N.A. Bogoslovskii and his role in the development of ideas on the age of the Ryazanian horizon and the lower cretaceous stratigraphy of Central Russia

Nikolai Andreevich Bogoslovskii (1862–1914) was a well-known soil scientist and geologist, who studied the Upper Jurassic and Lower Cretaceous deposits of Central Russia. He was the first scientist to distinguish the Ryazanian horizon and correlate it with the Berriasian deposits of Western Europe. He proposed the Lower Cretaceous stratigraphic scheme which was accepted by most Russian geologists.     

A constitutive law for thermo-plastic behaviour of rocks: an analogy with clays

Thermo-mechanical behaviour of rocks shows phenomenological similarities to that of clays. A visible decrease of strength and an increase in ductility at elevated temperatures are observed in drained conditions. In undrained conditions the strength decrease is even more dramatic and the ductile behaviour may turn into the brittle one, if a sufficient amount of water is present in the pores at the start of the process, or it is being released during heating by the decomposition of hydrous minerals. Applying a thermo-plasticity theory, major macroscopical characteristics of behaviour may be modelled. According to this theory, the elastic domain is postulated as temperature dependent, shrinking with temperature; heating may result in expansive or compactive volumetric irreversible strain depending on the confining stress. This theory is applied to the modelling of heat effects on local changes of permeability around a cylindrical nuclear waste container disposed off in deep clays, and in the numerical simulation of a mechanism initiating deep earthquakes.     

On the determination of the diffusion coefficient of heterogeneous aerosols by the dynamic method

Summary It is shown that the marked influence of the air-flow on the value of the diffusion coefficient as determined by the dynamic method can be fully explained when heterogeneity of the condensation nuclei in the aerosol is assumed. A theory of the dynamic method for heterogeneous aerosols is given on the assumption that the diffusion loss of a mixture of condensation nuclei of different diffusion coefficients is the sum of the diffusion losse of its components. Procedures for resolving heterogeneous aerosols into their components using the dynamic method are developed. The accuracy attainable by one of the methods which requires no assumptions on the number of components in the aerosol under investigation is illustrated by a numerical example.

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Zusammenfassung Es wird gezeigt, dass der bemerkenswerte Einfluss der Luftstromgeschwindigkeit auf die Grösse des mit der dynamischen Methode bestimmten Diffusionskoeffizienten völlig erklärt werden kann, wenn Heterogenität der Kondensationskerne im Aerosol angenommen wird. Eine Theorie der dynamischen Methode für heterogene Aerosole wird unter der Annahme, dass der Diffusionsverlust eines Gemisches von Kondensationskernen mit verschiedenen Diffusionskoeffizienten gleich der Summe der Diffusionsverluste ihrer Komponenten ist, gegeben. Verfahren der Zerlegung heterogener Aerosole in ihre Komponenten mittels der dynamischen Methode werden entwickelt. Die mit einem der Verfahren, welches keine Annahme über die Zahl der in dem zu untersuchenden Aerosol vorhandenen Komponenten benötigt, erreichbare Genauigkeit wird an einem numerischen Beispiel illustriert.

     

High temperature dehydroxylation of muscovite-2M1: a kinetic study by in situ XRPD

Muscovite-2M₁ shows a major phase transition at about 800°C, which is generally attributed in the literature to the structural dehydroxylation process, although a number of structural models have been proposed for the dehydroxylated phase, and different transformation mechanisms have also been put forward. The observed first order transformation involves an increase in the cell volume, and it is not clear to date how the cell expansion is related to the loss of hydroxyl groups. The phase change has been re-investigated here by in situ high temperature powder diffraction, both in non-isothermal and isothermal modes, to combine for the first time the structural and the kinetic interpretation of the transformation. The results unequivocally confirm that the reaction taking place in the temperature range 700–1000°C is truly a dehydroxylation process, involving the nucleation and growth of the high temperature dehydroxylated phase, having Al in 5-fold coordination. Structural simulations of the basal peaks of the powder diffraction patterns indicate that the model originally proposed by Udagawa et al. (1974) for the dehydroxylated phase correctly describes the high temperature phase. The kinetic analysis of the isothermal data using an Avrami-type model yields values for the reaction order compatible with a reaction mechanism limited by a monodimensional diffusion step. Apparent activation energy of the process in vacuum is about 251 kJ/mol. Experiments carried out at temperatures much higher than the onset temperature of the reaction show that the dehydroxylation reaction overlaps with the reaction of formation of mullite, the final product in the reaction pathway. Received: 24 April 1998 / Revised, accepted: 12 October 1998     

The Development of Laser Ablation ICP-MS and Calibration Strategies: Examples from the Analysis of Trace Elements in Volcanic Glass Shards and Sulfide Minerals

