Inclined lidar observations of boundary layer aerosol particles above the Kongsfjord,Svalbard

An inclined lidar with vertical resolution of 0.4 m was used for detailed boundary layer studies and to link observations at Zeppelin Mountain (474 m) and Ny-Ålesund, Svalbard. We report on the observation of aerosol layers directly above the Kongsfjord. On 29 April 2007, a layer of enhanced backscatter was observed in the lowest 25 m above the open water surface. The low depolarization ratio indicated spherical particles. In the afternoon, this layer disappeared. The ultrafine particle concentration at Zeppelin and Corbel station (close to the Kongsfjord) was low. On 1 May 2007, a drying process in the boundary layer was observed. In the morning, the atmosphere up to Zeppelin Mountain showed enhanced values of the backscatter coefficient. Around noon, the top of the highly reflecting boundary layer decreased from 350 to 250 m. The top of the boundary layer observed by lidar was confirmed by radiosonde data.     

Conditional heavy-tail behavior with applications to precipitation and river flow extremes

This article deals with the right-tail behavior of a response distribution \(F_Y\) conditional on a regressor vector \({\mathbf {X}}={\mathbf {x}}\) restricted to the heavy-tailed case of Pareto-type conditional distributions \(F_Y(y|\ {\mathbf {x}})=P(Y\le y|\ {\mathbf {X}}={\mathbf {x}})\), with heaviness of the right tail characterized by the conditional extreme value index \(\gamma ({\mathbf {x}})>0\). We particularly focus on testing the hypothesis \({\mathscr {H}}_{0,tail}:\ \gamma ({\mathbf {x}})=\gamma _0\) of constant tail behavior for some \(\gamma _0>0\) and all possible \({\mathbf {x}}\). When considering \({\mathbf {x}}\) as a time index, the term trend analysis is commonly used. In the recent past several such trend analyses in extreme value data have been published, mostly focusing on time-varying modeling of location or scale parameters of the response distribution. In many such environmental studies a simple test against trend based on Kendall’s tau statistic is applied. This test is powerful when the center of the conditional distribution \(F_Y(y|{\mathbf {x}})\) changes monotonically in \({\mathbf {x}}\), for instance, in a simple location model \(\mu ({\mathbf {x}})=\mu _0+x\cdot \mu _1\), \({\mathbf {x}}=(1,x)'\), but the test is rather insensitive against monotonic tail behavior, say, \(\gamma ({\mathbf {x}})=\eta _0+x\cdot \eta _1\). This has to be considered, since for many environmental applications the main interest is on the tail rather than the center of a distribution. Our work is motivated by this problem and it is our goal to demonstrate the opportunities and the limits of detecting and estimating non-constant conditional heavy-tail behavior with regard to applications from hydrology. We present and compare four different procedures by simulations and illustrate our findings on real data from hydrology: weekly maxima of hourly precipitation from France and monthly maximal river flows from Germany.     

Similarity-based approaches in hydrogeology: proposal of a new concept for data-scarce groundwater resource characterization and prediction

Hydrogeology Journal - A new concept is proposed for describing, analysing and predicting the dynamic behaviour of groundwater resources based on classification and similarity. The concept makes...     

OH defects in quartz in the system quartz–albite–water and granite–water between 5 and 25?kbar

The incorporation of OH defects in quartz from the systems quartz–water, quartz–albite–water and granite–water at pressures between 5 and 25?kbar and temperatures between 800 and 1,000?°C was investigated by IR spectroscopy. The two most important OH absorption features can be assigned to hydrogarnet defects (absorption band at 3,585?cm^?1) and coupled substitutions involving Al³⁺ (Al–H defects, absorption bands at 3,310, 3,378 and 3,430?cm^?1). Al incorporation in quartz is controlled by mineral/melt partitioning (D _Al ^Qz/Melt ?=?0.01) and exhibits a negative pressure dependence. This trend is not clearly reflected by the concentration of Al–H defects, which shows positive deviations from the theoretical 1:1 correlation of Al/H for some samples. In contrast to the Al–H defects, formation of hydrogarnet defects appears to be positively correlated to pressure and water activity, and may be used a petrological indicator. The overall water concentration exhibits only minor changes with pressure and temperature, but a clear correlation of water activity (controlled by various amounts of dissolved salts) and hydrogarnet substitution could be established.     

