Structural and magnetic properties of Co2Al4Si5O18 and Mn2Al4Si5O18 cordierite

The crystal structures, lattice dynamics and magnetic properties of synthetic Co-cordierite, Co₂Al₄Si₅O₁₈, and Mn-cordierite, Mn₂Al₄Si₅O₁₈ have been studied by neutron powder diffraction, infrared spectroscopy and magnetisation measurements. Due to different synthesis conditions, the Co-cordierite used here crystallised in the hexagonal α-cordierite structure with a disordered Si/Al distribution in the framework, while for the Mn-cordierite the orthorhombic β-structure has been determined. The experimentally determined paramagnetic moments, _exp (Mn) = 5.47(6) _B and _exp (Co) = 3.88(4) _B , are in good agreement with theoretical predictions for octahedrally coordinated Mn²⁺ and Co²⁺, respectively. In both compounds there is no magnetic long-range order down to at least 1.5 K. However, the onset of an anti-ferromagnetic short-range correlation of magnetic moments along [001] has been observed for Mn-cordierite by magnetisation and neutron diffraction measurements. This short-range magnetic correlation becomes evident from diffuse scattering observed at 2 K. The diffuse scattering has been interpreted in terms of a Blech-Averbach function. Received: 30 June 1998 / Revised, accepted: 3 March 1999     

Investigating groundwater flow components in an Alpine relict rock glacier (Austria) using a numerical model

Relict rock glaciers are complex hydrogeological systems that might act as relevant groundwater storages; therefore, the discharge behavior of these alpine landforms needs to be better understood. Hydrogeological and geophysical investigations at a relict rock glacier in the Niedere Tauern Range (Austria) reveal a slow and fast flow component that appear to be related to the heterogeneous structure of the aquifer. A numerical groundwater flow model was used to indicate the influence of important internal structures such as layering, preferential flow paths and aquifer-base topography. Discharge dynamics can be reproduced reasonably by both introducing layers of strongly different hydraulic conductivities or by a network of highly conductive channels within a low-conductivity zone. Moreover, the topography of the aquifer base influences the discharge dynamics, which can be observed particularly in simply structured aquifers. Hydraulic conductivity differences of three orders of magnitude are required to account for the observed discharge behavior: a highly conductive layer and/or channel network controlling the fast and flashy spring responses to recharge events, as opposed to less conductive sediment accumulations sustaining the long-term base flow. The results show that the hydraulic behavior of this relict rock glacier and likely that of others can be adequately represented by two aquifer components. However, the attempt to characterize the two components by inverse modeling results in ambiguity of internal structures when solely discharge data are available.     

Use of the Acoustic Energy Meter (AEM) for rapid geomorphological field assessment of rock hardness: comparison with Schmidt hammer R‐value

Rapid, field‐based assessments of rock hardness are required in a broad range of geomorphological investigations where rock intact strength is important. Several different methods are now available for taking such measurements, in particular the Schmidt hammer, which has seen increasing use in geomorphology in recent decades. This is despite caution from within the engineering literature regarding choice of Schmidt hammer type, normalization of rebound (R‐) values, surface micro‐roughness, weathering degree and moisture content, and data reduction/analysis procedures. We present a pilot study of the use of an Acoustic Energy Meter (AEM), originally produced, tested and developed within the field of underground mining engineering as a rapid measure of rock surface hardness, and compare it with results from a mechanical N‐Type Schmidt hammer. We assess its capabilities across six lithological study sites in southeast Queensland, Australia, in the Greater Brisbane area. Each rock exposure has been recently exposed in the 20th/21st century. Using a ‘paired’ sampling approach, the AEM G‐value shows an inverse relationship with Schmidt hammer R‐value. While both devices show variability with lithology, the AEM G‐values show less scatter than the Schmidt hammer. We conclude that each device can contribute to useful rock hardness testing in geomorphological research, but the AEM requires further field testing in a range of environments, and in particular on older and naturally‐exposed rock surfaces. Future evaluations can extend this pilot study by focusing on sampling procedures, energy sources, and data reduction protocols, within the framework of a comparison study with other rock hardness testing apparatus. Copyright © 2016 John Wiley & Sons, Ltd.     