This contribution presents a review of the recent developments in laser ablation inductively coupled plasma-mass spectrometry. We describe the important developments which have occurred in the laser systems used, leading to a spatial resolution of around 20 (im, and give an overview of the major instrument developments which have affected the geological applications of laser ablation ICP-MS. We describe the calibration of laser ablation for the analysis of trace elements in two different matrices: volcanic glass shards and sulfide minerals. We show how single glass shards can be analysed using the National Institute of Standards and Technology (NIST) glass certified reference materials for calibration and demonstrate the effect of using single spot analyses compared to rastering of the calibration sample. We show the importance of inter-shard variation and demonstrate that averaged single shard analyses produce data which compare well with bulk analyses. The calibration of the laser system for sulfide mineral analysis is discussed and two different strategies are proposed, one using spiked pressed powder pellets of sulfides and the other metal reference materials. We present conclusions and recommendations for the calibration of laser ablation ICP-MS instruments.     

Biogeochemistry of the Madeira river basin

A biogeochemical characterization of the Madeira river basin has been made to evaluate the local and global effects of possible alterations in the ecosystem caused by recent intensive occupation in Rondonia state. During the period April 1983—January 1986, sampling was made both by land and river along the tributaries and main channel of the Madeira river. The parameters analysed lead to a detailed study of the physicochemical quality of the waters of the basin and their relationship with the local geology, associated with the transport of solid material and the hydrological behavior of the ecosystem.Penman's method adapted to tropical rainforest conditions was used to evaluate the potential evapotranspiration for the basin. Estimated potential evapotranspiration was 1420 mm/y, 77% due to the energy balance. Real evapotranspiration was 94% of the estimated potential and the main residence time of the rain water in the basin was 2 months. The isotopic behavior of Hydrogen and Oxygen in the river waters of the region was typical of great rivers, the values being more positive during the dry season and more negative during the rainy season. An isotopic gradient of ¹⁸O 0.038 ()/100 km, was established from Porto Velho station to the estuary, which was considered low when compared with the value of 0.063 ()/100 km, obtained for the Amazon river.In general, the waters of the tributaries were poor in dissolved ion species when compared with the main channel of the Madeira river. Seasonal variation in the transport of suspended sediment kept the same pattern, greater transport being observed on rising water than during high water. A transport of 2.85 million tons per day was observed in the Madeira river near the mouth.     

Processes affecting deposition of sediment in a small, morphologically complex lake

Devil Lake is morphologically complex as a result of Pleistocene glacial erosion of the Frontenac Axis of the Canadian Shield. In order to assess the processes causing highly variable sedimentation in the lake, we monitored currents, suspended sediment and temperature in the lake before and during autumn overturn in 2002. Strong summer thermal stratification (stability number to 0.11 s^–1 declining with the approach of overturn) was insufficient to prevent a dynamic response in the hypolimnion to wind forcing. Superimposed on a gradual increase in suspended sediment concentration in the last weeks of stratification from less than 2 g/l to about 30 g/l were shorter-term rises lasting up to several days. Associated with these events was an increase in particle size of the sediment from a mode of 40–50 to 150–200 m ascribed to flocculation from primary particles. These events culminated in rapid (<1 h) clearing of the water associated with strong, sustained winds over the lake, especially from the southwest. After overturn, the events were more frequent, and flocculation was unable to develop as well in the more vigorous circulation. However, currents in the hypolimnion occurred throughout the period before, during and after overturn with speed related to wind speed, but direction largely independent of wind direction. The results represent an approach to understanding the nature of sedimentary processes and thus to strengthening the use of sedimentary records as proxy in environmental and paleoenvironmental assessment.     

Carbon chemistry of Luna 16 and Luna 20 samples

Luna 16 and Luna 20 samples were analyzed for volatilizable species using vacuum pyrolysis to 1400°C. The major gaseous products evolved (ranging from 10–650 μg/g) were H₂O, CO, CO₂, N₂ and CH₄. Minor components (all < 10 μg/g) included NH₃, HCN, NO, SO₂, H₂S, C₂H₂, C₂H₄, C₂H₆, C₃H₆ and higher hydrocarbons, benzene, toluene, and the polymeric contaminants Teflon^® and silicone oil. The total carbon and nitrogen contents (μg/g) for these sieved samples (< 125 μm) were: Luna 16—C 418, N 134 and Luna 20—C 380, N 80.     

Some results of night-time scintillations at low latitude

Ionospheric scintillation observations of VHF radio signals from FLEETSAT satellite (73°E longitude) at Bhopal from January 1990 to December 1990 have been used to study the characteristic variations of scintillation activity. It is found that scintillation occurrence is essentially a night-time phenomenon and day-time scintillations are very rare. Annual average nocturnal variation of percentage occurrence of scintillations shows maximum at around 2100–2200 hours LT. Seasonally, scintillations are most prominent during equinoxes and least during summer. Geomagnetic disturbances tend to decrease the occurrence of scintillations in the pre-midnight period.