Theoretical calculation of equilibrium Mg isotope fractionation between silicate melt and its vapor

Isotope fractionation during the evaporation of silicate melt and condensation of vapor has been widely used to explain various isotope signals observed in lunar soils, cosmic spherules, calcium–aluminum-rich inclusions, and bulk compositions of planetary materials. During evaporation and condensation, the equilibrium isotope fractionation factor (α) between high-temperature silicate melt and vapor is a fundamental parameter that can constrain the melt’s isotopic compositions. However, equilibrium α is difficult to calibrate experimentally. Here we used Mg as an example and calculated equilibrium Mg isotope fractionation in MgSiO₃ and Mg₂SiO₄ melt–vapor systems based on first-principles molecular dynamics and the high-temperature approximation of the Bigeleisen–Mayer equation. We found that, at 2500 K, δ²⁵Mg values in the MgSiO₃ and Mg₂SiO₄ melts were 0.141?±?0.004 and 0.143?±?0.003‰ more positive than in their respective vapors. The corresponding δ²⁶Mg values were 0.270?±?0.008 and 0.274?±?0.006‰ more positive than in vapors, respectively. The general \(\alpha - T\) equations describing the equilibrium Mg α in MgSiO₃ and Mg₂SiO₄ melt–vapor systems were: \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.264 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\) and \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.340 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\), respectively, where m is the mass of light isotope ²⁴Mg and m′ is the mass of the heavier isotope, ²⁵Mg or ²⁶Mg. These results offer a necessary parameter for mechanistic understanding of Mg isotope fractionation during evaporation and condensation that commonly occurs during the early stages of planetary formation and evolution.     

Bioaccumulation of heavy metals in <Emphasis Type="Italic">Limnobium laevigatum</Emphasis> and <Emphasis Type="Italic">Ludwigia peploides</Emphasis>: their phytoremediation potential in water contaminated with heavy metals

Contamination with heavy metals in surface and groundwater is a threat to human health and ecosystems. Due to this, the need arises to remediate water polluted through ecological and profitable technologies, such as phytoremediation. The objective of the work was to evaluate the concentration of lead (Pb) and zinc (Zn) in the floating macrophytes Limnobium laevigatum and Ludwigia peploides, after being exposed to contaminated water experimentally. In this way to be able to determine if these plants have mechanisms that allow them to accumulate the metals in the roots and to perform the translocation of these to different vegetative organs, L. laevigatum and L. peploides were placed in solutions contaminated with Pb ([Pb]?=?5 mg/l) and Zn ([Zn]?=?20 mg/l). The concentrations of metals in water, root and leaf samples were evaluated as a function of time (0, 1, 2 and 4 days). The determination of the metals was performed by the atomic absorption spectrophotometry technique. After 4 days of exposure to Pb and Zn, the plants showed high metal removal efficiencies of water, more to 70% in all cases. Pb was accumulated fundamentally by roots, while Zn was accumulated more in the leaves. In addition, the bioconcentration and translocation factors for each metal were calculated.     

Hydrothermal Dolomite: A Review and PerspectiveEI北大核心CSCD

Hydrothermal dolomite commonly closely associates with oil-gas reservoirs and sediment-hosted Pb-Zn deposits, the Mississippi Valley-type (MVT) Pb-Zn deposits in particular. Host rocks of MVT deposits usually experienced extensive dolomitization, and indeed, hydrothermal dolomite is considered as a useful prospective indicator for MVT mineralization. However, genetic link between the hydrothermal dolomitization and MVT Pb-Zn mineralization is a matter of debate. This paper briefly reviewed the nomenclature and research history of hydrothermal dolomite, introduced the major geological, geochemical characteristics, and distribution of hydrothermal dolomite, spatial and possibly genetic relationship between hdyrothermal dolomite and hdyrothermal ore deposits and oil-gas reservoirs based on case studies including the occurrence of hydrothermal dolomites in MVT deposits in Southwest China. The temporal and genetic relationships between dolomitizaiton and thermal sulfate reduction, sulfide precipitation and thus the location of ore mineralization well worthy more attention, and comprehensive geological and isotope geochemical and state of art in situ techniques will contribute to understanding of the genesis of hydrotherml dolomite and the spatially related ore deposits and oil-gas reservoirs. © 2018, Science Press. All right reserved.     

Science-based approach for credible accounting of mitigation in managed forests

Background

The credibility and effectiveness of country climate targets under the Paris Agreement requires that, in all greenhouse gas (GHG) sectors, the accounted mitigation outcomes reflect genuine deviations from the type and magnitude of activities generating emissions in the base year or baseline. This is challenging for the forestry sector, as the future net emissions can change irrespective of actual management activities, because of age-related stand dynamics resulting from past management and natural disturbances. The solution implemented under the Kyoto Protocol (2013–2020) was accounting mitigation as deviation from a projected (forward-looking) “forest reference level”, which considered the age-related dynamics but also allowed including the assumed future implementation of approved policies. This caused controversies, as unverifiable counterfactual scenarios with inflated future harvest could lead to credits where no change in management has actually occurred, or conversely, failing to reflect in the accounts a policy-driven increase in net emissions. Instead, here we describe an approach to set reference levels based on the projected continuation of documented historical forest management practice, i.e. reflecting age-related dynamics but not the future impact of policies. We illustrate a possible method to implement this approach at the level of the European Union (EU) using the Carbon Budget Model.

