1H NMR spectra of humic and fulvic acids and their peracetic oxidation products

¹H NMR spectra of humic (HA) and fulvic (FA) acids and their oxidative degradation products are reported. The HA shows the presence of -(CH₂)_n - CH₃ (n > 6) chemical fragments belonging to n-alkanes and/or n-fatty acids physically adsorbed onto the macromolecule structure. These fragments are absent in the FA fraction. Both humic fractions reveal the presence of similar amounts of aromatic protons which partly undergo exchange phenomena. The importance of this experimental observation is discussed. Oxidative degradation seems to cause partial cleavage of aromatic rings, more pronounced in the FA than in the HA. The degraded FA shows a higher total acidity and a higher phenolic OH content than the degraded HA. Both degraded fractions display some sharp singlet signals at 1.9 and 3.9 ppm arising from protons belonging to repetitive chemical fragments probably formed during the oxidation reaction. Tentative assignments of these signals are given. A general analysis of the HA and FA degraded spectra seems to indicate that the chemical fragments which undergo peracetic oxidation are substantially similar. The extent of oxidation of the two humic fractions is different. The HA degradation products reveal the presence of oligomeric structures, whereas the degraded FA appears less resistant to the oxidizing agent.     

Analyses of the warm season rainfall climatology of the northeastern US using regional climate model simulations and radar rainfall fields

We examine the warm season (April-September) rainfall climatology of the northeastern US through analyses of high-resolution radar rainfall fields from the Hydro-NEXRAD system and regional climate model simulations using the weather research and forecasting (WRF) model. Analyses center on the 5-year period from 2003 to 2007 and the study area includes the New York-New Jersey metropolitan region covered by radar rainfall fields from the Fort Dix, NJ WSR-88D. The objective of this study is to develop and test tools for examining rainfall climatology, with a special focus on heavy rainfall. An additional emphasis is on rainfall climatology in regions of complex terrain, like the northeastern US, which is characterized by land-water boundaries, large heterogeneity in land use and cover, and mountainous terrain in the western portion of the region. We develop a 5-year record of warm season radar rainfall fields for the study region using the Hydro-NEXRAD system. We perform regional downscaling simulations for the 5-year study period using the WRF model. Radar rainfall fields are used to characterize the interannual, seasonal and diurnal variation of rainfall over the study region and to examine spatial heterogeneity of rainfall. Regional climate model simulations are characterized by a wet bias in the rainfall fields, with the largest bias in the high-elevation regions of the model domain. We show that model simulations capture broad features of the interannual, seasonal, and diurnal variation of rainfall. Model simulations do not capture spatial gradients in radar rainfall fields around the New York metropolitan region and land-water boundaries to the east. The model climatology of convective available potential energy (CAPE) is used to interpret the regional distribution of warm season rainfall and the seasonal and diurnal variability of rainfall. We use hydrologic and meteorological observations from July 2007 to examine the interactions of land surface processes and rainfall from a regional perspective.     

Organohalogen contaminants and trace metals in North-East Atlantic porbeagle shark (Lamna nasus)

The North-East Atlantic porbeagle (Lamna nasus) population has declined dramatically over the last few decades and is currently classified as ‘Critically Endangered’. As long-lived, apex predators, they may be vulnerable to bioaccumulation of contaminants. In this study organohalogen compounds and trace elements were analysed in 12 specimens caught as incidental bycatch in commercial gillnet fisheries in the Celtic Sea in 2011. Levels of organohalogen contaminants were low or undetectable (summed CB and BDE concentrations 0.04–0.85 mg kg⁻¹ wet weight). A notably high Cd concentration (7.2 mg kg⁻¹ wet weight) was observed in one mature male, whereas the range observed in the other samples was much lower (0.04–0.26 mg kg⁻¹ wet weight). Hg and Pb concentrations were detected only in single animals, at 0.34 and 0.08 mg kg⁻¹ wet weight, respectively. These contaminant levels were low in comparison to other published studies for shark species.     

