塔里木盆地原油的轻烃分类及成因研究

通过对塔里木盆地不同地区不同层位205个原油样品的色谱分析研究,应用其轻烃的组分作关系图,将塔里木盆地原油划分为海相油(A)、湖相油(B)和煤成油(C)三大类。海相烃源岩中过渡金属及其配位体结构有利于五环优势,导致其生成的海相原油(A)具五环优势;陆相烃源岩中过渡金属及其配位体结构有利于三环优势和六环优势,导致其生成的陆相原油(B,C)具三环优势和六环优势。应用正庚烷值与异庚烷值作关系图,将塔里木盆地原油划分为海相油(A)、陆相油(B+C)两大类。海相油(A)沿脂肪族干酪根曲线分布,陆相油(B+C)大多沿芳香族干酪根曲线分布。对于同类烃源岩,随着埋深和压力不断增加,烃源岩中干酪根自由体积将不断减小,对六环优势抑制最大,对五环优势抑制较大,对三环优势抑制较小,对直接裂解抑制最小,导致其生成的原油中正庚值和异庚烷值随埋深增加而增加。     

春播期亚欧环流形势的客观分型及其在物理-统计预报中的应用

本文对1972—1978年七年春播期(3月27日—5月10日)500mb亚欧环流形势,应用变K-均值聚类法进行客观分型,共得九型。对它们和春播期四种主要中期天气过程——连阴雨和低温连阴雨、过程性天气、连晴,用对应分析方法数量化。以环流形势与同期的北半球500mb波谱分析中选出的物理量作为因子,对天气过程类型作出了逐步回归和AID聚类的统计推断。 对1979、80年春播期作了预报检验,效果尚好。     

Climatic regime shift and decadal anomalous events in China

Climatic time series from historical documents and instrumental records from China showed temporal and regional patterns in the last two to three centuries, including two multidecadal oscillations at quasi-20-year and quasi-70-year timescales revealed by signal analysis from wavelet transform. Climatic anomalous events on the decadal timescale were identified based on the two oscillations when their positive (or negative) phases coincide with each other to amplify amplitude. The coldest event occurred in the decade of 1965–1975 in eastern China, while the periods of 1920–1930, 1940–1950, and 1988–2000 appeared to be warmer in most parts of China. For the precipitation series in northern China, the dry anomalous event was found in the late 1920s, while the wet anomalous event occurred in the 1950s. A severe drought in 1927–1929 in northern China coincided with the anomalous warm and dry decade, caused large-scale famine in nine provinces over northern China. Climatic anomalous events with a warm-dry or cold-wet association in the physical climate system would potentially cause severe negative impacts on natural ecosystem in the key vulnerable region over northern China. The spatial pattern of summer rainfall anomalies in the eastern China monsoon region showed an opposite variations in phase between the Yellow River Valley (North China) and the mid-low Yangtze River Valley as well as accompanied the shift of the northernmost monsoon boundary. Climatic regime shifts for different time points in the last 200 years were identified. In North China, transitions from dry to wet periods occurred around 1800, 1875, and 1940 while the transitions from wet to dry periods appeared around 1840, 1910, and the late 1970s. The reversal transition in these time points can also be found in the lower Yangtze River. Climatic regime shifts in China were linked to the interaction of mid- and low latitude atmospheric circulations (the westerly flow and the monsoon flow) when they cross the Tibetan Plateau in East Asia.     

呼和浩特市降水化学特征分析

对2006年呼和浩特市降水离子监测资料进行分析,结果表明:降水呈碱性,季节分布明显,夏季降水集中且pH值为全年最低,冬季降水量少,pH值较高;SO42-离子为主要致酸离子,阳离子中Ca2+,Mg2+离子的浓度很高;降水中主要成分之间相关性显著,Ca2+的中和作用较强;降水气团的后向轨迹分析表明蒙古国的沙漠地区是呼和浩特冬春季碱性降水的主要来源,夏季较低的pH值降水则部分源于我国的华中、华北地区的酸性污染物中长距离输送。     

