Integrated Deep Soil N and Groundwater Isotope Investigation of N Sources Captured by Municipal Wells

Identification of major nitrate sources that adversely impact groundwater quality in municipal well capture zones in areas of emerging nitrate contamination is essential to minimize leaching and prevent exceedance of the nitrate drinking water standard. Vertical profiles of nitrate leachate in deep soils provide an estimate of the amount of nitrate in transit beneath irrigated, row-cropped fields; depths of peak leachate; and the approximate rate of downward movement. Profiles of pore-water soil-nitrate concentrations in thick 60-feet (~18 m), fine-textured soils near Hastings, Nebraska clearly indicate that considerably more nitrate leached beneath furrow-irrigated than center-pivot irrigated fields. Peak leaching appeared to correlate with recorded periods of poor weather conditions during some growing seasons and may best be controlled by “spoon feeding” fertilizer to the crop through the sprinkler irrigation system at times of nutrient need. The presence of trace levels of atrazine and deethylatrazine to 60 feet (18 m) in core samples indicates that larger, more complex anthropogenic molecules also leach through the fine-textured soils. The light δ¹⁵N_NO3 values in the surficial groundwater beneath fertilized and irrigated cropland indicate that ammonium fertilizer is a major N source and suggest that the natural soil-N contribution is negligible. δ¹⁵N_NO3 values were most enriched in irrigation wells located within municipal well capture zones downgradient of a large feedlot. Dual isotope method (DIM) δ¹⁵N_NO3 and δ¹⁸O_NO3 values suggest that the Hastings’ municipal wells farther downgradient are contaminated with a mixture of nitrate from manure and commercial ammonium-based fertilizer. DIM values indicate an absence of denitrification, which has implications for long-term management of the water resources.     

The Japanese medaka (Oryzias latipes) model: applicability for investigating the immunosuppressive effects of the aquatic pollutant benzo[a]pyrene (BaP)

Despite the fact that BaP is a carcinogen, mammalian immunosuppressant, and ubiquitous aquatic pollutant, knowledge regarding the effects of BaP on the immune system of fish is still lacking. To begin to fill this gap, studies were conducted in medaka to examine the effects and mechanisms by which BaP exposure might alter host immunocompetence. Fish, exposed by IP injection of BaP (2-600 microg/g BW), were examined after 48 h for effects upon immune function and CYP1A expression/activity. Benzo[a]pyrene, at a concentration below that which increased levels of CYPIA expression/activity (2 microg BaP/g BW) suppressed lymphocyte proliferation. Concentrations of BaP at 20 and 200 microg/g BW. suppressed antibody-forming cell (AFC) numbers, superoxide production, and host resistance against bacteria. In contrast, exposure to the low affinity aryl hydrocarbon receptor (AhR) agonist, benzo[e]pyrene (BeP), neither induced CYP1A expression nor altered immune function. Given the lack of immunosuppressive effects produced by BeP, and the fact that exposure to the AhR antagonist (and CYP1A inhibitor) alpha-naphthoflavone (ANF) ameliorated the suppressive effects of BaP upon AFC numbers, the AhR pathway (including CYP1A-mediated production of reactive BaP metabolites) appears important in mediating BaP-induced immunotoxicity in fish, as in mammals. In the past, the medaka has proven a successful model for assessing carcinogenic agents. These studies have demonstrated its utility for also determining the immunosuppressive effects of an important aquatic contaminant.     

Luminescence from glacimarine sediment-trap samples at the Antarctic Peninsula

Radiocarbon (¹⁴C) dating yields variable and high reservoir and core-top ages for glacimarine sediments around Antarctica. To test the suitability of luminescence as an alternate dating method we investigated the effectiveness of clock zeroing (by daylight) within fine-silt-size siliciclastic sediments from year-long vertical-array sediment traps in Andvord Bay and Brialmont Cove at the Antarctic Peninsula. Both long-bleach and short-bleach multi-aliquot IR-PSL (infrared photon stimulated luminescence) and single-aliquot, post-IR blue-PSL dating tests were conducted. As well, dual-bandwidth-bleaching thermoluminescence (TL) tests were performed on samples from Brialmont Cove. These TL bleaching tests indicate that silt from the middle and bottom traps at this site has had little or no exposure to daylight, but that silt from the top trap has had some exposure. All 24 samples (representing different seasons and different trap depths) exhibit anomalously old apparent ages (12 ka–60 ka) across annual seasons and depths of deposition when either long-bleach multi-aliquot or late-background-subtraction single-aliquot PSL procedures were employed. Thus regional bottom silts would be unsuited for dating by these two luminescence dating approaches. However, a short-bleach multi-aliquot IR-PSL procedure yields the expected zero ages for several samples, a promising result that requires further exploration.     

