Applications of a two-flow model for remote sensing of substances in water

A version of the two-flow radiative transfer model is presented as a simple method to study the relationship between substances in water and the backscattered radiation field. It is shown that under the assumption of a diffuse radiative input into a water body, the irradiance attenuation coefficient k can be regarded as an inherent property. A cuvette system is presented which allows one to measure and calculate the attenuation coefficient k, the absorption coefficient a and the backscattering coefficient Bb of various substances. The model can be used to check the applicability of a remote sensing technique for a specific research area and for specific parameters, and to estimate the expected accuracy, and the signal depth. The inversion of the model can be applied as a technique to estimate concentrations in water from the backscattered radiation. The critical assumption of a diffuse radiative input and transfer, which has to be made when using the model for natural conditions, is discussed.The research work was supported by the Deutsche Forschungsgemeinschaft.     

U/Pb and Pb/Pb zircon ages for arc-related intrusions of the Bolu Massif (W Pontides, NW Turkey): evidence for Late Precambrian (Cadomian) age

We present new U/Pb and Pb/Pb radiometric age data from two tectono-stratigraphic units of the regionally extensive Bolu Massif, in the W Pontides (İstanbul Fragment), N Turkey. A structurally lower unit (Sünnice Group) is cut by small meta-granitic intrusions, whereas the structurally higher unit comprises meta-volcanic rocks (Çaşurtepe Fm) cut by meta-granitic plutons (Tüllükiriş and Kapıkaya plutons). U/Pb single-crystal dating of zircons from the Kapıkaya Pluton yielded a concordant cluster, with a mean ²³⁸U/²⁰⁶Pb age of 565.3 ± 1.9 Ma. Zircons from the Tüllükiriş Pluton (affected by Pb loss) gave a ²⁰⁷Pb/²⁰⁶Pb age of 576 ± 6 Ma age (Late Precambrian). Small meta-granitic intrusions cutting the Sünnice Group yielded a less precise ²⁰⁷Pb/²⁰⁶Pb age of 262 ± 19 Ma (Early Permian). The older ages from the Bolu Massif confirm the existence of latest Precambrian arc magmatism related to subduction of a Cadomian ocean. We infer that the Bolu Massif represents a fragment of a Cadomian active margin. Cadomian orogenic units were dispersed as exotic terranes throughout the Variscan and Tethyan orogens, and the Bolu Massif probably reached its present position prior to latest Palaeozoic time. Our dating results also confirm that NW Turkey was affected by Hercynian magmatism related to subduction of Palaeotethys, as inferred for other areas of the Pontides.     

The physical state of pore water of na smectite used as barrier component

The molecules constituting the first hydrate layers on montmorillonite crystal platelets appear to be characterized by preferred orientation and, depending on the exchangeable cation, by an ice-like configuration. Such organized interlamellar water is concluded to contribute to the high swelling pressure and shear resistance, as well as to the very low hydraulic conductivity at high clay bulk densities. At low densities the parallel arrangement of the lamellae alters to edge-to-face associations and the fraction of free water increases. However, even at very low densities the homogeneity of the clay gel still offers very tortuous passages to flowing water, which is manifested by a very low hydraulic conductivity.     

Refining the timing of eclogite metamorphism: a geochemical,petrological, Sm-Nd and U-Pb case study from the Pohorje Mountains,Slovenia (Eastern Alps)

High-pressure metamorphism in the Pohorje Mountains of Slovenia (Austroalpine unit, Eastern Alps) affected N-MORB type metabasic and metapelitic lithologies. Thermodynamic calculations and equilibrium phase diagrams of kyanite–phengite-bearing eclogites reveal PT conditions of >2.1 GPa at T<750°C, but within the stability field of quartz. Metapelitic eclogite country rocks contain the assemblage garnet + phengite + kyanite + quartz, for which calculated peak pressure conditions are in good agreement with results obtained from eclogite samples. The eclogites contain a single population of spherical zircon with a low Th/U ratio. Combined constraints on the age of metamorphism come from U/Pb zircon as well as garnet–whole rock and mineral–mineral Sm-Nd analyses from eclogites. A coherent cluster of single zircon analyses yields a ²⁰⁶Pb/²³⁸U age of 90.7±1.0 Ma that is in good agreement with results from Sm-Nd garnet–whole rock regression of 90.7±3.9 and 90.1±2.0 Ma (εNd: +8) for two eclogite samples. The agreement between U-Pb and Sm-Nd age data strongly suggests an age of approximately 90 Ma for the pressure peak of the eclogites in the Pohorje Mountains. The presence of garnet, omphacite and quartz inclusions in unfractured zircon indicates high-pressure rather than ultrahigh pressure conditions. The analysed metapelite sample yields a Sm-Nd garnet–whole rock scatterchron age of 97±15 Ma. These data probably support a single P-T loop for mafic and pelitic lithologies of the Pohorje area and a late Cretaceous high-pressure event that affected the entire easternmost Austroalpine basement including the Koralpe and Saualpe eclogite type locality in the course of the complex collision of the Apulian microplate and Europe.     

