The nature of crystalline silica from the TAG submarine hydrothermal mound, 26°N Mid Atlantic Ridge

Silica occurs in abundance in a variety of hydrothermal samples from the Trans-Atlantic Geotraverse (TAG) hydrothermal mound, 26°N Mid-Atlantic Ridge. The water content, trace element chemistry, and mineralogy of crystalline silica from 15 different samples have been examined by vibrational spectroscopy and probe microanalysis. The samples are from: shallow subsurface ferric iron oxyhydroxide silica deposits (n=4), a fragment of an active white smoker chimney (n=1), anhydrite bearing hydrothermal breccias (n=2), pyrite silica breccias (n=3), and silicified wall rock breccias (n=5). Length-fast chalcedony occurs in association with variable quantities of ferric iron oxyhydroxides in hydrothermal breccias from the mound flanks, within shallower subsurface chert samples, and within white smoker chimney walls. Samples from the anhydrite zone contain textures which are suggestive of an origin involving replacement of anhydrite. Samples taken from TAG 1 and 5 from below the anhydrite zone contain no chalcedony. Instead they contain subhedral quartz crystals which show oscillatory zoning in aluminium. Two types of crystalline silica namely, type A and type B quartz, are defined on the basis of the infrared spectra in the OH region from 3200 cm⁻¹ to 3600 cm⁻¹. The type A quartz occurs beneath the anhydrite zone at TAG 1 and 5. We propose a model that relates specific varieties of crystalline silica to different thermal and chemical environments within the mound interior. Length-fast chalcedony occurs in an outer low temperature envelope across the top and sides of the mound. The common association between length-fast chalcedony and ferric iron oxyhydroxides suggests that chalcedony crystallization is favoured where catalysis by ferric iron can occur. The apparent suppression of fibrous silica at the expense of single quartz crystals with increasing depth is attributed to differing growth rates and degrees of supersaturation of silica-bearing solutions with increasing temperature within the mound. The transition from type A to type B single crystal growth is interpreted to occur at temperatures approaching ˜360 °C due to decreasing solubility of aluminium in quartz, so that aluminium is rendered unavailable for type A valence compensation. Received: 10 September 1998 / Accepted: 6 July 1999     

SHORELINE CHANGE AT THOMPSON ISLAND,BOSTON HARBOR,MASSACHUSETTS, 1938-1977

A photogrammetric and sediment analysis is presented to illustrate the relationship between beach erosion and seacliff recession on Thompson Island, Boston Harbor, Massachusetts. Aerial photographs taken in 1938, 1952, 1963, and 1977 were measured to determine rates of shoreline change around the island. The 39-year average rate of beach erosion is 0.3 m/yr ± 2% with an average rate of cliff recession at 0.2 m/yr ± 2%. Rates of beach erosion between six orientations that reflect principal wave approach to the island were not found to be significantly different (0.05) for the 39-year period. The rank order correlation between beach erosion and cliff recession for these six orientations was moderately well correlated (0.63). To determine possible controls of cliff erosion, 58 sediment samples were collected from glacial cliffs along the shoreline. The textural composition was determined, and then tested with discriminant function analysis. Partial correlation analysis between beach erosion and cliff recession holding a surrogate for sediment size constant improved the rank order from 0.63 to 0.84. The results indicate that coarser-grained cliffs recede at faster rates, but with less erosion occurring on adjacent beaches. Alternatively, finer-grained cliffs recede at slower rates, but with greater erosion occurring on adjacent beaches.     

A photoelectric lightcurve survey of small main belt asteroids

A survey to obtain photoelectric lightcurves of small main-belt asteroids was conducted from November 1981 to April 1982 using the 0.91- and 2.1-m telescopes at the University of Texas McDonald Observatory. A total of 18 main-belt asteroids having estimated diameters under 30 km were observed with over half of these being smaller than 15 km. Rotational periods were determined or estimated from multiple nights of observation for nearly all of these yielding a sample of 17 small main-belt asteroids which is believed to be free of observational selection effects. All but two of these objects were investigated for very short periods in the range of 1 min to 2 hr using power spectrum analysis of a continuous set of integrations. No evidence for such short periods was seen in this sample. Rotationally averaged B(1,0) magnitudes were determined for most of the surveyed asteroids, allowing diameter estimates to be made. Imposing the suspected selection effects of photographic photometry on the results of this survey gives excellent agreement with the results from that technique. This shows that the inability of photographic photometry to obtain results for many asteroids is indeed due to the rotational parameters of those asteroids.     