Oxygen isotopic constraints on the origin and parent bodies of eucrites, diogenites, and howardites

A few eucrites have anomalous oxygen isotopic compositions. To help understand their origin and identify additional samples, we have analyzed the oxygen isotopic compositions of 18 eucrites and four diogenites. Except for five eucrites, these meteorites have Δ¹⁷O values that lie within 2σ of their mean value viz., −0.242 ± 0.016‰, consistent with igneous isotopic homogenization of Vesta. The five exceptional eucrites—NWA 1240, Pasamonte (both clast and matrix samples), PCA 91007, A-881394, and Ibitira—have Δ¹⁷O values that lie, respectively, 4σ, 5σ, 5σ, 15σ, and 21σ away from this mean value. NWA 1240 has a δ¹⁸O value that is 5σ below the mean eucrite value. Four of the five outliers are unbrecciated and unshocked basaltic eucrites, like NWA 011, the first eucrite found to have an anomalous oxygen isotopic composition. The fifth outlier, Pasamonte, is composed almost entirely of unequilibrated basaltic clasts. Published chemical data for the six eucrites with anomalous oxygen isotopic compositions (including NWA 011) exclude contamination by chondritic projectiles as a source of the oxygen anomalies. Only NWA 011 has an anomalous Fe/Mn ratio, but several anomalous eucrites have exceptional Na, Ti, or Cr concentrations. We infer that the six anomalous eucrites are probably derived from five distinct Vesta-like parent bodies (Pasamonte and PCA 91007 could come from one body). These anomalous eucrites, like the isotopically normal, unbrecciated eucrites with 4.48 Gyr Ar-Ar ages, are probably deficient in brecciation and shock effects because they were sequestered in small asteroids (10 km diameter) during the Late Heavy Bombardment following ejection from Vesta-like bodies. The preservation of Vesta’s crust and the lack of deeply buried samples from the hypothesized Vesta-like bodies are consistent with the removal of these bodies from the asteroid belt by gravitational perturbations from planets and protoplanets, rather than by collisional grinding.     

Ore belts of the Greater Altai and their ore resource potential

The results of comprehensive geological and metallogenic studies of the Greater Altai are presented. This project has been carried out since 1997 under the guidance of Academician G.N. Shcherba. The importance of these investigations is determined by the need to enhance and further develop mineral resources of nonferrous, noble, rare, and other metals for operating mining and metallurgical enterprises of Kazakhstan. The great body of information on the geology, geophysics, and metallogeny of the region obtained over many years has been integrated on the basis of new global tectonics. The Greater Altai embraces the Hercynides of the Rudny Altai, Qalba-Narym, West Qalba, Zharma-Saur, and the adjacent territories of Russia and China. The present-day tectonic units are considered to be detached blocks of ancient continental massifs that drifted in the Paleoasian ocean and then amalgamated into the structure of the Greater Altai during the Hercynian collision. The tectonic and metallogenic demarcation of the studied territory made possible the recognition of the Rudny Altai, Qalba-Narym, West Qalba, and Zharma-Saur ore belts, different in geology, geodynamic evolution, and metallogeny. The formation conditions and localization of volcanic-hosted massive sulfide, gold, and rare-metal deposits pertaining to certain ore-bearing geochronological levels were specified, and the potential of the region for various mineral resources was estimated.     

A reported early-man site adjacent to southern Alaska's continental shelf: A geologic solution to an archeologic enigma

An extensive ancient archeologic site containing lithic artifacts and associated with mammoth remains was reported at Chinitna Bay, southern Alaska in 1943. The presence of such a site adjacent to the continental shelf at the base of the rugged Aleutian Range suggested that humans may have inhabited the inner shelf environment during the late Pleistocene at times of lowered sea level. Because of the site's potential significance, an interdisciplinary research team relocated and reinvestigated the area in 1978, but failed to find evidence of prehistoric human habitation. Geologic studies and radiocarbon dating indicate that the strata reported at the site are intertidal in origin, very late Holocene in age, and have undergone significant tectonic movement in the recent past. These observations indicate that the previously published observations of the Chinitna Bay site are probably invalid.     

Tectonic Position of the South Anyui Suture

Geotectonics - The South Anyui Fold System was formed at the end of the Early Cretaceous at the site of a closed oceanic basin as a result of the collision of the Chukotka microcontinent with the...     

Statistics of magnetic fields for OB stars

Based on an analysis of the catalog of magnetic fields, we have investigated the statistical properties of the mean magnetic fields for OB stars. We show that the mean effective magnetic field B of a star can be used as a statistically significant characteristic of its magnetic field. No correlation has been found between the mean magnetic field strength B and projected rotational velocity of OB stars, which is consistent with the hypothesis about a fossil origin of the magnetic field. We have constructed the magnetic field distribution function for B stars, F(B), that has a power-law dependence on B with an exponent of ≈−1.82. We have found a sharp decrease in the function F(B) for B ⩽ 400 G that may be related to rapid dissipation of weak stellar surface magnetic fields.