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381.
Changes of radon concentration in the ground have been reported to correlate with seismic activity in many places over widely varying distances from the earthquake epicenters, sometimes over 100's and occasionally over 1000's of km depending on the magnitude M of the earthquakes. For proper use of such correlations in forecasting the location and size of impending earthquakes, it would be useful to establish a relation between M and the maximum distance xM at which radon can be significantly altered by preseismic effects.We have monitored radon in the ground continuously at Blue Mountain Lake, NY starting Dec. 3. 1975 and at three locations in Alaska—Icy Bay, Yakataga, and Sand Point (starting Nov. 12, 1979; March 5, 1980; and June 29, 1980 respectively). Sample correlations from visual examination of the recent radon record and tentative use of a proposed scaling relation show a number of possible earthquake-related signals at these locations. The data are compatible with scaling relations that were derived from two separate models of premonitory elastic strains. In this work xM = 100.48M, where xM is in units of km and M ≥ 3. Since tilt and strain signals correlate similarly with magnitude and distance, it is likely that most earthquake-related radon signals are mechanically induced. 相似文献
382.
The maximum flotation response for three naturally occurring calcium minerals, apatite, calcite and fluorite with sodium oleate collector correlated directly with the minimum interfacial tension of the air/solution interface. For fluorite and apatite the minimum surface tension occurred about the mid-pH region and was attributed to the formation of pre-micellar associated species in solution. In the case of calcite the minimum was observed at high pH since the presence of high concentrations of calcium ions in solution appeared to reduce the concentration of amphililic species in the low and mid-pH regions.Microelectrophoresis data demonstrated that the three minerals acquired a negative charge in sodium oleate solution, resulting from adsorption of oleate species on the mineral surfaces.The flotation behaviour of the systems were shown to be related to the species distribution diagrams suggesting that the role of the acid soap dimer, soap dimer, molecular and lattice species could make a significant contribution to the character and composition of the interfacial films.High flotation response was explained by strong adhesion between the hydrophobic particle and bubble. It was suggested that the reduction in surface tension may not be the major factor contributing to the flotation efficiency but indicated the presence of associated surfactant species in solution which could also synergistically adsorb at the solid/liquid interface, increasing the hydrophobic character of the mineral surface. This would maximize the magnitude of the contact angle and hence the strength of the adhesion between particle and bubble. This adsorption behaviour is not in general agreement with conventionally non-hydrolyzable collector theory which is usually based on electrostatic models. 相似文献
383.
Distribution of forms of sulfur in peats from saline environments in the Florida Everglades 总被引:1,自引:0,他引:1
Although there is published information on the mechanism of sedimentary pyrite formation resulting from bacterial reduction of sulfate, little is known about the distribution of forms of sulfur, including organic, in peats. In order to increase understanding of the geochemistry of sulfur in coals, we have determined distributions of forms of sulfur in five cores of saline peat and one of brackish peat, all from areas near the Shark River and Whitewater Bay in the coastal swamps of south Florida. All concentrations vary widely with depth. Total sulfur concentrations range up to 6% of dry solids. Minor amounts of sulfur are present as H2S, S0, SO42−, and acid-soluble sulfide, but the principal forms are usually pyritic and organic. The ratio, organic/pyritic, is highly variable, but at a majority of levels in a profile is considerably greater than unity. It is inferred that topochemical factors are important in determining the distribution of sulfur forms in any element of volume. 相似文献
384.
385.
Subsidence profiles across 29 oil and gas fields in the 12,200-km2 Houston, Texas, regional subsidence area, which is caused by decline of ground-water level, suggest that the contribution of petroleum withdrawal to local land subsidence is small. Despite large volumes of petroleum production, subsidence at most fields was not increased by oil and gas withdrawal. Local increases of subsidence were detected at only six fields—Alco-Mag, Chocolate Bayou, Goose Creek, Hastings, Mykawa, and South Houston. With the exception of the 1-m subsidence from 1917 to 1925 at Goose Creek, differential subsidence across oil and gas fields was smaller by a factor of two or more than subsidence caused by aquifer compaction. At four fields—Barbers Hill, Cedar Bayou, Humble, and Pierce Junction—subsidence was substantially less than in the surrounding area. Except for Cedar Bayou, these fields are associated with shallow salt domes that partly occupy the aquifer system; for the three fields, subsidence during the periods of record came to less than half the subsidence in the surrounding area. In addition to land subsidence, faults with an aggregate length of more than 240 km (150 mi) have offset the land surface in historical time. Natural geologic deformation, ground-water pumping, and petroleum withdrawal have all been considered as potential causes of the historical offset across these faults. The minor amount of localized land subsidence associated with oil and gas fields, however, suggests that petroleum withdrawal is not a major cause of the historical faulting, at least by a differential compaction mechanism. 相似文献
386.