Least squares best-fit circles (with applications to Mohr''s diagram)

Procedures are outlined for the selection of a least squares best-fit circle to data points defined by rectangular Cartesian coordinates. Equations are derived to allow fitting of circles centered on the x-axis as well as off-axis Mohr circles. These procedures are applicable to the estimation of second-order tensors such as stress and strain by means of Mohr's diagram.     

Change in the magnetic properties of bituminous coal intruded by an igneous dike, Dutch Creek Mine, Pitkin County, Colorado

Magnetization measurements have been made on natural coke–coal samples collected at various distances from a felsic porphyry dike in a coal seam in Dutch Creek Mine, Colorado to help characterize the nature and distribution of the iron-bearing phases. The magnetization passes through a maximum at the coke-to-coal transition about 31 cm from the dike contact. The magnetic measurements support the geochemical data indicating that magmatic fluids along with a high-temperature gas pulse moved into the coal bed. Interaction of the magmatic fluids with the coal diminished the reducing power of the thermal gas pulse from the dike to a point about 24 cm into the coal. The hot reducing gas penetrated further and produced a high temperature (400–525°C) zone (at about 31 cm) just ahead of the magmatic fluids. Metallic iron found in this zone is the principal cause of the observed high magnetization. Beyond this zone, the temperature was too low to alter the coal significantly.     

Uplift rates of the Loyalty Islands as determined by 230Th234U dating of raised coral terraces

Uplift rates of the Loyalty Islands (S.W. Pacific) have been determined from ${}^{230}\text{Th}{}^{234}\text{U}$ dating of raised coral terraces standing 2 to 7.5 m above sea level. The ages of the terraces on Ouvéa and Lifou correspond closely to previously documented periods of high sea levels at 120,000 and 180,000 yr BP. A +2-m terrace on Beautemps-Beaupré is considered to be beyond the range of the dating technique. The uplift rates of the various islands show a decrease toward the west. This lends support to the hypothesis of a lithospheric bulge of the leading edge of the Australian plate prior to its subduction at the level of the New Hebrides trench.     

A disturbed molecular disc in the Circinus galaxy

We have used the Swedish ESO Submillimeter Telescope to observe the molecular gas in the Circinus galaxy using the CO(1 → 0) transition as a tracer. The central region and major axis have been mapped and several other points were also observed. The gas in the galaxy is concentrated towards the nucleus, the peak being coincident with the radio/optical core. The inclination of the molecular galactic disc is more comparable to that of the radio continuum than to that of the large-scale H  i emission. Evidence for an anomalous spur structure pointing radially away from the galactic centre is presented, and may indicate a causal link between it and similar features seen in optical lines and radio continuum. Our data suggest the presence of a central molecular ring or disc with radius 300 ± 50 pc and a rotation velocity of about 200 km s⁻¹ (assuming i  = 73°). The dynamical mass of the nucleus is estimated to be no greater than 3.9 × 10⁹ M_⊙. Assuming that the distribution of gas varies smoothly in the outer regions, we calculate the mass of molecular gas in the galaxy to be at least M _mol = 1.1 × 10⁹ M_⊙, and the star-forming efficiency to be 11 ± 2 L_⊙ M_⊙⁻¹. These results imply that Circinus is undergoing a massive central starburst which may be, at least partially, responsible for its extended minor axis emission seen in several wavebands.     

Kema terrane: A fragment of a back-arc basin of the early Cretaceous Moneron–Samarga island-arc system, East Sikhote–Alin range, Russian Far East

Abstract The Kema terrane is a suite of Barremian(?)–Aptian to Albian volcano-sedimentary rocks of Sikhote–Alin that are interpreted as deposits of the back-arc basin of the Moneron–Samarga island-arc system. Compositional features of the different-type deposits indicate a near-slope depositional environment influenced by volcanic processes. Studies of slump fold orientation testify to the accumulation of material from southeast to northwest by gravitational sliding. Compositional characteristics of terrigenous rocks suggest the major provenance for detrital material was an ensialic volcanic island arc. Petrochemical characteristics of basaltic rocks indicate that the formations studied were confined to the back part of the arc.