Some applications of paleoecology to the management of tidal marshes

The shallow-water habitat is under increasing environmental pressures from accelerated sea-level rise and continual urban sprawl and will require well-informed management decisions to maintain its health into the future. One of the keys to the effective management of the shallow-water habitat is understanding the processes responsible for its development. Paleoecology has the potential to provide much insight into the development of the system, particularly when the impacts of accelerated sea-level rise on vegetation and sedimentation dynamics in tidal marshes is being considered. For example, a paleoecological comparison of tidal salt marshes to tidal freshwater marshes shows that rates of development will dictate the system's response to accelerated sea-level rise, with tidal freshwater marshes capable of transgressing landward more rapidly than their saline counterparts. Such information implies that management of the adjacent uplands is as important to the future of the system as management of the marsh itself. Therefore, it is important to consult paleoecological research when management strategies are being considered. *** DIRECT SUPPORT *** A01BY074 00010     

On the breakdown of zircon upon “dry” thermal annealing

Zircon samples without and with secondary chemical alteration from diverse sources were subjected to heat treatment at 1400 °C for 96 h. Resulting new phases and textures suggest that decomposition of zircon into component oxides occurred in all experiments to various degrees. The crucible material was found to have a strong influence on the extent of breakdown, especially in the case of altered starting materials. In this study the progressive stages of the breakdown of zircon grains are described. The factors that may govern the decomposition are discussed, including radiation damage, secondary alteration and external reaction conditions (sample container, atmosphere). Alumina crucibles should generally be avoided in dry annealing of zircon, to minimise uncontrolled breakdown into oxides.     

A chemical and thermodynamic model of oil generation in hydrocarbon source rocks

Thermodynamic calculations and Gibbs free energy minimization computer experiments strongly support the hypothesis that kerogen maturation and oil generation are inevitable consequences of oxidation/reduction disproportionation reactions caused by prograde metamorphism of hydrocarbon source rocks with increasing depth of burial.These experiments indicate that oxygen and hydrogen are conserved in the process.Accordingly, if water is stable and present in the source rock at temperatures ?25 but ?100 °C along a typical US Gulf Coast geotherm, immature (reduced) kerogen with a given atomic hydrogen to carbon ratio (H/C) melts incongruently with increasing temperature and depth of burial to produce a metastable equilibrium phase assemblage consisting of naphthenic/biomarker-rich crude oil, a type-II/III kerogen with an atomic hydrogen/carbon ratio (H/C) of ∼1, and water. Hence, this incongruent melting process promotes diagenetic reaction of detritus in the source rock to form authigenic mineral assemblages.However, in the water-absent region of the system CHO (which is extensive), any water initially present or subsequently entering the source rock is consumed by reaction with the most mature kerogen with the lowest H/C it encounters to form CO₂ gas and a new kerogen with higher H/C and O/C, both of which are in metastable equilibrium with one another.This hydrolytic disproportionation process progressively increases both the concentration of the solute in the aqueous phase, and the oil generation potential of the source rock; i.e., the new kerogen can then produce more crude oil.Petroleum is generated with increasing temperature and depth of burial of hydrocarbon source rocks in which water is not stable in the system CHO by a series of irreversible disproportionation reactions in which kerogens with higher (H/C)s melt incongruently to produce metastable equilibrium assemblages consisting of crude oil, CO₂ gas, and a more mature (oxidized) kerogen with a lower H/C which in turn melts incongruently with further burial to produce more crude oil, CO₂ gas, and a kerogen with a lower H/C and so forth.The petroleum generated in the process progresses from heavy naphthenic crude oils at low temperatures to mature petroleum at ∼150 °C. For example, the results of Computer Experiment 27 (see below) indicate that the overall incongruent melting reaction in the water-absent region of the system C-H-O at 150 °C and a depth of ∼4.3 km of an immature type-II/III kerogen with a bulk composition represented by C₂₉₂H₂₈₈O_12(c) to produce a mature (oxidized) kerogen represented by C₁₂₈H₆₈O_7(c), together with a typical crude oil with an average metastable equilibrium composition corresponding to C_8.8H_16.9 (C_8.8H_16.9(l)) and CO₂ gas (CO_2(g)) can be described by writing

(A)     

ISIS IR: The first infrared fibre-fed spectrograph

ISIS IR is the first attempt to use fibre optics for near infrared spectroscopy (1.8m). It is a field spectrograph (2D spectroscopy), and can work at various resolving powers (up to 25000). It can be transported anywhere, and soon it will be used at CFHT with one NICMOS 3-based camera.Département d'Astrophysique Extragalactique et de Cosmologie     