DDT,PCB and benzo(a)pyrene levels in white croaker (Genyonemus lineatus) from southern California

In 1978 the California Department of Fish and Game carried out a major, independent sportfishing survey in southern California. The results of that survey indicated that approximately one million angler-trip hours per year were spent fishing and that one in three fish caught was a white croaker (Genyonemus lineatus). There was no attempt by the Department of Fish and Game to determine the disposition of caught fish. We conducted a subsequent survey in 1980 which included 12 popular sportfishing sites in the Los Angeles area. Our results also indicated that one in three fish caught was a white croaker. In addition our survey showed that 82% of the sportfishermen ate the white croaker they caught and the median consumption was 14.8 g day^?1 person^?1. White croaker were then sampled by hook-and-line from 11 of the 12 survey sites plus two control sites and analysed for PCB, DDT and BaP. Median PCB levels ranged from 0.014 to 0.41 mg wet kg^?1; median DDT from 0.059 to 7.5 mg wet kg^?1 and BaP was below detectable limits of 1 ng for all sites.     

Physical parameters of near-Earth asteroid 1982 DV

Visual and infrared observations were made of Amor asteroid 1982 DV during its discovery apparition. Broadband visual and near-infrared photometry shows that it is an S-class asteroid. Narrowband spectrophotometry shows an absorption feature due to olivine or pyroxene or both centered at 0.93 μm. Applying a nonrotating thermal model to 10-μm photometry, the geometric albedo is calculated to be approximately 0.27. The geometric albedo for a slowly rotating, rocky surface was calculated for 1 night to be 0.15, consistent with S-class asteroid albedos. Thus, 1982 DV is either one of the most reflective S-class asteroids known, or a significant amount of bare rock is exposed on the asteroid's surface. For the nonrotating model, ellipsoidal dimensions for 1982 DV are 3.5 × 1.4 × 1.4 km.     

The sea-surface microlayer of puget sound: Part I. Toxic effects on fish eggs and larvae

The sea surface is an important habitat for the developmental stages (eggs and larvae) of many fish and invertebrates; it is also a concentration point for anthropogenic contaminants entering the sea. Studies were conducted to determine the extent to which the sea surface of Puget Sound was toxic to the early life history stages of fish. Three urban bays with suspected contamination, a rural reference bay, and a Central Sound site were compared. Surface-dwelling eggs and organisms (zooneuston) were collected with a surface-skimming neuston net and their densities enumerated. Sand sole (Psettichthys melanostictus) embryos were exposed in the field and laboratory to the sea-surface microlayer. To develop a useful year-round approach to monitoring sea-surface toxicity, larval development of anchovies, kelp bass, and sea urchins was also evaluated as an indication of sea-surface microlayer toxicity.During the spawning season (February and March), urban boys in Puget Sound had lower concentrations of sand sole eggs and neustonic organisms on the sea surface than did the rural bayor Central Sound reference sites. Compared to the reference sites, laboratory exposure to surface microlayer samples collected from urban bay sites generally resulted in more chromsomal aberrations in developing sole embryos, reduced hatching success of sole larvae, and reduced growth in trout cell cultures. In situ hatching success of sole eggs was reduced by half or more in urban bays compared to reference sites.Toxicity was associated with visible surface slicks and, in urban bays, increased with increasing surface pressure (dynes cm⁻¹). Results to be reported separately (Part II) indicate that toxicity is strongly correlated with the presence of high concentrations of polycyclic aromatic hydrocarbons and metals in the sea-surface microlayer. The toxicity of SMIC samples was similar when evaluated by sole, anchovy, kelp bass, or sea urchin tests. A sea-surface monitoring program could use sea urchin embryos to evaluate site-specific sea-surface toxicity throughout the year.     

COMPARING TRADITIONAL METHODS FOR SELECTING CLASS INTERVALS ON CHOROPLETH MAPS*

The most common goal when classing data for choropleth maps is to create homogeneous classes which contain similar data values. None of the four traditional data classing methods examined here (quartile, equal interval, standard deviation, and natural breaks) consistently generalized the experimental data sets into homogeneous classes. These methods were most accurate for data sets with specific distributional characteristics, but none classed all of any type of distribution accurately. Only the optimization method produced reliable and accurate results for all of the experimental data.     

