The Reference Manure Concept for Transformation Tests of Veterinary Medicines and Biocides in Liquid Manure

Veterinary medicines and biocides are frequently applied in animal houses of livestock husbandry. Due to these application patterns, they reach liquid manure. So far these substances are not transformed during manure storage, they enter soil by the application of manure as organic fertilizer. Therefore, biodegradability of veterinary medicines and biocides in manure is in the focus of regulatory procedures of environmental risk assessment. Since the representative and reproducible sampling of manures from high volume tanks is considered impossible due to high matrix variabilities, the reference manure concept was developed to utilize liquid bovine and pig manures for reproducible laboratory testing. Accordingly, excrement samples of cattle and pigs individually kept at experimental and conventional animal houses were taken. Tap water was added to matrix characterized excrements in order to prepare bovine and pig reference manures of 10 and 5% dry substance contents, respectively. Subsequently, the long‐term transformation of selected ¹⁴C‐labeled test substances was investigated under strictly anaerobic conditions. The application of different batches of bovine or pig reference manures indicated that extrapolation of transformation rates within the same animal species was possible. However, results cannot be transferred from bovine to pig manure because of substance specific interactions with the different manure matrices. The dependency of metabolic dynamics on different dry substance contents (2.5, 5, 10%) was additionally investigated in both manure matrices. These tests clearly showed that the dry substance content of the reference manure is one of the most relevant factors affecting the transformation of veterinary medicines and biocides. In contrast to highly variable tank manures, the reference manure concept allows for the exact adjustment of this parameter to guarantee reproducible laboratory testing.     

Mercury in some granitoid rocks of the yukon and its relation to gold-tungsten mineralization

Data for the mean mercury contents of some granitoid rocks of the Yukon are presented. A correlation of high mercury content with plutons postulated to be the sources, or genetically related to the sources, of the alluvial gold deposits of the McQuesten area is established. In addition a relation is indicated between high mercury content in one intrusion and high content in the Palaeozoic shale host rock. A limited amount of data is presented on the mercury content of the Proterozoic and Palaeozoic rocks of the sampled area.     

Population growth and the development of a central place system

This paper describes the spatial and functional evolution of a central place system as market conditions change with population growth. Utilizing a partial equilibrium optimization model, we examine the spatial response of two economic sectors to increases in market populations resulting from natural increase and migration. Response in both sectors is conditioned by threshold demand, with factor prices also affecting one of the sectors. As the central place system evolves it exhibits spatial and functional characteristics that are initially consistent with a Löschian landscape, then a Christallerian landscape at higher populations, while at even larger populations Krugman’s landscape emerges.     

Nonlinear least-squares method via an isomorphic geometrical setup

The resolution of a nonlinear parametric adjustment model is addressed through an isomorphic geometrical setup with tensor structure and notation, represented by a u-dimensional “model surface” embedded in a flat n-dimensional “observational space”. Then observations correspond to the observational-space coordinates of the pointQ, theu initial parameters correspond to the model-surface coordinates of the “initial” pointP, and theu adjusted parameters correspond to the model-surface coordinates of the “least-squares” point . The least-squares criterion results in a minimum-distance property implying that the vector Q must be orthogonal to the model surface. The geometrical setup leads to the solution of modified normal equations, characterized by a positive-definite matrix. The latter contains second-order and, optionally, thirdorder partial derivatives of the observables with respect to the parameters. This approach significantly shortens the convergence process as compared to the standard (linearized) method.     

Water level variations in the Neuse and Pamlico Estuaries,North Carolina due to local and remote forcing