Anatomy of individual agglutinates from a lunar highland soil

Abstract— We report results of our investigation of the relationship between values of I_s/FeO (relative concentration of nanophase Fe⁰ divided by total FeO content), glass abundance, total Fe content, and degree of digestion of <20 μm clasts for 22 individual agglutinates (250–1000 μm) from the mature Apollo 16 soil 61181 (I_s/FeO = 82 units in the <250 μm fraction). Agglutinates are important products of space weathering on the Moon, and they influence spectral observations at visible and near-IR wavelengths. Values of I_s/FeO for individual agglutinates (250–1000 μm) within this single soil span a range from 3 to 262 units which is larger than the range observed for all Apollo 16 bulk soils (～0 to 110 units). No correlation was observed between I_s/FeO and glass abundance and FeO concentrations for either agglutinitic glass or whole agglutinate particles under investigation. Our results suggest that the variation in I_s/FeO for agglutinates from a single soil may be in part a consequence of natural mixing processes on the Moon that produce highly-variable environments (with respect to surface exposure) for agglutinate formation and in part to variable kinetics of reactions in an agglutinate melt, which are influenced by a variety of factors including melt composition, temperature, impactor velocity, and quench rate. We cannot exclude but do not see evidence for other processes including addition of exotic agglutinates, micrometeoritic bombardment into compositionally-diverse microtargets, recycling of agglutinates, preferential melting of very fine soil particles, and production of nanophase Fe⁰ in amorphous rims of very fine irradiated lunar grains contributing to the observed variation of I_s/FeO.     

The Depiction of Coronal Structure in White-Light Images

The very steep decrease in density with heliocentric distance makes imaging of coronal density structures out to a few solar radii challenging. The radial gradient in brightness can be reduced using numerous image processing techniques, thus quantitative data are manipulated to provide qualitative images. We introduce a new normalizing-radial-graded filter (NRGF): a simple filter for removing the radial gradient to reveal coronal structure. Applied to polarized brightness observations of the corona, the NRGF produces images which are striking in their detail. Total-brightness, white-light images include contributions from the F corona, stray light, and other instrumental contributions which need to be removed as effectively as possible to properly reveal the electron corona structure. A new procedure for subtracting this background from LASCO C2 white-light, total-brightness images is introduced. The background is created from the unpolarized component of total-brightness images and is found to be remarkably time-invariant, remaining virtually unchanged over the solar cycle. By direct comparison with polarized-brightness data, we show that the new background-subtracting procedure is superior in depicting coronal structure accurately, particularly when used in conjunction with the NRGF. The effectiveness of the procedures is demonstrated on a series of LASCO C2 observations of a coronal mass ejection (CME).     

Solar total irradiance observations by Active Cavity Radiometers

Pyrheliometry, definition of the radiation scale in the International System of Units and monitoring the variability of solar total irradiance have been a focus of research at the Jet Propulsion Laboratory since the mid 1960's. A series of automated, electrically self-calibrating, cavity pyrheliometers known as Active Cavity Radiometers (ACR's) was developed as part of this program. A series of ground based experiments in 1968–69 led to the discovery of a systematic error in the International Pyrheliometric Scale. ACR's were among the instruments used to define the World Radiometric Reference in 1975.ACR flight experiments have been conducted to determine the 1 AU total solar irradiance and monitor its variability in time. A 1969 balloon experiment yielded a 1366 W m^-2 result. The value from a 1976 sounding rocket experiment was 1368.1 W m^-2. The results for two additional rocket experiments in 1978 and 80, revised in accordance with recent calibrations of ACR response to elevated pressures during these flights are: 1367.6 and 1367.8 W m^-2, respectively. An ACR experiment (ACRIM) on the Solar Maximum Mission satellite has shown continuous variability of the total solar flux below the ±0.05% level and two large, temporary decreases of 0.1–0.2% lasting more than a week. The mean 1 AU total flux for ACRIM's first five months' observations was 1367.7 W m^-2. Inflight comparison of ACR rocket and satellite measurements in May, 1980 demonstrated agreement to within ±0.05%. The 1 AU total solar irradiance results from ACR rocket and satellite experiments between 1976 and 1980 differ from their mean of 1367.8 W m^-2 by no more than ±0.02%. The less precise 1969 balloon result is 0.1% lower. Although no observations were made from 1970–75, if solar behaviour in those five years was similar to that observed since 1976 then the upper limits of long term solar total irradiance variability are ±0.2% for the 1969–1980 period and ±0.1% between 1976 and 1980, based on the set of ACR observations.Proceedings of the 14th ESLAB Symposium on Physics of Solar Variations, 16–19 September 1980, Scheveningen, The Netherlands.