Pathways of manganese in an open estuarine system

The distribution of Mn was examined in the bottom sediments and water column (suspended paniculate matter) of the Laurentian Trough. Gulf of St. Lawrence. A characteristic profile of Mn with depth in the sediment consisted of a Mn-enriched surface oxidized zone, less than 20 mm thick, and a Mn-depleted subsurface reducing zone. A subsurface Mn maximum occurred within the oxidized zone. Below this maximum the concentration dropped sharply to nearly constant residual levels in the reducing zone. The accumulating estuarine sediments are deficient in Mn compared to the river input of suspended matter and are definitely not the ultimate sink for manganese. Manganese escapes from the sediment by diffusion and resuspension, forming Mn-enriched, fine-grained particles which are flushed out in the estuarine circulation. 5.0 × 10⁹gyr^?1 of Mn, or 50% more than the river input of dissolved Mn. are exported to the open ocean. In spite of the efficient mobilization and export of Mn, the quantity exported is a small fraction (0.2%) of the total flux to the deep-sea sediments. This is related to the low levels of paniculate matter transported by the St. Lawrence River. The export phénomenon, however, is probably true of many coastal regions of muddy sediments and thus has interesting implications for the oceanic budget of Mn.     

Titaniferous phlogopites from the leucite lamproites of the West Kimberley area,Western Australia

Phlogopites in the wolgidites, fitzroyites and cedricites (leucite lamproites) of the West Kimberley area range in composition from titaniferous phlogopite to titaniferous tetraferriphlogopite. Two distinct compositional trends are present. In wolgidites micas are characterized by strong total iron enrichment, moderate Al and Mg depletion and little enrichment in tetrahedral ferric iron. Micas in fitzroyites and cedricites are characterized by strong depletion in Al and strong enrichment in tetrahedral ferric iron at approximately constant Mg contents. Individual centers of fitzroyite intrusion are characterized by distinct mica TiO₂ contents. The phlogopite compositional trends at low pressures are very different to those of kimberlite micas. An origin of these lamproites involving differentiation of a kimberlitic magma is considered unlikely.     

The composition and origin of metal in howardites

Howardites can be divided into two main groups, Ni-rich (>350ppm Ni) and Ni-poor (<150ppm Ni). In the Ni-rich group Ni occurs principally in metal grains associated with melt rocks and is largely derived from projectiles which caused the melting. The metal in Bununu, Kapoeta and Malvern melt rocks plots in the meteoritic Ni-Co range and in Bununu and Kapoeta is enriched in P. By contrast, most metal grains in primary lithic and crystal clasts in howardites are Ni-poor and plot mainly in the composition field of pristine lunar anorthosite metal. However, there are variations in the abundance and exact composition of primary metal from howardite to howardite and each therefore represents a discrete source region. The matrix metal in Bholgati, Bununu, and Kapoeta shows the diversity of compositions expected in a polymict breccia, with compositions plotting in and between the anorthositic and meteoritic Ni-Co fields. Other howardites show a more limited range of matrix metal compositions, because of limited metal-bearing clasts.Petersburg differs from other howardites in several ways. The metal in primary clasts has a unique $\text{Ni}\text{Co}$ ratio of about 40, which indicates derivation from a different reservoir from other howardite primary clasts. The metal in the matrix consists of large grains intergrown with silicates with compositions clustering tightly at 3.3% Ni, 0.2% Co. This is interpreted as equilibration, possibly as the result of deeper burial for Petersburg than for other howardites.     

An analysis of the Chow-Kulandaiswamy GHS model

The Chow-Kulandaiswamy general hydrologic system (GHS) model is revisited. Based on a mathematical study by Singh and McCann the GHS model is simplified. Explicit solutions are obtained for special cases which can satisfactorily determine watershed surface runoff response due to given rainfall excess. A rational criterion is developed to determine the number of derivative terms to be retained in the model. In order to determine the coefficients in the GHS model the method of moments is proposed. Criteria are developed to determine complex roots and oscillations for these coefficients. By analysing Chow-Kulandaiswamy's results it is found that in a majority of cases which they studied roots are complex. Moreover, for the cases which have complex roots, a majority of the solutions oscillate. A brief sensitivity analysis of the GHS model is performed with regard to: (a) its leading coefficient, and (b) the order of the differential equation. Finally, the peak characteristics are specified for the second order case and their qualitative properties are shown for the third order case.     

