Field methods for amending marine sediment with activated carbon and assessing treatment effectiveness

Previous laboratory studies have shown reductions in PCB bioavailability for sediments amended with activated carbon (AC). Here we report results on a preliminary pilot-scale study to assess challenges in scaling-up for field deployment and monitoring. The goals of the preliminary pilot-scale study at Hunters Point Shipyard (San Francisco, USA) were to (1) test the capabilities of a large-scale mixing device for incorporating AC into sediment, (2) develop and evaluate our field assessment techniques, and (3) compare reductions in PCB bioavailability found in the laboratory with well-mixed systems to those observed in the field with one-time-mixed systems. In this study we successfully used a large-scale device to mix 500kg of AC into a 34.4m(2) plot to a depth of 1ft, a depth that includes the majority of the biologically active zone. Our results indicate that after 7 months of AC-sediment contact in the field, the 28-day PCB bioaccumulation for the bent-nosed clam, Macoma nasuta, field-deployed to this AC-amended sediment was approximately half of the bioaccumulation resulting from exposure to untreated sediment. Similar PCB bioaccumulation reductions were found in laboratory bioassays conducted on both the bivalve, M. nasuta and the estuarine amphipod, Leptocheirus plumulosus, using sediment collected from the treated and untreated field plots one year after the AC amendment occurred. To further understand the long-term effectiveness of AC as an in situ treatment strategy for PCB-contaminated sediments under field conditions, a 3-year comprehensive study is currently underway at Hunters Point that will compare the effectiveness of two large-scale mixing devices and include both unmixed and mixed-only control plots.     

Host galaxy morphologies of X-ray selected AGN: assessing the significance of different black hole fuelling mechanisms to the accretion density of the Universe at z∼ 1.

We use morphological information of X-ray selected active galactic nuclei (AGN) hosts to set limits on the fraction of the accretion density of the Universe at   z ≈ 1  that is not likely to be associated with major mergers. Deep X-ray observations are combined with high-resolution optical data from the Hubble Space Telescope in the All-wavelength Extended Groth strip International Survey, Great Observatories Origins Deep Survey (GOODS) North and GOODS South fields to explore the morphological breakdown of X-ray sources in the redshift interval  0.5 < z < 1.3  . The sample is split into discs, early-type bulge-dominated galaxies, peculiar systems and point sources in which the nuclear source outshines the host galaxy. The X-ray luminosity function and luminosity density of AGN at   z ≈ 1  are then calculated as a function of morphological type. We find that disc-dominated hosts contribute  30 ± 9  per cent to the total AGN space density and  23 ± 6  per cent to the luminosity density at   z ≈ 1  . We argue that AGN in disc galaxies are most likely fuelled not by major merger events but by minor interactions or internal instabilities. We find evidence that these mechanisms may be more efficient in producing luminous AGN     compared to predictions for the stochastic fuelling of massive black holes in disc galaxies.     

Identification of spectral units on Phoebe

We apply a multivariate statistical method to the Phoebe spectra collected by the VIMS experiment onboard the Cassini spacecraft during the flyby of June 2004. The G-mode clustering method, which permits identification of the most important features in a spectrum, is used on a small subset of data, characterized by medium and high spatial resolution, to perform a raw spectral classification of the surface of Phoebe. The combination of statistics and comparative analysis of the different areas using both the VIMS and ISS data is explored in order to highlight possible correlations with the surface geology. In general, the results by Clark et al. [Clark, R.N., Brown, R.H., Jaumann, R., Cruikshank, D.P., Nelson, R.M., Buratti, B.J., McCord, T.B., Lunine, J., Hoefen, T., Curchin, J.M., Hansen, G., Hibbitts, K., Matz, K.-D., Baines, K.H., Bellucci, G., Bibring, J.-P., Capaccioni, F., Cerroni, P., Coradini, A., Formisano, V., Langevin, Y., Matson, D.L., Mennella, V., Nicholson, P.D., Sicardy, B., Sotin, C., 2005. Nature 435, 66-69] are confirmed; but we also identify new signatures not reported before, such as the aliphatic CH stretch at 3.53 μm and the ∼4.4 μm feature possibly related to cyanide compounds. On the basis of the band strengths computed for several absorption features and for the homogeneous spectral types isolated by the G-mode, a strong correlation of CO₂ and aromatic hydrocarbons with exposed water ice, where the uniform layer covering Phoebe has been removed, is established. On the other hand, an anti-correlation of cyanide compounds with CO₂ is suggested at a medium resolution scale.     

Radio source calibration for the Very Small Array and other cosmic microwave background instruments at around 30 GHz

Accurate calibration of data is essential for the current generation of cosmic microwave background (CMB) experiments. Using data from the Very Small Array (VSA), we describe procedures which will lead to an accuracy of 1 per cent or better for experiments such as the VSA and CBI. Particular attention is paid to the stability of the receiver systems, the quality of the site and frequent observations of reference sources. At 30 GHz the careful correction for atmospheric emission and absorption is shown to be essential for achieving 1 per cent precision.
The sources for which a 1 per cent relative flux density calibration was achieved included Cas A, Cyg A, Tau A and NGC 7027 and the planets Venus, Jupiter and Saturn. A flux density, or brightness temperature in the case of the planets, was derived at 33 GHz relative to Jupiter which was adopted as the fundamental calibrator. A spectral index at ∼30 GHz is given for each.
Cas A, Tau A, NGC 7027 and Venus were examined for variability. Cas A was found to be decreasing at 0.394 ± 0.019 per cent yr⁻¹ over the period 2001 March to 2004 August. In the same period Tau A was decreasing at 0.22 ± 0.07 per cent yr⁻¹. A survey of the published data showed that the planetary nebula NGC 7027 decreased at 0.16 ± 0.04 per cent yr⁻¹ over the period 1967–2003. Venus showed an insignificant (1.5 ± 1.3 per cent) variation with Venusian illumination. The integrated polarization of Tau A at 33 GHz was found to be 7.8 ± 0.6 per cent at position angle =148°± 3°.     

