Variation in DOC and trace metal concentration along the heavily urbanized basin in Kathmandu Valley,Nepal

Water samples were analyzed for DOC and trace metals from Bagmati River within Kathmandu valley, Nepal, to understand the variation trends of DOC and trace metals and their relationship along the drainage network. The variability in organic matter and wastewater input within the Bagmati drainage basin appeared to control DOC and most of the trace metal concentration. The large input of organic matter and wastewater creates anoxic condition by consuming dissolved oxygen and releasing higher concentrations of DOC, trace elements such as nickel, arsenic, barium, cadmium, and copper with downstream distance. Concentrations of DOC and trace metals like barium and zinc showed strong relationships with human population density and suggest that human activities have strong control on these parameters along the drainage network. The DOC and most of the trace metal concentration increased with downstream distance and appeared to be directly associated with human activities. The variation trends of most of the trace metals appeared to be the same; however, concentration varied widely. Inputs of organic matter and wastewater due to human activities appeared directly to be associated for the variation of DOC and trace metals along the Bagmati drainage network within Kathmandu valley.     

Plant Cover,Herbivory, and Resiliency in a Cape Cod Salt Marsh: Multi-year Responses and Recovery Following Manipulation of Nutrients and Competition

To assess responses and recovery of salt marsh grass species, we manipulated external nutrient supply and removed shoots of Spartina alterniflora or Spartina patens from fertilized and control plots in a Massachusetts marsh. The pulse-and-recovery experiment included treatments for 5 years, and recovery for an additional 7 years. Responses of these potential competitors sensitively depended on local contingencies of elevation and nutrient dose, and, moreover, the differences in outcomes were emphasized at longer time scales. Local contingencies became manifest as differences in responsiveness and resiliency of the different grass species, with differing time courses and longer-term outcomes as to what species were present. These features might explain the diverse results obtained in shorter-term salt marsh experiments, and provide a view of the complex suite of species-specific and external environmental variables that may control competitive interactions in general.     

Multidisciplinary inferences on a newly recognized active east‐dipping extensional system in Central Italy

We use a multidisciplinary approach to gather preliminary evidence for a Quaternary east‐dipping extensional detachment in Central Italy. This structure crops out in the Sabini‐Eastern Simbruini (SES) and would be hidden at mid‐crustal depths beneath the L'Aquila 2009 (M_w6.3) epicentral area. The SES geometry is reconstructed through geological mapping, structural analysis and seismic line interpretation. The geometry of the mid‐crustal segment, referred to as the Ocre Segment (OS), is interpreted through seismological analyses of the largest aftershock (M_w5.4) of the L'Aquila 2009 sequence. The kinematic compatibility between the SES and the OS under a common SW–NE tensional field is tested through stress inversion of both geological and seismological data. The reliability of OS activation is tested through slip tendency analysis. Like other Italian cases, the SES and the OS are preliminarily interpreted as expressions at different depths of the same unknown east‐dipping extensional detachment, characterized by a ramp–flat–ramp geometry.     

Use of phytoplankton species indicators to track the origin of phytoplankton blooms in Willapa Bay, Washington

We focus on the question of whether high phytoplankton production events observed in a United States Pacific Northwest estuary consist of estuarine species blooms fueled by oceanic nutrient input or reflect offshore oceanic blooms that have advected into the estuary. Our approach is to use certain phytoplankton species as indicators associated with water mass origin, either estuarine or oceanic, to help resolve this question in Willapa Bay, Washington. We used species analysis and primary production data from 10 selected dates in May–September of 1998 and 1999, representing periods of high through low productivity. Out of 108 phytoplankton species identified from Willapa Bay, nine were selected and tested as indicators of oceanic species, six as estuarine, and two as surf zone. Our test results demonstrated the oceanic and estuarine species to be satifactory indicators of source waters. The prevalence of these species indicators in our samples revealed that the highest primary production and the appearance ofPseudo-nitzschia spp. were associated with oceanic intrusions of phytoplankton biomass into Willapa Bay. While the largest blooms were oceanic in origin, numerous medium-sized production events were from either oceanic, surf zone, or estuarine sources, indicating a complex situation.     

GIS-based hazard mapping and zonation of debris flows in Xiaojiang Basin,southwestern China

Debris flow sites were identified at 140 locations in the Xiaojiang Basin in Yunnan province, southwestern China. Their spatial distribution and catchment characteristics are described in detail on the basis of previous research, air photo interpretation, field investigation and mapping using Geographical Information Systems (GIS). Using a statistical approach, a quantitative model of hazards assessment and zonation was developed through synthesis analysis of basin areas, gradients, and the relative reliefs of these debris flow sites. In terms of debris flow hazard assessment, areas within the Xiaojiang Basin can be classified as severe, heavy and light hazard regions.     