正态分布检验在地下水检测质量控制中的应用

对地下水调查中37种必测组分检测过程的替代物进行筛选,应用D’Agostino法对替代物的测量结果进行正态性检验。利用正态分布函数"3σ"原则,定义了各替代物质量控制指标的有效区间。应用正态函数随机变量的数学期望和方差,计算得到各替代物有效区间内的正态函数分布概率均大于97%,替代物过程能力指数计算结果表明,二溴氟代甲烷、甲苯-d8、对溴氟苯、1,2-二氯苯-d4、氟苯等挥发性有机污染物分析过程选用的替代物质量控制过程处于稳定的监控状态;2,4,5,6-四氯间二甲苯、二丁基氯菌酸酯、p-三联苯、十氯联苯等半挥发性有机污染物分析过程选用的替代物监控指标分析过程能力不足。建议参考美国EPA方法中有关监控指标质量控制区间的要求,适当放宽对半挥发性有机物检测流程中选用的替代物质量控制区间的有效范围。正态分布在地下水检测过程质量控制中的应用,为实验室检测过程的质量管理提供了科学、有效的数学依据。     

车贝雪夫多项式的约简算法

解释了文献「１」中关于化整后的车贝雪夫多项式约简处理的技术原理,给出了一种可快速实现多项式约简处理的求算方法。     

Land surface temperature shaped by urban fractions in megacity region

The influence of spatial scales on surface fluxes is an interesting but not fully investigated question. This paper presents an analysis on the influence of spatial scales on surface fluxes in the north Tibetan Plateau based on eddy covariance (EC) and large aperture scintillometer (LAS) data at site Nagqu/BJ, combined with the land surface temperature (LST) and normalized difference vegetation index (NDVI) of moderate-resolution imaging spectroradiometer (MODIS). The analysis shows that sensible heat fluxes calculated with LAS data (H_LAS) agree reasonably well with sensible heat fluxes calculated with EC data (H_EC) in the rain and dry seasons. The difference in their footprints due to the wind direction is an important reason for the differences in H_EC and H_LAS. The H_LAS are statistically more consistent with H_EC when their footprints overlap than when their footprints do not. A detailed analysis on H_EC and H_LAS changes with net radiation and wind direction in rain and dry season indicates that the spatial heterogeneity in net radiation created by clouds contributes greatly to the differences in H_EC and H_LAS in short-term variations. A significant relationship between the difference in footprint-weighted averages of LST and difference in H_EC and H_LAS suggests that the spatial heterogeneity in LST at two spatial scales is a reason for the differences in H_EC and H_LAS and that LST has a positive correlation with the differences in H_EC and H_LAS. A significant relationship between the footprint-weighted averages of NDVI and the ratio of sensible heat fluxes at two spatial scales to net radiation (H/Rn) in the rain season supports the analysis that the spatial heterogeneity in canopy at two spatial scales is another reason for differences in H_EC and H_LAS and that canopy has a negative correlation with (H/Rn). An analysis on the influence of the difference in aerodynamic roughness lengths at two spatial scales on sensible heat fluxes shows that the influence is greater in the dry season and smaller in the rain season because the ratio of z_{0m_LAS} to z_{0m_EC} is big in the dry season and is close to 1.0 in the rain season. This study on spatial scales on surface fluxes in the Tibetan Plateau will be helpful in analyzing and understanding its influence on climate.     

2008年1月一次强雨雪过程的诊断分析

采用NCEP1°×1°客观再分析资料和常规观测资料,对2008年1月25—29日发生在长江中下游地区的强雨雪过程进行诊断分析,结果表明,低空急流与强雨雪有着密切关系,强雨雪的发生需具备一定的温度条件以及水汽场与动力场的耦合机制。对强雨雪过程的湿Q矢量诊断分析表明,700hPa湿Q矢量辐合区以及850hPa锋生函数正值区与强雨雪区对应较好,对雨雪天气的发生有着很好的指示意义。湿位涡特征分析表明,此次强雨雪过程发生在层结稳定的大气中且垂直涡度发展较强。     

年代际气候变率问题的研究

对年代际气候变率的研究工作和主要结果作了综合评述，并对该领域的研究前景作了一定的阐述。