Analytical model for screening potential CO<Subscript>2</Subscript> repositories

Assessing potential repositories for geologic sequestration of carbon dioxide using numerical models can be complicated, costly, and time-consuming, especially when faced with the challenge of selecting a repository from a multitude of potential repositories. This paper presents a set of simple analytical equations (model), based on the work of previous researchers, that could be used to evaluate the suitability of candidate repositories for subsurface sequestration of carbon dioxide. We considered the injection of carbon dioxide at a constant rate into a confined saline aquifer via a fully perforated vertical injection well. The validity of the analytical model was assessed via comparison with the TOUGH2 numerical model. The metrics used in comparing the two models include (1) spatial variations in formation pressure and (2) vertically integrated brine saturation profile. The analytical model and TOUGH2 show excellent agreement in their results when similar input conditions and assumptions are applied in both. The analytical model neglects capillary pressure and the pressure dependence of fluid properties. However, simulations in TOUGH2 indicate that little error is introduced by these simplifications. Sensitivity studies indicate that the agreement between the analytical model and TOUGH2 depends strongly on (1) the residual brine saturation, (2) the difference in density between carbon dioxide and resident brine (buoyancy), and (3) the relationship between relative permeability and brine saturation. The results achieved suggest that the analytical model is valid when the relationship between relative permeability and brine saturation is linear or quasi-linear and when the irreducible saturation of brine is zero or very small.     

Stress anisotropy in natural debris flows during impacting a monitoring structure

Landslides - The frictional resistance of rock and debris is supposed to induce stress anisotropy in the unsteady, non-uniform flow of gravitational mass flows, including debris flows. Though...     

Numerical simulation of a stratigraphic model

A multi-lithology diffusive stratigraphic model is considered, which simulates at large scales in space and time the infill of sedimentary basins governed by the interaction between tectonics displacements, eustatic variations, sediment supply, and sediment transport laws. The model accounts for the mass conservation of each sediment lithology resulting in a mixed parabolic, hyperbolic system of partial differential equations (PDEs) for the lithology concentrations and the sediment thickness. It also takes into account a limit on the rock alteration velocity modeled as a unilaterality constraint. To obtain a robust, fast, and accurate simulation, fully and semi-implicit finite volume discre tization schemes are derived for which the existence of stable solutions is proved. Then, the set of nonlinear equations is solved using a Newton algorithm adapted to the unilaterality constraint, and preconditioning strategies are defined for the solution of the linear system at each Newton iteration. They are based on an algebraic approximate decoupling of the sediment thickness and the concentration variables as well as on a proper preconditioning of each variable. These algorithms are studied and compared in terms of robustness, scalability, and efficiency on two real basin test cases.     

ESR dating of palaeolithic calcite: A comparison between powder and monocrystal spectra with thermal annealing

Evolution of ESR spectra with thermal annealing at different temperatures is studied for a monocrystal calcite taken in the Orgnac III site. Up to 20 ESR lines are recognized from the angular dependence of these lines. These lines are compared with the ESR lines observed for powder and rotating monocrystal calcites.The h1 line (g = 2.0057) and h3 line (g = 2.0007) are isotropic or nearly isotropic and are due to the electrons trapped in the amorphous region formed by fission tracks or alpha-ray recoil nuclei. The h2 line (g = 2.0021) is a composite of several different lines.     

Refining the timing of eclogite metamorphism: a geochemical,petrological, Sm-Nd and U-Pb case study from the Pohorje Mountains,Slovenia (Eastern Alps)

High-pressure metamorphism in the Pohorje Mountains of Slovenia (Austroalpine unit, Eastern Alps) affected N-MORB type metabasic and metapelitic lithologies. Thermodynamic calculations and equilibrium phase diagrams of kyanite–phengite-bearing eclogites reveal PT conditions of >2.1 GPa at T<750°C, but within the stability field of quartz. Metapelitic eclogite country rocks contain the assemblage garnet + phengite + kyanite + quartz, for which calculated peak pressure conditions are in good agreement with results obtained from eclogite samples. The eclogites contain a single population of spherical zircon with a low Th/U ratio. Combined constraints on the age of metamorphism come from U/Pb zircon as well as garnet–whole rock and mineral–mineral Sm-Nd analyses from eclogites. A coherent cluster of single zircon analyses yields a ²⁰⁶Pb/²³⁸U age of 90.7±1.0 Ma that is in good agreement with results from Sm-Nd garnet–whole rock regression of 90.7±3.9 and 90.1±2.0 Ma (εNd: +8) for two eclogite samples. The agreement between U-Pb and Sm-Nd age data strongly suggests an age of approximately 90 Ma for the pressure peak of the eclogites in the Pohorje Mountains. The presence of garnet, omphacite and quartz inclusions in unfractured zircon indicates high-pressure rather than ultrahigh pressure conditions. The analysed metapelite sample yields a Sm-Nd garnet–whole rock scatterchron age of 97±15 Ma. These data probably support a single P-T loop for mafic and pelitic lithologies of the Pohorje area and a late Cretaceous high-pressure event that affected the entire easternmost Austroalpine basement including the Koralpe and Saualpe eclogite type locality in the course of the complex collision of the Apulian microplate and Europe.