Measured oxygen fugacities of the Angra dos Reis achondrite as a function of temperature

Measurements of the oxygen fugacity (?O₂) as a function of temperature (T) were made on an interior bulk sample of the cumulate achondrite, Angra dos Reis. Data clustered between the?O₂-T relationship of the iron-wüstite assemblage and 1.2 log atm units above iron-wüstite. Interpretation of the data indicates that, throughout most of the cooling history of the meteorite, ?O₂ values were defined by equilibria involving iron-bearing species at values close to the ?O₂ of the assemblage iron-wüstite. Measured ?O₂ data are compatible with crystallization and cooling at pressures greater than 50 bars.     

The effect of Tibetan uplift on the formation and preservation of Tertiary lacustrine source-rocks in eastern China

The Cenozoic continental sedimentary basins in eastern China are rich in lacustrine source rocks. Based on their paleogeographic location and fossils, these basins can be grouped into inland and near-shore basins. Before the collision of India and Eurasia about 45 million years ago, the inland basins were dominated by arid climates that were unfavorable for the substantial preservation of oil source rocks. In contrast, the contemporary near-shore basins experienced alternating arid and humid climates, probably induced by sea level changes, which produced conditions that favoured the formation and preservation of oil source rocks. With the rise of the Tibetan Plateau, the Asian monsoon was initiated or significantly intensified in the Late Eocene. This, in turn, changed the arid climates in the inland basins to humid or to alternating arid and humid, providing ideal conditions for the formation and preservation of lacustrine source rocks in the inland basins. The evidence suggests that Tibetan uplift played a crucial role in the generation and preservation of the Cenozoic lacustrine source rocks in eastern China.This is the third paper in a series of papers published in this issue on Climatic and Tectonic Rhythms in Lake Deposits.     

Simulations of a late lunar-forming impact

Results of about 100 hydrodynamic simulations of potential Moon-forming impacts are presented, focusing on the “late impact” scenario in which the lunar forming impact occurs near the very end of Earth's accretion (Canup and Asphaug, 2001, Nature 412, 708-712). A new equation of state is utilized that includes a treatment of molecular vapor (“M-ANEOS”; Melosh, 2000, in: Proc. Lunar Planet. Sci. Conf. 31st, p. 1903). The sensitivity of impact outcome to collision conditions is assessed, in particular how the mass, angular momentum, composition and origin (target vs. impactor) of the material placed into circumterrestrial orbit vary with impact angle, speed, impactor-to-target mass ratio, and initial thermal state of the colliding objects. The most favorable conditions for producing a sufficiently massive and iron-depleted protolunar disk involve collisions with an impact angle near 45 degrees and an impactor velocity at infinity <4 km/sec. For a total mass and angular momentum near to that of the current Earth-Moon system, such impacts typically place about a lunar mass of material into orbits exterior to the Roche limit, with the orbiting material composed of 10 to 30% vapor by mass. In all cases, the vast majority of the orbiting material originates from the impactor, consistent with previous findings. By mapping the end fate (escaping, orbiting, or in the planet) of each particle and the peak temperature it experiences during the impact onto the figure of the initial objects, it is shown that in the successful collisions, the impactor material that ends up in orbit is primarily that portion of the object that was heated the least, having avoided direct collision with the Earth. Using these and previous results as a guide, a continuous suite of impact conditions intermediate to the “late impact” (Canup and Asphaug, 2001, Nature 412, 708-712) and “early Earth” (Cameron, 2000, in: Canup, R.M., Righter, K. (Eds.), Origin of the Earth and Moon, pp. 133-144; 2001, Meteorit. Planet. Sci. 36, 9-22) scenarios is identified that should also produce iron-poor, ∼lunar-sized satellites and a system angular momentum similar to that of the Earth-Moon system. Among these, those that leave the Earth >95% accreted after the Moon-forming impact are favored here, implying a giant impactor mass between 0.11 and 0.14 Earth masses.     

Postglacial relative sea‐level observations from Ireland and their role in glacial rebound modelling

The British Isles have been the focus of a number of recent modelling studies owing to the existence of a high‐quality sea‐level dataset for this region and the suitability of these data for constraining shallow earth viscosity structure, local to regional ice sheet histories and the magnitude/timing of global meltwater signals. Until recently, the paucity of both glaciological and relative sea‐level (RSL) data from Ireland has meant that the majority of these glacial isostatic adjustment (GIA) modelling studies of the British Isles region have tended to concentrate on reconstructing ice cover over Britain. However, the recent development of a sea‐level database for Ireland along with emergence of new glaciological data on the spatial extent, thickness and deglacial chronology of the Irish Ice Sheet means it is now possible to revisit this region of the British Isles. Here, we employ these new data to constrain the evolution of the Irish Ice Sheet. We find that in order to reconcile differences between model predictions and RSL evidence, a thick, spatially extensive ice sheet of ～600–700 m over much of north and central Ireland is required at the LGM with very rapid deglaciation after 21 k cal. yr BP. Copyright © 2007 John Wiley & Sons, Ltd.     