North Atlantic climate impact on early late‐glacial climate oscillations in the south‐eastern Alps inferred from a multi‐proxy lake sediment record

High‐resolution multi‐proxy analyses of a sediment core section from Lake Jeserzersee (Saissersee) in the piedmont lobe of the Würmian Drau glacier (Carinthia, Austria) reveal pronounced climatic oscillations during the early late glacial (ca. 18.5–16.0k cal a BP). Diatom‐inferred epilimnetic summer water temperatures show a close correspondence with temperature reconstructions from the adjacent Lake Längsee record and, on a hemispheric scale, with fluctuations of ice‐rafted debris in the North Atlantic. This suggests that North Atlantic climate triggered summer climate variability in the Alps during the early late glacial. The expansion of pine (mainly dwarf pine) between ca. 18.5 and 18.1k cal a BP indicates warming during the so‐called ‘Längsee oscillation’. The subsequent stepwise climate deterioration between ca. 18.1 and 17.6k cal a BP culminated in a tripartite cold period between ca. 17.6 and 16.9k cal a BP with diatom‐inferred summer water temperatures 8.5–10 °C below modern values and a shift from wet to dry conditions. This period probably coincides with a major Alpine glacier advance termed the Gschnitz stadial. A warmer interval between ca. 16.9 and 16.4k cal a BP separates this cold phase from a second, shorter and less pronounced cold phase between ca. 16.4 and 16.0k cal a BP, which is thought to correlate with the Clavadel/Senders glacier advance in the Alps. The following temperature increase, coupled with wet (probably snow‐rich) conditions, caused the expansion of birch during the transition period to the late glacial interstadial. Copyright © 2011 John Wiley & Sons, Ltd.     

ESR dating of palaeolithic calcite: A comparison between powder and monocrystal spectra with thermal annealing

Evolution of ESR spectra with thermal annealing at different temperatures is studied for a monocrystal calcite taken in the Orgnac III site. Up to 20 ESR lines are recognized from the angular dependence of these lines. These lines are compared with the ESR lines observed for powder and rotating monocrystal calcites.The h1 line (g = 2.0057) and h3 line (g = 2.0007) are isotropic or nearly isotropic and are due to the electrons trapped in the amorphous region formed by fission tracks or alpha-ray recoil nuclei. The h2 line (g = 2.0021) is a composite of several different lines.     

Remote sensing of substances in water

Remote sensing of water colour and its application to the mapping of pigments, suspended matter and other substances by means of airborne and spaceborne sensors is discussed. After an introduction to the physical process involved, the methods for a quantitative interpretation especially of CZCS data are indicated. Applications towards the monitoring of coastal pollution, of algae blooms and of dynamic processes are shown by means of selected examples. Multispectral scanner and imaging spectrometer technologies are discussed with special reference to NASA's Earth Observation System and ESA's Earth Observation Programme.     

Cyclotella-taxa (Bacillariophyceae) in lakes of the Alpine region and their relationship to environmental variables

Surface sediment diatom assemblages for 86 Alpine lakes were analysed focusing on the dominant genusCyclotella and corresponding environmental data. The range of morphological variability of theCyclotella bodanica/radiosa, C. distinguenda, C. ocellata, C. comensis andC. stelligera complexes was documented. Significance tests included in the canonical correspondence analysis (CCA) indicated that total phosphorus, conductivity and surface water temperature were significantly correlated withCyclotella taxa assemblage distribution. Numerical species optima and tolerances were calculated in respect to these significant variables using weighted averaging (WA) regression and calibration. CCA and WA were able to provide information about the environmental preferences of the various morphotypes observed.