Cretaceous and Paleogene geologic history of coastal Ecuador

Following a general review of the Cretaceous and Paleogene geology of Ecuador, we propose a geologic history from early Cretaceous through Oligocene time with emphasis on the coastal part of the country that is based on the interpretive interaction of three oceanic plates (the Bolívar, proto-Nazca, and Nazca) and the continental South American plate. The proposed history invokes large lateral displacements, the intervention of the previously unrecognized Bolívar plate, the development of three successive subduction zones, the formation of a distant oceanic island arc and its subsequent collision with the South American plate, the emplacement of a major olistostrome complex, and an intricate record of displacement on a currently inactive transform fault. The proposed history offers a viable solution to four major problems of the geology of coastal Ecuador.

---

Zusammenfassung Aus der Kreide- und Paläogen-Geschichte Ecuadors läßt sich die Entwicklung der Küstenregion ableiten. Sie wird vom Zusammenwirken von drei ozeanischen Platten (Bolivar, Proto-Nazca und Nazca) und der kontinentalen Platte Südamerikas bestimmt. Die Entwicklung umfaßt ausgedehnte Seitenverschiebungen, das Auftreten einer bisher nicht erkannten Bolivar-Platte, die Anlage von drei aufeinanderfolgenden Subduktionszonen, die Bildung eines Inselbogens und die folgende Kollision mit der Südamerikanischen Platte, die Ablagerung eines großen Olisthostrom-Komplexes und die Verschiebungen entlang einer heute inaktiven Transform-Verwerfung. Damit sind eine Reihe von Problemen der Geologie des Küstenabschnittes Ecuadors gelöst.

---

Résumé Passant en revue la géologie de l'Equateur au Crétacique et Paléogène, les auteurs proposent une histoire géologique allant depuis le Crétacique inférieur à l'Oligocène en mettant l'accent sur la région cÔtière, et en se basant sur l'interaction de trois plaques océaniques (bolivienne, proto-Nasca et Nasca) et de la plaque continentale de l'Amérique du Sud. L'histoire proposée fait appel à de grands déplacements, à l'intervention de la plaque bolivienne non reconnue antérieurement, au développement de trois zones de subduction successives, à la formation d'une guirlande d'Îles océaniques distante et sa collision subséquente avec la plaque de l'Amérique du Sud, à la mise en place d'un grand complexe olistostromique et à un déplacement sur une faille transformante inactive. L'histoire proposée apporte une solution viable à quatre problèmes de la géologie de la Région cÔtière de l'Equateur.

---

. (, protoNazca Nazca) . : , , , , , Olistostrome . .

---

---

Contribution No. 6 A, Departamento de Geología, Escuela Politécnica Nacional, Quito, Ecuador.     

The respective effects of water vapor and temperature on the turbulent fluxes of sensible and latent heat

Various aspects of the Brook correction for the effects of moisture fluctuations or gradients on atmospheric specific heat and, consequently, on the vertical flux of sensible heat are discussed, and additional forms of the complete and approximate equations are derived. Corollary expressions for the influence of temperature fluctuations or gradients on vertical latent heat flux are presented. Errors due to neglecting these temperature and moisture effects on the respective fluxes are compared in terms of the Bowen ratio. Either of these normally neglected effects can change the direction (sign) and very substantially affect the magnitude of the corresponding flux. The effects sometimes compensate in the total, sensible plus latent, heat flux. Calculations include practical examples from the very different climates of the tropical Atlantic Ocean and the Great Plains of Nebraska.     