Structural studies of imogolite and allophanes by aluminum-27 and silicon-29 nuclear magnetic resonance spectroscopy

High-resolution aluminum-27 and silicon-29 nuclear magnetic resonance spectra of natural and synthetic imogolites and allophanes obtained using high-field“magic-angle” sample-spinning (MASS) techniques indicate that the imogolite and protoimogolite components of allophanes are characterized by sharp (≈3 ppm) silicon-29 resonances at ?78±1 ppm from tetramethylsilane (in accord with Barron et al. 1982), and quite narrow (≈10 ppm at 11.7 Tesla) aluminum-27 resonances, at 5.2±1 ppm from Al(H₂O) ₆ ³⁺ (in accord with Wilson et al. 1984). However, the spectra of natural allophanes usually contain significant intensity arising from a less well defined material, characterized by a broad (≈20 ppm) silicon-29 resonance centered at ?90±2 ppm from tetramethylsilane, and a second relatively narrow (≈15 ppm at 11.7 Tesla) aluminum-27 resonance at 58.5±2 ppm from Al(H₂O) ₆ ³⁺ . Similar characteristic spectral features are exhibited by a synthetic amorphous Si:Al (1:1) gel, and presumably indicate the presence of framework aluminosilicate materials in the gel, and in most allophanes.     

Alteration paragenesis and mineral chemistry of the Tjårrojåkka apatite–iron and Cu (-Au) occurrences, Kiruna area, northern Sweden

The northern Norrbotten area in northern Sweden, is an important mining district and hosts several deposits of Fe-oxide Cu-Au-type. One of the best examples of spatially, and possibly genetically, related apatite–iron and copper–gold deposits in the region is at Tjårrojåkka, 50 km WSW of Kiruna. The deposits are hosted by strongly sheared and metamorphosed intermediate volcanic rocks and dolerites and show a structural control. The Tjårrojåkka iron deposit is a typical apatite–iron ore of Kiruna-type and the Tjårrojåkka copper occurrence shows the same characteristics as most other epigenetic deposits in Norrbotten. The host rock has been affected by strong albite and K-feldspar alteration related to mineralisation, resulting in an enrichment of Na, K, and Ba. Fe and V were depleted in the altered zones and added in mineralised samples. REE were enriched in the system, with the greatest addition related to mineralisation. Y was also mobile associated with albite alteration and copper mineralisation. The Tjårrojåkka iron and copper deposits show comparable hydrothermal alteration minerals and paragenesis, which might be a product of common host rock and similarities in ore fluid composition, or overprinting by successive alteration stages. Mineralogy and mineral chemistry of the alteration minerals (apatite, scapolite, feldspars, amphiboles, and biotite) indicate a higher salinity and Ba/K ratio in the fluid related to the alterations in the apatite–iron occurrence than in the copper deposit, where the minerals are enriched in F and S. The presence of hematite, barite, and in SO₄ in scapolite suggests more oxidising-rich conditions during the emplacement of the Tjårrojåkka-Cu deposit. From existing data it might be suggested that one evolving system created the two occurrences, with the copper mineralisation representing a slightly later product.     

Sensitivity to space and time resolution of a hydrological model using digital elevation data

The space and time resolutions used for the input variables of a distributed hydrological model have a sufficient impact on the model results. This resolution depends on the required accuracy, experimental site and the processes and variables taken into account in the hydrological model. The influence of space and time resolution is studied here for the case of TOPMODEL, a model based on the variable contributing area concept, applied to an experimental 12 km² catchment (Coët-Dan, Brittany, France) during a two month winter period. A sensitivity analysis to space and time resolution is performed first for input variables derived from the digital elevation data, secondly for the optimized values of the TOPMODEL parameters and finally for modelling efficiency. This analysis clearly shows that a relevant domain of space and time resolutions where efficiency is fairly constant can be defined for the input topographic variables, as opposed to another domain of larger resolutions that induces a strong decrease of modelling efficiency. It also shows that the use of a single set of parameters, defined as mean values of parameters on this relevant domain of resolution, does not modify the accuracy of modelling. The sensitivity of the parameters to space and time resolution allows the physical significance of the parameter values to be discussed.     

Exploring the past through lynchet landscapes in the Vosges Mountains and the Lorraine Plateau (France)

Lynchets are ridges formed by erosion and sediment accumulation downstream of agricultural plots and offer valuable insights into past agricultural activity. These microtopographies cover vast areas and serve as indicators of historical changes in land use. As a result, their ubiquity across Europe makes them particularly interesting. In this study, we propose a geoarchaeological approach to analyze six lynchets, four in the Vosges Mountains and two on the Lorraine Plateau (France). The lynchets can be considered soil archives with no stratigraphic organization or chronological sequence from bottom to top, making it difficult to determine the age of the lynchets and identify changes in land use over time. To this end, we propose the analysis of historical and geo-historical archives combined with the “pedosedimentary” archives of lynchets through charcoal identification and dating combined with near-infrared spectroscopy to determine the age, vegetation, and past land use changes associated with lynchet landscapes. By combining these multiple data sources, we are better able to show the chronological development of these ancient agricultural systems and uncover valuable information on landscape history. Charcoal dating suggests a higher frequency of fires from the Middle Ages. The dating aligns with the regional dynamics of anthropogenic fires, indicating a potential use of fire for cultural purposes. We also demonstrate the difficulty of extrapolating the dating of a lynchet to the entire lynchet system. Our results highlight the difficulties of interpreting the formation and dating of lynchets and the lynchet system on the sole basis of charcoal analysis. However, we highlight the value of applying pedoanthracology to lynchets to determine the dynamics of land use change in former fields.