Trace elements in streambed sediments of floodplains: consequences for water management measures

The occurrence of trace metals was studied at the interface between groundwater and the drainage system of a large floodplain in NE Germany, the Oderbruch region. Depending on the predominant hydraulic connectivity between groundwater and the drainage channels, the geochemical environment creates a high variability in the accumulation of Fe, Mn, Cd, Zn, Cu, and As. The mobility of the trace metals depends on spatial variable redox transition zones which act as geochemical barriers between the anaerobe aquifer and the oxic surface waters. In drainage ditches with high exchange flow between groundwater and surface water the transition zone is small and unstable with a low retention potential for trace metals. Decreasing hydraulic gradients and respectively decreasing base flow cause the change for an extensive transition zone with increasing trace metal accumulation in the channel sediments. The accumulation is mainly controlled by oxidation and degassing of CO₂. In the streambed sediments of channels which periodically run dry an effective chemical barrier can be observed. This Fe dominated oxic horizon controls the accumulation of Mn > Cu > As > Zn > Cd, which are mainly associated with fresh, amorphous Fe oxyhydroxides. The chemical barriers can be instable and reversible. Therefore, water management decisions are discussed which stabilize the barriers by controlling aquifer-channel exchange rates, channel oxygen content and surface water levels.     

A Practical Measurement Strategy to Estimate Nonlinear Chlorinated Solvent Sorption in Low foc Sediments

In this study, we tested a practical strategy useful for accurate chlorinated volatile organic compound (cVOC) sorption prediction. Corresponding to the feature of the superposition of adsorption due to thermally altered carbonaceous matter (TACM) with organic carbon‐water partitioning, a nonlinear Freundlich sorption isotherm covering a wide range of aqueous concentrations was defined by equilibrium sorption measurement at one or a few low concentration points with extrapolation to the empirical organic carbon‐water partition coefficient (K_oc,e) near compound solubility. We applied this approach to obtain perchloroethene equilibrium sorption isotherm parameters for TACM‐containing glacial sand and gravel subsoil samples from a field site in New York. Sorption and associated K_oc,c applicable to low (5–500 µg/L) and high (>100,000 µg/L) aqueous concentrations were determined in batch experiments. (The K_oc,c is the organic carbon‐normalized sorption partition coefficient corresponding to aqueous concentration C_w.) The K_oc,c measurements at low concentration (~5 µg/L) were 6 to 34 times greater than the K_oc,e. The importance of this type of data is illustrated through presentation of its substantial impact on the site remedy. In so doing, we provide an approach that is broadly applicable to cVOC field sites with similar circumstances (low carbon content glacial sand and gravel with TACM).     

John’s creek valley: a mountainous catchment for long-term interdisciplinary human-environment system research in Upper Styria (Austria)

The John’s creek valley (Johnsbachtal) is presented as a long-term, interdisciplinary cooperation platform in upper Styria (Austrian Alps) that brings together the interests and knowledge of persons with different backgrounds (scientists, teachers, students, as well as local actors and the population) with the central aim to generate mutual benefit for all involved parties. It covers an area of around 65 km² with elevations between 600 and 700 m in the valley to over 2,300 m in the summit regions. Annual mean temperature ranges from approximately 8 °C in the lower elevations of the valley to below 0 °C in the summit regions. Annual precipitation mounts to values of 1,500 mm and more than 1,800 mm in the lower elevations and summit regions, respectively. To allow for a long-term monitoring of the complex meteorological and hydrological conditions in the area, a hydroclimatological monitoring network has been installed that is described in detail in this paper. A special characteristic of the installed meteorological stations is that they cover a large range of altitudes and, therefore, allow to capture the gradients in meteorological variables induced by the complex Alpine topography. Furthermore, the hydroclimatological monitoring network in John’s creek valley is largely independent of regular third-party project funding, and therefore, not temporarily limited in its existence. A number of catchment research activities that cover a variety of disciplines (e.g., climatology, hydrology, (hydro)geology, geomorphology) and that largely benefit from the hydroclimatological data recorded in John’s creek valley are presented together with preliminary results. The latter include spatial distributions of meteorological and hydrological variables (e.g., precipitation, evapotranspiration and snowmelt) calculated for the test site using the hydrometeorological model AMUNDSEN. Furthermore, the results of hydrogeological investigations that have been carried out at the Etzbach spring are presented and discussed.     