Tectonic pattern of the Azores spreading centre and triple junction

The major tectonic elements of the Azores triple junction have been mapped using long-range side-scan sonar. The data enable the Mid-Atlantic Ridge axis to be located with a precision of a few kilometres. Major faults and other tectonic and volcanic elements of the ridge maintain their regional trend of 010° to 020° past the triple junction area. There is no oblique spreading, and only minor transform offsets of the Mid-Atlantic Ridge occur here. The main effect of the triple junction or Azores hot spot is to diminish the amplitude of the median valley to 200 m or less. There is no axial high: a topographic high seen on several profiles is located to the east of the Mid-Atlantic Ridge spreading axis and does not appear to have any fundamental significance.The third arm of the triple junction includes the Azores srreading centre which appears to have developed as a series of en echelon rifted basins (the Terceira Rift) extending from Formigas Trough at 36.8°N, 24.5°W to a point near 39.3°N, 28.8°W. There are indications that recent activity in the spreading centre may be concentrated in a series of ridges which flank the older rifted basins. Until recently the northwest end of the Terceira Rift was connected to the Mid-Atlantic Ridge axis either directly at an RRR junction, or via a transform fault. The triple junction has probably moved south during the last 6 Ma to a positin on the Mid-Atlantic Ridge near 38.7°N.Initiation of the Azores spreading centre may have occurred during the 36 Ma B.P. rearrangement of poles, with an RFF triple junction north from the East Azores fracture zone to the North Azores fracture zone and transferring a wedge of European plate to the African plate.The tectonic elements revealed by this study are in good agreement with inferred earthquake mechanisms and with the RM2 plate tectonic model of Minster and Jordan, but east-west motion between North America and Africa does not seem to be compatible with the other motions at the triple junction unless it is of very recent (2>3 Ma) origin.     

Uranium and copper exploration by nearshore lake sediment geochemistry, Kaipokok region of Labrador

Uranium and copper concentrations were determined on 184 sediment samples collected systematically arount the periphery of 24 lakes in the Kaipokok region of Labrador. The results allowed us to define several zones across glacial drift and lake-covered terrain which are enriched in these elements and which warrant further exploration. Some zones are extensions of known U and Cu mineralization, but others had not previously been found.This survey demonstrates that systematic nearshore lake sediment sampling and geochemical analysis is an informative method of mineral exploration which can be used as a follow-up to reconnaissance level sampling.     

Rare earth element geochemistry of potassic lavas from the Birunga and Toro-Ankole regions of Uganda,Africa

Neutron activation determination of La, Ce, Sm, Eu, Tb, Yb, Lu, Ta, Hf, Sc, Co and Th in potassic lavas from the Birunga and Toro-Ankole regions show that the rocks are characterized by high rare earth element (REE) contents (161–754 ppm) and form two groups based upon differing La/Yb ratios. One group is made up of katungite, ugandite and mafurite with La/Yb =146–312, and the other of rocks of the leucitite and phonolitic tephrite series, La/Yb =30–56. The trace element content of the ugandite group is similar to that of kimberlites. The data do not indicate any trends of differentiation or simple relationships between the two groups of rocks, although katungite is unlikely to be parental to rocks of lower La/Yb ratios. It is unlikely that in terms of La/Yb ratios that partial melting of mica-garnet-lherzolite mantle can form katungite because of the very small amounts of partial melting required (0.2%), although the La/Yb ratios of 150–200 (ugandites, mafurites) and 30–60 (leucitites, phonolitic tephrites) can be accounted for by 0.3–1.5% and 1–9% melting respectively, if the REE are then concentrated without further La and Yb fractionation. Partial melting of mantle which has been metasomatized by alkaline earths and REE bearing fluids or mixing of carbonatite and nephelenite are also compatable with the observed geochemistry of the lavas. It is considered that gas transfer processes which selectively enrich the light REE may have obscured REE evidence pertaining to early partial melting and/or differentiation processes and therefore that REE geochemistry is of little use in determining the petrogenetic processes involved in the formation of potassic lavas.