Hydraulic redistribution and hydrological controls on aspen transpiration and establishment in peatlands following wildfire

In the sub‐humid Western Boreal Plains of Alberta, where evapotranspiration often exceeds precipitation, trembling aspen (Populus tremuloides Michx.) uplands often depend on adjacent peatlands for water supply through hydraulic redistribution. Wildfire is common in the Boreal Plains, so the resilience of the transfer of water from peatlands to uplands through roots immediately following wildfire may have implications for aspen succession. The objective of this research was to characterize post‐fire peatland‐upland hydraulic connectivity and assess controls on aspen transpiration (as a measure of stress and productivity) among landscape topographic positions. In May 2011, a wildfire affected 90,000 ha of north central Alberta, including the Utikuma Region Study Area (URSA). Portions of an URSA glacio‐fluval outwash lake catchment were burned, which included forests and a small peatland. Within 1 year after the fire, aspen were found to be growing in both the interior and margins of this peatland. Across recovering land units, transpiration varied along a topographic gradient of upland midslope (0.42 mm hr^?1) > upland hilltop (0.29 mm hr^?1) > margin (0.23 mm hr^?1) > peatland (0.10 mm hr^?1); similar trends were observed with leaf area and stem heights. Although volumetric water content was below field capacity, P. tremuloides were sustained through roots present, likely before fire, in peatland margins through hydraulic redistribution. Evidence for this was observed through the analysis of oxygen (δ¹⁸O) and hydrogen (δ²H) isotopes where upland xylem and peat core signatures were ?10.0‰ and ?117.8‰ and ?9.2‰ and ?114.0‰, respectively. This research highlights the potential importance of hydraulic redistribution to forest sustainability and recovery, in which the continued delivery of water may result in the encroachment of aspen into peatlands. As such, we suggest that through altering ecosystem services, peatland margins following fire may be at risk to aspen colonization during succession.     

Applications of particle-tracking techniques to bank infiltration: a case study from El Paso,Texas, USA

This paper presents results of a small scale study that utilized particle-tracking techniques to evaluate transport of river water through an alluvial aquifer in a bank infiltration testing site in El Paso, Texas, USA. The particle-tracking survey was used to better define filtration parameters. Several simulations were generated to allow visualization of the effects of well placement and pumping rate on flow paths, travel time, the size of the pumping influence zone, and proportion of river-derived water and groundwater mixing in the pumping well. Simulations indicate that migration of river water into the aquifer is generally slow. Most water does not arrive at the well by the end of an 18-day pumping period at 0.54 m³/min pumping rate for a well located 18 m from the river. Forty-four percent of the water pumped from the well was river water. The models provided important information needed to design appropriate sampling schedules for bank filtration practices and ensured meeting adequate soil-retention times. The pumping rate has more effect on river water travel time than the location of the pumping well from the river. The examples presented in this paper indicate that operating the pumping well at a doubled distance from the river increased the time required for the water to travel to the well, but did not greatly change the capture zone.     

Iron(III) accumulations in inland saline waterways,Hunter Valley,Australia: Mineralogy,micromorphology and pore-water geochemistry

Discharge of Fe(II)-rich groundwaters into surface-waters results in the accumulation of Fe(III)-minerals in salinized sand-bed waterways of the Hunter Valley, Australia. The objective of this study was to characterise the mineralogy, micromorphology and pore-water geochemistry of these Fe(III) accumulations. Pore-waters had a circumneutral pH (6.2–7.2), were sub-oxic to oxic (Eh 59–453 mV), and had dissolved Fe(II) concentrations up to 81.6 mg L⁻¹. X-ray diffraction (XRD) on natural and acid-ammonium-oxalate (AAO) extracted samples indicated a dominance of 2-line ferrihydrite in most samples, with lesser amounts of goethite, lepidocrocite, quartz, and alumino-silicate clays. The majority of Fe in the samples was bound in the AAO extractable fraction (Fe^Ox) relative to the Na-dithionite extractable fraction (Fe^Di), with generally high Fe^Ox:Fe^Di ratios (0.52–0.92). The presence of nano-crystalline 2-line ferrihydrite (Fe₅HO₃·4H₂O) with lesser amounts of goethite (α-FeOOH) was confirmed by scanning electron microscopy (SEM) coupled with energy dispersive X-ray analysis (EDX), and transmission electron microscopy (TEM) coupled with selected area electron diffraction (SAED). In addition, it was found that lepidocrocite (γ-FeOOH), which occurred as nanoparticles as little as ∼5 lattice spacings thick perpendicular to the (0 2 0) lattice plane, was also present in the studied Fe(III) deposits. Overall, the results highlight the complex variability in the crystallinity and particle-size of Fe(III)-minerals which form via oxidation of Fe(II)-rich groundwaters in sand-bed streams. This variability may be attributed to: (1) divergent precipitation conditions influencing the Fe(II) oxidation rate and the associated supply and hydrolysis of the Fe(III) ion, (2) the effect of interfering compounds, and (3) the influence of bacteria, especially Leptothrix ochracea.