Increasing organic pollution in Kingston Harbour,Jamaica

Kingston Harbour is a multi-purpose resource with more than half a million people and a variety of industries on its shores. Primary treated domestic sewage, raw industrial waste and run-off from agricultural land discharge into the bay. Successive surveys since 1968 show a progressive deterioration and the urgent need for a reduction of organic pollution if the benthic fauna is not to be destroyed.     

Past and present glaciological responses to climate in eastern Baffin Island

Much of Baffin Island is close to the modern glaciation limit and climatic changes within the last decade are already being reflected in snow cover extent. Statistical analysis of glacierized and ice-free corries indicates that changes in direct solar radiation due to astronomical factors are inadequate to account for glacierization of those at present ice-free. These and other sources of evidence demonstrate the need for augmented winter snowfall in order to increase the extent of glacierization. The pattern of glacial history in this area is for maximum ice extent during the early glacial phase (>68,000, <137,000 BP), folfxlowed by a reduction in ice volume during the cold pleniglacial (>24,000, < 68,000 BP) and then a limited late glacial advance (the Cockburn Stade, ca. 8,000 BP) due to increased precipitation. The Barnes Ice Cap did not disappear in the Holocene as it did in the last interglacial. The area is highly suitable for long-term monitoring of climatic change and glacial response.     

Multivariate analyses of crater parameters and the classification of craters

Multivariate analyses were performed on certain linear dimensions of six genetic types of craters. A total of 320 craters, consisting of laboratory fluidization craters, craters formed by chemical and nuclear explosives, terrestrial maars and other volcanic craters, and terrestrial meteorite impact craters, authenticated and probable, were analyzed in the first data set in terms of their mean rim crest diameter (D _r), mean interior relief (R _i), rim height (R _e), and mean exterior rim width (W _e ). The second data set contained an additional 91 terrestrial craters of which 19 were of experimental percussive impact and 28 of volcanic collapse origin, and which was analyzed in terms ofD _r,R _i, andR _e. Principal component analyses were performed on the six genetic types of craters; 90% of the variation in the variables can be accounted for by two components. 99% of the variation in the craters formed by chemical and nuclear explosives is explained by the first component alone. Classification using the CLUS procedure (Rubin and Friedman, 1967) indicates an optimum number of two groups; the main difference between the groups was the presence or absence of rims. The rimmed group of craters could, if desired, be subdivided on the basis of the dimension of the rim crest diameter. Several small rimless craters were classified as rimmed craters, this is believed to have resulted from the small difference in the dimension of their rim crest diameter to rim height, as contrasted with the larger rimless craters; thus, this distinction may also be size dependent. No evidence was found to support an exogenic-endogenic classification scheme of craters, with respect to the variables measured.     

The infrared spectrum of Rhea

A new infrared spectrum of the leading side of Rhea is presented in the 0.65- to 2.5 μm region with 1.5% spectral resolution and 3 to 5% data precision. Water ice absorptions previously identified at 2.02, 1.65, and 1.55 μm are confirmed and more precisely defined. The 1.25-μm water ice absorption is identified for the first time and the 1.04-μm water ice absorption is probably also present. The spectrum of the leading side of Rhea is very similar to the spectrum of the leading side of Ganymede in the 0.6- to 2.5-μm region. The Rhea spectrum is also very similar to laboratory spectra of water frost on ice blocks rather than that of an optically thick frost. The strong water ice absorption features, high albedo, and little downturn in reflectance toward shorter wavelengths from 0.6 to 0.4 μm all indicate a surface of nearly pure water ice. The surface of Rhea is probably at least 90 wt% water ice and may be as much as 98 wt%. Of the remaining constituents, neither minerals nor clathrathes can be excluded. If the surface of Rhea were a methane clathrate, the surface would still be about 90 wt% water ice.     

Solar rotation measurements at Mount Wilson

This paper describes a thorough reevaluation of the procedures for reducing the data acquired at the Mt. Wilson Observatory synoptic program of solar observations at the 150-foot tower. We also describe a new program of acquiring as many scans per day as possible of the solar magnetic and velocity fields. We give a new fitting formula which removes the background velocity field from each scan. An important new feature of our reduction algorithm is our treatment of the limb shift which permits time variation in this function. We identify the difference between the limb shift along the north-south axis and the east-west axis as potentially being a result of meridional circulation. Our analysis interprets the time variation in the east-west limb shift as being the result of changes in a vertical component of the meridional circulation.The performance of the system improved in 1982 as a result of the installation of a new exit slit assembly. The amplitude of the limb shift variations found prior to 1982 is larger than is easily explained with simple ideas of meridional circulation. However, we have not been able to firmly identify instrumental causes for the variations although small changes in the band-pass of the exit slit assembly could have contributed.We have established a correlation between the observed stray light in the system and a component of the velocity field which is antisymmetric with respect to the solar central meridian. We remove this stray light effect by adding an additional term to the fitting function.Finally, we show that the inclusion of the above improvements allows us to study the torsional oscillations at high latitude using a procedure which can retain the longitude dependent information about the velocity pattern.     