Results

Using EU country data, we show that forest sinks between 2013 and 2016 were greater than that assumed in the 2013–2020 EU reference level under the Kyoto Protocol, which would lead to credits of 110–120 Mt CO₂/year (capped at 70–80 Mt CO₂/year, equivalent to 1.3% of 1990 EU total emissions). By modelling the continuation of management practice documented historically (2000–2009), we show that these credits are mostly due to the inclusion in the reference levels of policy-assumed harvest increases that never materialized. With our proposed approach, harvest is expected to increase (12% in 2030 at EU-level, relative to 2000–2009), but more slowly than in current forest reference levels, and only because of age-related dynamics, i.e. increased growing stocks in maturing forests.

Conclusions

Our science-based approach, compatible with the EU post-2020 climate legislation, helps to ensure that only genuine deviations from the continuation of historically documented forest management practices are accounted toward climate targets, therefore enhancing the consistency and comparability across GHG sectors. It provides flexibility for countries to increase harvest in future reference levels when justified by age-related dynamics. It offers a policy-neutral solution to the polarized debate on forest accounting (especially on bioenergy) and supports the credibility of forest sector mitigation under the Paris Agreement.

     

河北围场早白垩世鲎虫化石性双形现象研究

对产自河北围场下白垩统九佛堂组的65件鲎虫化石标本进行研究。根据其形态特征,认为这些鲎虫化石属于三角围场鲎虫（Weichangiops triangularisYang et Hong, 1980）。有观点认为,具有上肛板的鲎虫为冷水型鲎虫,而不具上肛板的鲎虫为暖水型鲎虫。河北围场采集的鲎虫化石有的具上肛板,有的不具上肛板,目前没有任何证据表明其为冷水型鲎虫与暖水型鲎虫混生的产物。通过研究,对三角围场鲎虫的特征进行了适当修正,认为围场地区的鲎虫化石具1对复眼,因此依据单个复眼而建立的新亚科——围场鲎虫亚科（Weichangiopsinae）不成立,应予以摒弃。三角围场鲎虫存在明显的性双形现象,雄性个体尾部具有上肛板,雌性个体不具有上肛板,这对于鲎虫化石分类研究具有重要的科学价值,可避免在生物分类时发生同物异名现象。     

DYYZ-Ⅱ型自动气象站测温故障排除方法与思路

文章通过DYYZ-Ⅱ型自动气象站出现的一次气温、地温数据缺测故障,分析了DYYZ-Ⅱ型自动气象站出现测温故障时的故障排除过程与排除思路,为保障技术人员在处理此类故障时提供了方法和依据。     

杭锦旗北部牧草引种试验

利用在内蒙古杭锦旗北部进行牧草引种试验的数据,结合产量效益分析了4个牧草品种对当地土壤与气候条件的适应性,初步得出适应杭锦旗北部气候、生态条件的牧草品种,并通过产量效益分析,确定了适合当地的牧草间、混作模式,为当地建立人工饲草基地发展生态畜牧业提供决策参考。     

Atmospheric radiative transfer simulation for atmospheric correction of remote sensing data

The radiance leaving the earth-atmosphere system which can be sensed by a satellite borne radiometer is the sum of radiation emission from the earth surface and each atmospheric level that are transmitted to the top of the atmosphere. The radiation emission from the earth surface and the radiance of each atmospheric level can be separated from the radiance at the top the atmospheric level measured by a satellite borne radiometer. However, it is very difficult to measure the atmospheric radiance, especially the synchronous measurement with the satellite. Thus some atmospheric radiative transfer models have been developed to provide many options for modeling atmospheric radiation transport, such as LOWTRAN, MODTRAN, 6S, FASCODE, LBLRTM, SHARC, and SAMM. Meanwhile, these models can support the detailed detector system design, the optimization and evaluation of satellite mission parameters, and the data processing procedures. As an example, the newly atmospheric radiative transfer models, MODTRAN will be compared with other models after the atmospheric radiative transfer is described. And the atmospheric radiative transfer simulation procedures and their applications to atmospheric transmittance, retrieval of atmospheric elements, and surface parameters, will also be presented.     

区域农业用地营养盐剩余量的长期变化研究

根据太湖南部长兴县农业统计资料,对该地区1949~2002年农业用地上N、P的剩余量作出评估。评估结果认为,1949~2002年期间,单位农业用地面积的N、P剩余量具有显著地增加趋势。20世纪50及60年代期间,N的剩余量增加缓慢,自70年代中期以后增加迅速。1996年达到历史最大值。1996年后,N剩余量呈现减少趋势。60年代初期以前,P处于亏损状态。1975~1980年期间,P剩余量呈现缓慢增长趋势,其后出现回落,自80年代中期以后出现迅速增加趋势。1992~1998年期间,P剩余量维持在35~45 kg/(hm²·a)之间的高水平变化,自1999年以后出现显著回落。     

实时子结构实验Chang算法的稳定性和精度

与慢速拟动力子结构实验相比,实时子结构实验的优点在于它能真实地反映速度相关型试件的特性。实时子结构实验的逐步积分算法通常借用拟动力算法,但是目前液压伺服作动器很难实现速度反馈控制,因而试件速度不能实现原算法的假定值,这样一来算法的稳定性和计算精度将发生改变。台湾学者S.Y.Chang提出一种无条件稳定的显式拟动力算法,本文分析了这种方法应用于实时子结构实验时的稳定性和计算精度。研究发现在实时子结构实验中该方法由无条件稳定变成了有条件稳定的,精度也发生了改变。