becomes an angular unconformity up near the shelf edge. This unconformity, with both subaerial and subaqueous components, is interpreted as a sequence boundary and developed by vigorous sand delivery and bypass across the shelf edge during the time interval of falling relative sea level. The studied shelf‐margin clinoforms accreted mostly during falling stage (sea level below the shelf edge), but the outer shelf later became estuarine as sea level became re‐established above the shelf edge.     

Electrons in feldspar II: a consideration of the influence of conduction band-tail states on luminescence processes

 Most natural feldspars contain many charged impurities, and display a range of bond angles, distributed about the ideal. These effects can lead to complications in the structure of the conduction band, giving rise to a tail of energy states (below the high-mobility conduction band) through which electrons can travel, but with reduced mobility: transport through these states is expected to be thermally activated. The purpose of this article is twofold. Firstly, we consider what kind of lattice perturbations could give rise to both localized and extended conduction band-tail states. Secondly, we consider what influence the band tails have on the luminescence properties of feldspar, where electrons travel through the sample prior to recombination. The work highlights the dominant role that 0.04–0.05-eV phonons play in both the luminescence excitation and emission processes of these materials. It also has relevance in the dating of feldspar sediments at elevated temperatures. Received: 11 May 2001 / Accepted: 6 September 2001     

Foreshocks and aftershocks of the M W = 7.1, 1992, earthquake in the Atrato region, Colombia

We study the October 18, M _W = 7.1, 1992 Atrato earthquake, and its foreshocks and aftershocks, which occurred in the Atrato valley, northwestern Colombia. The main shock was preceded by several foreshocksof which the M _W = 6.6, October 17 earthquacke was the largest. Inparticular, we examine foreshocks and aftershocks performing joint-hypocenter relocations using high quality Pn and Sn wave readingsfrom permanent regional networks. We observed a few hours prior to the main shock a sudden increase of foreshocks. Maybe this could be used as a predictor since foreshocks have been known for other major events in the region. Our locations align for 90 km with a trend of 5^° ±4^° in agreement with the Harvard CMT solution showing the faultplane trending 9^° to be the plane of rupture. In relation to theepicenter of the main shock, maximum intensities were located to thesouth, consistent with a rupture that traveled from north to south witha larger energy release in the south as suggested by an empirical Green'sfunction study (Li and Toksöz, 1993; Ammon et al., 1994). The boundarybetween the Panama and North Andes blocks has been placed close to thePanama-Colombia border as either a sharp boundary or a diffuse zone. TheAtrato earthquake, however, shows that the plate boundary between thePanama and North Andes microblocks is a diffuse deformation zone. Thiszone has a width of at least 2^° stretching from 78^°W to 76^°W. Quantification of earthquake moment release (during the past30 years) in this zone shows a similar amount of moment release in thewestern and eastern parts of this zone.     

Tiller recruitment and mortality in the dryland bunchgrass Eragrostis curvula as affected by defoliation intensity

A greenhouse experiment was conducted to investigate the effects of moderate (14 cm) vs. severe (7 cm) defoliation on tiller recruitment and mortality within the interior and on the perimeter of weeping lovegrass (Eragrostis curvula) tussocks. Tiller number per marked shoot within the interior was significantly greater in plants defoliated at 14-cm stubble height than at 7-cm stubble height (2·37 vs. 0·43, p<0·05) 28 weeks after defoliation; likewise, tiller number per marked shoot was also greater on the perimeter of tussocks in the higher stubble than the lower stubble defoliation treatment (5·10 vs. 2·03, p<0·05). Tiller natality increased significantly 4 weeks after defoliation except for tillers cut to 7-cm stubble height within the interior of tussocks where tiller natality reached a peak at 4·5 weeks after defoliation. During the later stages of canopy development, tiller numbers per marked shoot gradually declined as tiller mortality increased. Tillers began senescing 13 weeks after defoliation, and the senescence rate was 52% greater in the 7-cm stubble height treatment than in the 14-cm stubble height treatment (2·33 vs. 1·53, p<0·0001). Within the interior of tussocks, number of the marked tillers more than doubled under the 14-cm stubble height treatment, whereas the plants lost 57% of the monitored tillers under the 7-cm stubble height treatment. We concluded that the central dieback process in weeping lovegrass is accelerated by severe defoliation.     

Scaling effects on modeled surface energy-balance components using the NOAH-OSU land surface model

As surface exchange processes are highly non-linear and heterogeneous in space and time, it is important to know the appropriate scale for the reasonable prediction of these exchange processes. For example, the explicit representation of surface variability has been vital in predicting mesoscale weather events such as late-afternoon thunderstorms initiated by latent heat exchanges in mid-latitude regions of the continental United States. This study was undertaken to examine the effects of different spatial scales of input data on modeled fluxes, so as to better understand the resolution needed for accurate modeling. A statistical procedure was followed to select two cells from the Southern Great Plains 1997 hydrology experiment region, each 20 km×20 km, representing the most homogeneous and the most heterogeneous surface conditions (based on soil and vegetation) within the study region. The NOAH-OSU (Oregon State University) Land Surface Model (LSM) was employed to estimate surface energy fluxes. Three scales of study (200 m, 2 and 20 km) were considered in order to investigate the impacts of the aggregation of input data, especially soil and vegetation inputs, on the model output. Model results of net radiation and latent, sensible and ground heat fluxes were compared for the three scales. For the heterogeneous area, the model output at the 20-km resolution showed some differences when compared with the 200-m and 2-km resolutions. This was more pronounced in latent heat (12% decrease), sensible heat (22% increase), and ground heat flux (44% increase) estimation than in net radiation. The scaling effects were much less for the relatively homogeneous land area with 5% increase in sensible heat and 4% decrease in ground heat flux estimation. All of the model outputs for the 2- and 20-km resolutions were in close agreement. The results suggested that, for this study region, soils and vegetation input resolution of about 2 km should be chosen for realistic modeling of surface exchange processes. This resolution was sufficient to capture the effects of sub-grid scale heterogeneity, while avoiding the data and computational difficulties associated with higher spatial resolutions.