Variability in the speciation of iron in the northern North Sea

Variations in the speciation of iron in the northern North Sea were investigated in an area covering at least two different water masses and an algal bloom, using a combination of techniques. Catalytic cathodic stripping voltammetry was used to measure the concentrations of reactive iron (Fe_R) and total iron (Fe_T) in unfiltered samples, while dissolved iron (Fe_D) was measured by GFAAS after extraction of filtered sea water. Fe_R was defined by the amount of iron that complexed with 20 μM 1-nitroso-2-napthol (NN) at pH 6.9. Fe_T was determined after UV-digestion at pH 2.4. Concentrations of natural organic iron complexing ligands and values for conditional stability constants, were determined in unfiltered samples by titration. Mean concentrations of 1.3 nM for Fe_R, 10.0 nM for Fe_T and 1.7 nM for Fe_D were obtained for the area sampled. Fe_R concentrations increased towards the south of the area investigated, as a result of the increased influence of continental run off. Fe_R concentrations were found to be enhanced below the nutricline (below 40 m) as a result of the remineralisation of organic material. Enhanced levels of Fe_T were observed in some surface samples and in samples collected below 30 m at stations in the south of the area studied, thought to be a result of high concentrations of biogenic particulate material and the resuspended sediments respectively. Fe_D concentrations varied between values similar to those of Fe_T in samples from the north of the area to values similar to those of Fe_R in the south. The bloom was thought to have influenced the distribution of both Fe_R and Fe_T, but less evidence was observed for any influence on Fe_R and Fe_D. The concentration of organic complexing ligands, which could possibly include a contribution from adsorption sites on particulate material, increased slightly in the bloom area and in North Sea waters. Iron was found to be fully (99.9%) complexed by the organic complexing ligands at a pH of 6.9 and largely complexed (82–96%) at pH 8. The ligands were almost saturated with iron suggesting that the ligand concentration could limit the concentration of iron occurring as dissolved species.     

A Wet/Wet Differential Pressure Sensor for Measuring Vertical Hydraulic Gradient

Vertical hydraulic gradient is commonly measured in rivers, lakes, and streams for studies of groundwater–surface water interaction. While a number of methods with subtle differences have been applied, these methods can generally be separated into two categories; measuring surface water elevation and pressure in the subsurface separately or making direct measurements of the head difference with a manometer. Making separate head measurements allows for the use of electronic pressure sensors, providing large datasets that are particularly useful when the vertical hydraulic gradient fluctuates over time. On the other hand, using a manometer-based method provides an easier and more rapid measurement with a simpler computation to calculate the vertical hydraulic gradient. In this study, we evaluated a wet/wet differential pressure sensor for use in measuring vertical hydraulic gradient. This approach combines the advantage of high-temporal frequency measurements obtained with instrumented piezometers with the simplicity and reduced potential for human-induced error obtained with a manometer board method. Our results showed that the wet/wet differential pressure sensor provided results comparable to more traditional methods, making it an acceptable method for future use.     

Rapid changes in the sodium exosphere of Mercury

We imaged Mercury in sodium D₁ and D₂ emission for 6 days during the period 13–20 November 1997 using a 10×10-arc s aperture image slicer coupled to a high-resolution spectrograph. We corrected the sodium images for smearing by the terrestrial atmosphere by computing the actual seeing function from surface reflection images, and used this function to correct the sodium images. During the period of observation, large daily changes took place in both the total amount of sodium and its distribution over the planet. Total sodium increased by a factor of about 3 during this period. The sodium emission was brightest at longitudes near the subsolar longitude in the range 130–150°, with excess sodium at northern latitudes on some days, and excess sodium at southern latitudes on other days. There are no obviously outstanding geologic features at this longitude. The rapid changes observed during this period suggest a connection with solar activity, since the planet itself is apparently geologically inactive. The F10.7 cm solar flux during this period varied only slightly, with an increase of about 15%, probably insufficient to account for the observed changes. However, there were a number of coronal mass ejection (CME) events, some of which were directed towards the general area of Mercury. We suggest that the changes in the visible neutral sodium atmosphere might be a result of the effect of CMEs on Mercury.     