Jean Servant Robert Delmas Jacques Rancher Marcel Rodriguez 《Journal of Atmospheric Chemistry》1984,1(4):391-401
A partial balance of mineral N is given for the basins of two coastal rivers in a forest zone in the Ivory Coast. The dry and wet depositions on the basin surfaces is given for particulate matter (NO3
–, NH4
+). The quantity of mineral N washed away in the rivers is evaluated. The losses from leaching of the soils by rainwater are about 0.33 to 1.0% of the atmospheric depositions for NH4
+–N and 2.2 to 5.8% for NO3
––N. The yearly atmospheric input of N compounds to the ecosystem, about 1.4 g N m–2 y–1, is at least 14% of mineral N formed in the soils and is therefore quite significant. 相似文献
387.
A one-dimensional hydrostatic and incompressible numerical model based upon the shallow water wave equations is developed and used to simulate surface outflows from convective storms. Axial symmetry is employed to simulate surface outflows from storms in non-shearing environments, while slab symmetry is used to simulate unidirectional convective outflows.The model is initialized with observed data from GATE and is found to be capable of simulating the slope, depth, overall shape, and propagation speed of the outflow of tropical squall-lines.The model is used to construct a series of nomograms relating the depth of the head of the gust front to the origin and strength of the downdraft for various density differences and downdraft radii. The model predicts that convection which generates wide downdrafts originating deep within cumulonimbi and growing in strongly sheared environments (encouraging unidirectional outflows at the surface) produces the deepest gust fronts. To maintain these outflows requires the weakest downdraft velocities; when the downdrafts cease, such outflows do not decay rapidly. Conversely, the model predicts that narrow downdrafts originating near cloud base and growing in environments which encourage radial outflows, produce the shallowest gust fronts. To maintain radial outflows requires the strongest downdrafts; when the downdrafts cease, radial outflows decay most rapidly. 相似文献
388.
389.
The spectrophotometric measurements of chloro complexes of lead in aqueous HCl, NaCl, MgCl2 and CaCl2 solutions at 25°C have been analyzed using Pitzer's specific interaction equations. Parameters for activity coefficients of the complexes PbCl+, PbCl20 and PbCl3? have been determined for the various media. Values of , and were obtained for the cumulative formation constants. []. These values are in reasonable agreement with literature data. The Pitzer parameters for the PbCl ion pairs in various media were used to calculate the speciation of Pb2+ in an artificial seawater solution. 相似文献
390.
The “North American shale composite”: Its compilation,major and trace element characteristics 总被引:6,自引:0,他引:6
L.Peter Gromet Larry A. Haskin Randy L. Korotev Robert F. Dymek 《Geochimica et cosmochimica acta》1984,48(12):2469-2482
The compilation and major element composition of the “North American shale composite” (NASC) are reported for the first time, along with redeterminations for the REE and selected other elements by modern, high precision analytical methods. The NASC is not strictly of North American origin; 5 of the constituent samples are from Africa and Antarctica, and 15 are from unspecified locations. The major element composition of the NASC compares quite closely with other average shale compositions. New analyses of the NASC document that significant portions of the REE and some other trace elements are contained in minor phases (zircon and possibly other minerals) and that their uneven distribution in the NASC powder appears to have resulted in heterogeneity among analyzed aliquants. The results of this study show that the REE distributions of detrital sediments can be dependent to some extent on their minor mineral assemblages and the sedimentological factors that control these assemblages. Consequently, caution should be exercised in the interpretation of the REE distributions of sediment samples as they may be variable and biased relative to average REE distribution of the crustal rocks supplying detritus. These effects appear to be largely averaged out in sediment composites, with the result that their REE distributions are more likely to be representative of their provenances. 相似文献