Scenarios of land use and land cover change in the conterminous United States: Utilizing the special report on emission scenarios at ecoregional scales

Global environmental change scenarios have typically provided projections of land use and land cover for a relatively small number of regions or using a relatively coarse resolution spatial grid, and for only a few major sectors. The coarseness of global projections, in both spatial and thematic dimensions, often limits their direct utility at scales useful for environmental management. This paper describes methods to downscale projections of land-use and land-cover change from the Intergovernmental Panel on Climate Change's Special Report on Emission Scenarios to ecological regions of the conterminous United States, using an integrated assessment model, land-use histories, and expert knowledge. Downscaled projections span a wide range of future potential conditions across sixteen land use/land cover sectors and 84 ecological regions, and are logically consistent with both historical measurements and SRES characteristics. Results appear to provide a credible solution for connecting regionalized projections of land use and land cover with existing downscaled climate scenarios, under a common set of scenario-based socioeconomic assumptions.     

Changes in European temperature extremes can be predicted from changes in PDF central statistics

Although uncertainties are still large, many potentially dangerous effects have already been identified concerning the impacts of global warming on human societies. For example, the record-breaking 2003 summer heat wave in Europe has given a glimpse of possible future European climate conditions. Here we use an ensemble of regional climate simulations for the end of the twentieth and twenty-first centuries over Europe to show that frequency, length and intensity changes in warm and cold temperature extremes can be derived to a close approximation from the knowledge of changes in three central statistics, the mean, standard deviation and skewness of the Probability Distribution Function, for which current climate models are better suited. In particular, the effect of the skewness parameter appears to be crucial, especially in the case of cold extremes, since it mostly explains the relative warming of these events compared to the whole distribution. An application of this finding is that the future impacts of extreme heat waves and cold spells on non-climatological variables (e.g., mortality) can be estimated to a first-order approximation from observed time series of daily temperature transformed in order to account for simulated changes in these three statistics.     

Cyclic testing of unreinforced masonry walls in two‐way bending

An experimental programme was conducted in which eight full‐scale unreinforced masonry walls were subjected to cyclic face loading using a system of airbags. Of the eight walls, six contained a window opening and four were subjected to vertical pre‐compression. Combined supports at the vertical and horizontal edges ensured that under face loading the walls underwent two‐way bending. The test walls were found to possess good post‐peak strength and displacement capacity as well as reasonable energy dissipation characteristics. Significant strength and stiffness degradation and non‐symmetry of strength in the positive and negative displacement directions were also evident. Discussion of the causes of the aforementioned trends and their implications towards the seismic response of masonry walls is provided. Copyright © 2006 John Wiley & Sons, Ltd.     

Impacts of Positional Error on Spatial Regression Analysis: A Case Study of Address Locations in Syracuse, New York

Positional error is the error produced by the discrepancy between reference and recorded locations. In urban landscapes, locations typically are obtained from global positioning systems or geocoding software. Although these technologies have improved the locational accuracy of georeferenced data, they are not error free. This error affects results of any spatial statistical analysis performed with a georeferenced dataset. In this paper we discuss the properties of positional error in an address matching exercise and the allocation of point locations to census geography units. We focus on the error's spatial structure, and more particularly on impacts of error propagation in spatial regression analysis. For this purpose we use two geocoding sources, we briefly describe the magnitude and the nature of their discrepancies, and we evaluate the consequences that this type of locational error has on a spatial regression analysis of pediatric blood lead data for Syracuse, NY. Our findings include: (1) the confirmation of the recurrence of spatial clustering in positional error at various geographic resolutions; and, (2) the identification of a noticeable but not shockingly large impact from positional error propagation in spatial auto‐binomial regression analysis results for the dataset analyzed.     

On the perturbations of the five outer planets by the four inner ones

The expressions given by Clemence were checked by the comparison of numerical values of their second differentials with the numerical values of the perturbing forces. Agreement was good in most cases, save that the use of the second differentials unduly magnified some terms rightly neglected by Clemence. In the appendix the work of Clemence is compared with that of Carpenter and the differences are found to be all smaller than the contributions from the secular variation of the eccentricity, which are so small that they were neglected by Clemence. The differences can be removed by considering the secular variation of the eccentricity and by making a small adjustment in the integration constants.     

Hydrogen peroxide concentrations in the Peru upwelling area

The concentration of hydrogen peroxide was measured in waters off the coast of Peru during June and July 1983. The study period coincided with the end of the 1982/83 El Niño and the onset of coastal upwelling. Depth profiles of hydrogen peroxide concentration exhibit surface maxima and decrease with depth to the base of the mixed layer. Surface peroxide concentrations ranged from 0.8 to 5 × 10^?8 M. Below the mixed layer hydrogen peroxide was below the detection limit (5 × 10^?9 M). Diel variations were observed, with surface peroxide levels increasing during the day and decreasing at night. The nearshore station exhibited lower hydrogen peroxide concentrations than offshore stations, a reversal of the trend found in other coastal regions. This is attributed to the lack of coastal vegetation and runoff, and to active coastal upwelling of deeper water with low hydrogen peroxide concentrations.