Bathymetry of three deep-sea channels in the northeast and central Tufts Abyssal Plain

The drainage pattern in the northeast and central Tufts Abyssal Plain is described in detail. Satellite navigation on the systematic survey has allowed precise location of the major channel systems of the northeast Pacific Ocean. Two hundred channel profiles were collected from the echograms showing the Moresby-Scott, Mukluk, and Horizon Channel Systems trending in either a southwestward or westward direction across this section of the Tufts Plain. The channel profiles illustrate the prominence of the higher and wider right-hand levee (facing downstream). The Moresby-Scott Channel System disperses in the form of several distributaries throughout the area studied, and is probably responsible for much of the sediment deposits. Unlike the Moresby-Scott, the Mukluk extends throughout the survey area as a solitary channel with one minor branch. The Horizon Channel crosses the Sedna Fracture Zone east of the Sedna Seamount and terminates in distributary fashion in the central portion of the Tufts Plain. The Moresby-Scott, Mukluk, and Horizon Channels form one major system which encompasses the entire northeast and central Tufts Abyssal Plain.     

'Stokes imaging' of the accretion region in magnetic cataclysmic variables — I. Conception and realization

Modelling the polarized cyclotron emission from magnetic cataclysmic variables has been a pivotal technique for determining the structure of the accretion zones on the white dwarf. To date, model solutions have been obtained from trial fits to the intensity and polarization data, which have been constructed from emission regions (for example arcs and spots) put in by hand. These models were all inferred indirectly from arguments based on the polarization and X-ray light curves.   We present a more analytical and objective technique using optimization by a genetic algorithm, Tikhonov regularization and Powell's method that robustly models the details of polarized emission.   To demonstrate the success of this technique, we show the results of several simulations in which we calculated the intensity and polarization curves from arbitrarily shaped emission regions on the surface of a sphere and then applied our code to these curves to recover the original test data. We also show how adding artificial noise affects the outcome of the optimization technique.     

Does upward seepage of river water and storm water runoff determine water quality of urban drainage systems in lowland areas? A case study for the Rhine–Meuse delta

The water quality of urban drainage ditches in lowlands in the Rhine‐Meuse delta was analysed with principal component analysis (PCA) during a dry period and a rain storm, and related to the seepage of polluted river water and effective impervious area (EIA). This was done in order to test the hypothesis that seepage of river water and storm water runoff from impervious areas strongly determine the water quality of urban drainage systems along large lowland rivers. Our analysis revealed that upward seepage of groundwater originating from rivers Rhine and Meuse was positively correlated with nitrate, potassium, sodium and chloride and negatively correlated with alkalinity, calcium, magnesium and iron. EIA was correlated with very few environmental variables (i.e. phosphate, pH and iron in the dry period and iron during the rain storm). Nickel and zinc concentrations generally exceeded the maximum allowable concentrations (MAC), while lead and phosphorus concentrations were just above the nutrient standards and MAC in a few locations during the rain storm. To optimize water quality in urban water systems, attention should be paid to all sources of pollution and not only to EIA. The impact of local groundwater seepage originating from large rivers in lowlands on the chemistry of urban water systems is often underestimated and should be taken into account when assessing water quality and improving water quality status. Copyright © 2009 John Wiley & Sons, Ltd.     

Simultaneous optical polarimetry and X-ray observations of the magnetic CV CP Tuc (AX J2315−592)

CP Tuc (AX J2315–592) shows a dip in X-rays which lasts for approximately half the binary orbit and is deeper in soft X-rays compared with hard X-rays. It has been proposed that this dip is due to the accretion stream obscuring the accretion region from view. If CP Tuc were a polar, as has been suggested, then the length of such a dip would make it unique amongst polars since in those polars in which a dip is seen in hard X-rays the dip lasts for only 0.1 of the orbit. We present optical polarimetry and RXTE observations of CP Tuc which show circular polarization levels of ∼10 per cent and find evidence for only one photometric period. These data confirm CP Tuc as a polar. Our modelling of the polarization data implies that the X-ray dip is due to the bulk of the primary accretion region being self-eclipsed by the white dwarf. The energy dependence of the dip is due to a combination of this self-eclipse and also the presence of an X-ray temperature gradient over the primary accretion region.