Weathering of an Arctic oil spill over 20 years: the BIOS experiment revisited. Baffin Island Oil Spill

A small experimental oil spill was conducted on the northern tip of Baffin Island Nunavut, Canada (72 degrees 31' N, 79 degrees 50' W) in August 1981, and the natural weathering of the oil has been followed by periodic visits. This paper reports on the chemical composition of oil collected in August 2001. The vast majority of the initial oil has gone, but small patches remain. Some samples remain essentially unaltered despite their 20 years of exposure to the elements, while others show that biodegradation and photooxidation can play important roles in removing the majority of the components of the oil. Using 17alpha(H)21beta(H)hopane as a conserved marker within the oil, we show that the most biodegraded sample has lost more than 87% of the hydrocarbons initially present, while another has lost a substantial proportion of its initial chrysene and alkylated congeners. Potential explanations for the different weathering patterns seen in samples collected from this small site are briefly discussed.     

Phase relations in high-pressure metapelites in the system KFMASH (K2O–FeO–MgO–Al2O3–SiO2–H2O) with application to natural rocks

Using a previously published, internally consistent thermodynamic dataset and updated models of activity–composition relations for solid solutions, petrogenetic grids in the model system KFMASH (K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O) and the subsystems KMASH and KFASH have been calculated with the software THERMOCALC 3.1 in the P–T range 5–36 kbar and 400–810 °C, involving garnet, chloritoid, biotite, carpholite, talc, chlorite, staurolite and kyanite/sillimanite with phengite, quartz/coesite and H₂O in excess. These grids, together with calculated AFM compatibility diagrams and pseudosections, are shown to be powerful tools for delineating the phase equilibria and P–T conditions of pelitic high-P assemblages for a variety of bulk compositions. The calculated equilibria and mineral compositions are in good agreement with petrological observation. The calculation indicates that the typical whiteschist assemblage kyanite–talc is restricted to the rocks with extremely high X_Mg values, decreasing X_Mg in a bulk composition favoring the stability of chloritoid and garnet. Also, the chloritoid–talc paragenesis is stable over 19–20 kbar in a temperature range of ca. 520–620 °C, being more petrologically important than the previously highlighted assemblage talc–phengite. Moreover, contours of the calculated Si isopleths in phengite in P–T and P–X pseudosections for different bulk compositions extend the experimentally derived phengite geobarometers to various KFMASH assemblages.     

The Paleoproterozoic McArthur River (HYC) Pb/Zn/Ag deposit of northern Australia: organic geochemistry and ore genesis

Polycyclic aromatic hydrocarbons (PAHs) in ore and mudstone within the McArthur River ore deposit show compound distribution patterns similar to those of hydrothermally generated petroleum in the Guaymas Basin and significantly different from those found in conventional oil. PAH abundances and their isomer distributions result from a temperature gradient between the source of mineralizing fluids and the sediments fringing the ore system during ore formation. Along with other geochemical, geological, paleobiological and mineralogical lines of evidence, these data provide strong evidence that the ore formed within partially lithified sediments under marine conditions. Given that the McArthur River ore body is an exquisitely preserved example of a sediment-hosted base-metal deposit, these results may be widely applicable. The McArthur deposit is also a rich repository of paleobiological information, allowing studies of the microbiology of ore formation and the paleobiology of an ancient hydrothermal system, as is discussed elsewhere.     

Kinetics and Products of the Gas-Phase Reaction of OH Radicals with 5-Hydroxy-2-Pentanone at 296± 2 K

The 1,4-hydroxycarbonyl 5-hydroxy-2-pentanone is an important product of the gas-phase reaction of OH radicals with n-pentane in the presence of NO. We have used a relative rate method with 4-methyl-2-pentanone as the reference compound to measure the rate constant for the reaction of OH radicals with 5-hydroxy-2-pentanone at 296 ± 2 K. The carbonyls were sampled by on-fiber derivatization using a Solid Phase Micro Extraction (SPME) fiber coated with O> -(2,3,4,5,6-pentafluorobenzyl)hydroxylamine hydrochloride with subsequent thermal desorption of the oxime derivatives and quantification by gas chromatography with flame ionization detection. For comparison, the reference compound was also analyzed following sample collection onto a Tenax adsorbent cartridge. Products of the reaction were investigated using coated-fiber SPME sampling with gas chromatography-mass spectrometry analysis as well as by using in situ atmospheric pressure ionization mass spectrometry. A rate constant for the reaction of OH radicals with 5-hydroxy-2-pentanone of (1.6 ± 0.4) × 10^–11 cm³ molecule^–1 s^–1 was obtained at 296 ± 2 K. Two dicarbonyl products, of molecular weight 86 and 100, were observed and are attributed to CH₃C(O)CH₂CHO and CH₃C(O)CH₂CH₂CHO, respectively. Reaction schemes leading to these products are presented.     

THREE-DIMENSIONAL GEO-MORPHOLOGICAL MODELLING OF ESTUARINE WATERS

1 INTRODUCTION Estuaries and coastal zones have been used as means of navigation, disposal of waste material, fishing and many commercial and economic activities over the centuries. One of the most important phenomena in these regions is the suspended sediment transport, which may cause erosion and deposition, and hence changes in the estuarys morphology. In turn, such changes may lead to problems relating to navigation and estuarine management. When the bed boundary of an estuary change…