Surface water–groundwater interaction and chemistry in a mineral-armored hydrothermal outflow channel, Yellowstone National Park, USA

Small quantities of groundwater interact with hydrothermal surface water to drive in-stream geochemical processes in a silica-armored hot-spring outflow channel in Yellowstone National Park, USA. The objective of this study was to characterize the hydrology and geochemistry of this unique system in order to (1) learn more about the Yellowstone Plateau’s subsurface water mixing between meteoric and hydrothermal waters and (2) learn more about the chemical and physical processes that lead to accumulation of streambed cements, i.e., streambed armor. A combination of hydrological, geochemical, mineralogical, microscopic, and petrographic techniques were used to identify groundwater and surface-water exchange. Interaction could be identified in winter because of differences in surface water and groundwater composition but interaction at other times of the year cannot be ruled out. Dissolved constituents originating from groundwater (e.g., Fe(II) and Mg) were traced downstream until oxidation and/or subsequent precipitation with silica removed them, particularly where high affinity substrates like cyanobacterial surfaces were present. Because the stream lies in a relatively flat drainage basin and is fed mainly by a seasonally relatively stable hot spring, this system allowed study of the chemical processes along a stream without the obscuring effects of sedimentation.     

Assessing Nitrogen Dynamics Throughout the Estuarine Landscape

Assessing nitrogen dynamics in the estuarine landscape is challenging given the unique effects of individual habitats on nitrogen dynamics. We measured net N₂ fluxes, sediment oxygen demand, and fluxes of ammonium and nitrate seasonally from five major estuarine habitats: salt marshes, seagrass beds (SAV), oyster reefs, and intertidal and subtidal flats. Net N₂ fluxes ranged from 332?±?116 μmol?N-N₂?m^?2?h^?1 from oyster reef sediments in the summer to ?67?±?4 μmol?N-N₂?m^?2?h^?1 from SAV in the winter. Oyster reef sediments had the highest rate of N₂ production of all habitats. Dissimilatory nitrate reduction to ammonium (DNRA) was measured during the summer and winter. DNRA was low during the winter and ranged from 4.5?±?3.0 in subtidal flats to 104?±?34 μmol?¹⁵NH ₄ ⁺ ?m^?2?h^?1 in oyster reefs during the summer. Annual denitrification, accounting for seasonal differences in inundation and light, ranged from 161.1?±?19.2 mmol?N-N₂?m^?2?year^?1 for marsh sediments to 509.9?±?122.7 mmol?N-N₂?m^?2?year^?1 for SAV sediments. Given the current habitat distribution in our study system, an estimated 28.3?×?10⁶?mol of N are removed per year or 76 % of estimated watershed nitrogen load. These results indicate that changes in the area and distribution of habitats in the estuarine landscape will impact ecosystem function and services.     

Organic versus inorganic trace metal complexes in sulfidic marine waters—some speculative calculations based on available stability constants

A theoretical model has been developed in order to test the hypothesis that simple organic acids are the chief agents of trace metal solubility in H₂S-rich marine waters. The model utilizes stability constant given by Sillen and Martell (1964, 1971) and assumes that the free cation activity of each metal is controlled by simple solubility products. Typical values of pH, pS and Eh are employed in the calculations. The results indicate that free amino acids and hydrocarboxylic acids probably are not effective but that bisulfide and polysulfide complexes may be the chief agents of trace metal solubility. To the extent that it is present, the effect of dissolved organic matter on trace metal solubility probably resides in highly polymerized substances (e.g. humic acids).     

Doubtful Events Reported in Current Italian Earthquake Catalogues: The Medieval Earthquakes of Subiaco (Central Italy)

Within the framework of a study of the seismicity of the Aniene Valley (Central Italy), we analysed the medieval earthquakes of Subiaco (1216, 1227, 1299), the largest events reported for the area. Our main goal was to investigate some doubtful events reported in earthquake catalogues and, as such, currently utilised for seismic hazard estimates. A careful screening of the oldest available sources and their filiation pattern up to the present pointed out the uncertainty on the date and nature of these phenomena. A multidisciplinary approach based on the joint analysis of archaeological, geomorphologic and historical evidence allowed us to propose new interpretations concerning these events and their significance for the assessment of seismic hazard in the Aniene Valley. The main conclusion is that the dates of the 1216 and 1227 events are fairly unsupported. In particular, the 1216 earthquake could be dated back to between AD 1159 and 1181.