Tectono-sedimentary evolution of the Upper Prealpine nappe (Switzerland and France): nappe formation by Late Cretaceous-Paleogene accretion

Abstract

The Upper Prealpine nappe of the Swiss and French Prealps consists of a composite stack of various tectonic slivers (Gets, Simme, Dranse and Sarine sub-nappes, from top to bottom). The structural superposition and stratigraphic content of the individual sub-nappes suggests a successive stacking at the South Penninic/Adriatic transition zone during the Late Cretaceous and Early Paleogene. The present paper deals with two aspects. (1) new data obtained from the Complexe de base Series of the Dranse sub-nappe which underlies the Helminthoid Sandstone Formation, and (2) the development of a geodynamic accretionary model for the Upper Prealpine nappe stacking.

The Complexe de base Series reveals a succession of black shales at the base, grading upward into variegated red/green and red shales which were deposited in an abyssal plain environment starved of clastic input. It is overlain by the Helminthoid Sandstone Formation. The combined analysis of planktic and agglutinated benthic foraminifera and comparisons with other Tethyan series suggest an Albian to Campanian age of the Complexe de base succession. Tectonic transport of the abyssal plain segment into a trench environment allowed for the stratigraphic superposition by the Helminthoid sandstone sequence. The present findings combine well with the general scheme of the Upper Prealpine nappe stack and several single results on parts of the nappe stack. We take that opportunity to present a comprehensive model for the tectono-sedimentary evolution of the Upper Prealpine nappe.

We suggest that Late Jurassic-Early Cretaceous asymmetric (?) extension at the South Penninic-Adriatic margin created an extensional alloehthon. Later during the mid-Cretaceous, the start of convergence drove the obduction of oceanic crust on the northern margin of the extensional allochthon. The resulting ophiolitic/continental source supplied clasts to the trench basin in front (Manche turbidite series), and the backarc basin (Mocausa Formation) and abyssal plain (Perrières turbidite series) to the South. During Middle to Late Coniacian the main Adriatic margin was thrusted over the obductionrelated mixed belt and established an incipient accretionary prism containing the former trench, backarc and abyssal plain basin fill series. During this stage the Gueyraz (melange) Complex formed, which separates the trench series from the retroarc and abyssal plain formations. On top of the incipient accretionary prism a forearc basin developed hosting the Hundsrück Formation. The frontal abyssal plain formation (Complexe de base) still received few turbiditic intercalations. From Campanian time on, the forearc basin was bypassed and deposition of the Helminthoid Sandstone Formation occurred on the Complexe de base succession. During the Maastrichtian the abyssal plain and trench fill succession (Dranse nappe) was accreted to the incipient wedge, and in front of a newly active buttress, the Gurnigel trench basin was established. Another accretionary event during latest Paleocene/earliest Eocene added parts of that trench series to the base of the wedge (Sarine nappe). During the Late Eocene the accretionary wedge and remaining trench fill series (Gurnigel nappe) were thrusted en-bloc over the Middle Penninic limestone nappes and partly overtook the latter. Continued shortening of the resulting nappe pile and out-of-sequence thrusting accomplished the overriding of the Middle Penninic units over the former South Penninic Gurnigel trench series (inversion of palaeogeographic domains).