Water level time series records from the Neuse and Pamlico River Estuaries were statistically compared to local and distant wind field data, water level records within the Pamlico Sound and also coastal ocean sites to determine the relative contribution of each time series to water levels in the Neuse and Pamlico Estuaries. The objectives of this study were to examine these time series data using various statistical methods (i.e. autoregressive, empirical orthogonal function analysis (EOF), exploratory data analysis (EDA)) to determine short- and long-time-scale variability, and to develop predictive statistical models that can be used to estimate past water level fluctuations in both the Neuse Estuary (NE) and Pamlico Estuary (PE). Short- and long-time-scale similarities were observed in all time series of estuarine, Pamlico Sound and subtidal coastal ocean water level and wind component data, due to events (nor'easters, fronts and tropical systems) and seasonality. Empirical orthogonal function analyses revealed a strong coastal ocean and wind field contribution to water level in the NE and PE. Approximately 95% of the variation was captured in the first two EOF components for water level data from the NE, sound and coastal ocean, and 70% for the PE, sound and coastal ocean. Spectral density plots revealed strong diurnal signals in both wind and water level data, and a strong cross correlation and coherency between the NE water level and the North/South wind component. There was good agreement between data and predictions using autoregressive statistical models for the NE (R² = 0.92) and PE (R² = 0.76). These methods also revealed significant autoregressive lags for the NE (days 1 and 3) and for the PE (days 1, 2 and 3). Significant departures from predictions are attributed to local meteorological and hydrological events. The autoregressive techniques showed significant predictive improvement over ordinary least squares methods. The results are considered within the context of providing long time-scale hindcast data for the two estuaries, and the importance of these data for multidisciplinary researchers and managers.     

Silicones in Chesapeake Bay sediments

Sediment samples from the upper reaches to the mouth of the Chesapeake Bay were analysed for extractable organic silicon (silicone) content. Organic silicon in the sediments ranged from less than 0.2 to some 36 ppm, w/w. In general, silicone tended to accumulate in high depositional areas: the northern bay, and along the shores to the south. While present, anthropogenic inputs in terms of defined source were not clear. It appears that processes in the bay act to rapidly remove silicone from the water column, probably on a function of the flocculation/precipitation of seston, especially in the northern area.     

Can Plant Competition and Diversity Reduce the Growth and Survival of Exotic <Emphasis Type="Italic">Phragmites australis</Emphasis> Invading a Tidal Marsh?

The rapid proliferation of Phragmites australis in North America has challenged resource managers to curb its expansion and reduce the loss of functional tidal marsh. We investigated whether native plant competition could reduce the ability of Phragmites to invade a tidal marsh, and if plant diversity (species richness, evenness, and composition) altered the competitive outcome. Immature Phragmites shoots and four native halophytes were transplanted to small but dense field plots (~1,200 shoots m⁻²) comprising three community structure types (Phragmites alone, Phragmites + 1 native species, and Phragmites + 4 native species). Interspecific competition significantly reduced Phragmites aboveground biomass, shoot length production, density, and survival by approximately 60%. Additionally, plots planted with greater native diversity contained Phragmites with the lowest growth and survival, potentially indicating diversity-enhanced resource competition. Competition consistently reduced the growth of Phragmites even under favorable conditions: lack of strong tidal flooding stresses as well as elevated nutrient pools.     

Meteor44 Video Meteor Photometry

Meteor44 is a software system developed at MSFC for the calibration and analysis of video meteor data. The photometric range of the (8 bit) video data is extended from a visual magnitude range of from 8 to 3 to from 8 to −8 for both meteors and stellar images using saturation compensation. Camera and lens specific saturation compensation coefficients are derived from artificial variable star laboratory measurements. Saturation compensation significantly increases the number of meteors with measured intensity and improves the estimation of meteoroid mass distribution. Astrometry is automated to determine each image's plate coefficient using appropriate star catalogs. The images are simultaneously intensity calibrated from the contained stars to determine the photon sensitivity and the saturation level referenced above the atmosphere. The camera's spectral response is used to compensate for stellar color index and typical meteor spectra in order to report meteor light curves in traditional visual magnitude units. Recent efforts include improved camera calibration procedures and long focal length "streak" meteor photometry. Meteor44 has been used to analyze data from the 2001, 2002 and 2003 MSFC Leonid observational campaigns as well as several lesser showers.     

Experiments on steady buoyancy transfer through turbulent fluid layers separated by density interfaces

A laboratory experiment was performed to investigate mixing across a density interface which separates two turbulent fluid layers and coexists with a stabilizing buoyancy flux. It was found that the buoyancy flux (q₀) across the interface and through the turbulent layers (of depth D) becomes steady and constant in magnitude in the vertical direction, only when , where u is the horizontal r.m.s. velocity at the base of the mixed layers. The results suggest that mixing across the density interface is controlled by a dynamically important buoyancy gradient induced in the turbulent layers and that parameters such as the bulk Richardson number, , where Δb is the interfacial buoyancy jump, are of secondary importance. Measurements are used to infer the mixing mechanism at the interface, the mixing efficiency of stratified fluids and the entrainment law. Some geophysical applications of the results are also discussed.