Reservoirs of atmospheric chlorine: Prospects for HOCl revisted

We have re-examined the prospects of HOCl as an inert reservoir for atmospheric chlorine in the light of new theoretical calculations and available experimental measurements of its photodissociation cross-sections. The theoretical calculations and most recent laboratory studies imply that the broad maxima 3200 Å observed in two other experimental spectra may not belong to HOCl. On the basis of this implication HOCl could have a long lifetime against photodissociation in the stratosphere, and could, thereby, become a reservoir for atmospheric chlorine comparable to ClONO₂ or even HCl. In this capacity HOCl could reduce the predicted ozone destruction due to any given level of total chlorine burden. We have also examined the difficulties in laboratory measurements of the HOCl absorption spectrum with particular emphasis on identifying the impurities which may be present in the experimental system. It appears that specialized new experiments are needed to clearly establish the nature and strength of HOCl absorption in the neighbourhood of 3200 Å. Some refinements in the theoretical calculations also seem desirable. In view of the difficulties involved in the laboratory determination of HOCl photodissociation cross-sections, it is suggested that a search for possible stratospheric HOCl by atmospheric spectroscopists would be worthwhile.     

On the dissociation of nitrogen by electron impact and by E.U.V. photo-absorption

The dissociation of N₂ by electron impact and by e.u.v. photo-absorption is studied, and it is shown that the forbidden predissociation of the numerous ¹Π_u and ¹Σ_u⁺ valence and Rydberg states of N₂ in the 11–24eV energy range is the dominant mechanism for N atom production. By measuring the absolute emission cross sections for the e.u.v. singlet bands of N₂ and by using the generalized oscillator strength data of Lassettre (1974), it has been possible to construct a detailed model of the total N₂ dissociation cross section which is in good agreement with the measurements of Winters (1966) and Niehaus (1967) and provides some insights into the maximum possible $\text{N(}{}^2\text{D)}$ yield from dissociative excitation. The total cross section for exciting N₂ e.u.v. radiation in the 800Å–1100Å wavelength range has been measured and found to have a value of 3.4 ×10^?17 cm² at 100 eV under optically thin conditions. Although this result implies that large fluxes of e.u.v. photons should be excited in auroral substorms and in the airglow, they are not observed, and we show that this development is a consequence of radiation entrapment and predissociation. The total cross section for dissociating N₂ by electron impact is given for optically thin and thick media. And some questions concerning the energy budget of a magnetospheric storm which are raised by these results, are discussed.     

The spectral reflectivity of select areas on Europa

The July 12, 1973, occultation of Europa by Io was observed in 30 wavelength channels in the spectral region λλ3200-11, 000 Å with the 200-inch Hale telescope and a multichannel spectrometer. The data are presented in absolute units above the Earth's atmosphere. The data are analyzed to obtain the spectral reflectivity of seven localized areas on the disk of Europa centered on 324°W longitude. The equatorial material is confirmed to be darker than the eastward-skewed bright north polar cap and a hint is evident that the darker material as well may be somewhat redder than the cap material.     

Geopotential harmonics of order 15 and odd degree from analysis of resonant orbits

We have analysed the variations of inclination in 13 satellite orbits as they pass slowly, under the action of air drag, through 15th-order resonance with the geopotential, when successive equatorial crossings are 24° apart and the ground track repeats after 15 rev. The size and form of the change in inclination are determined mainly by the values of the geopotential harmonics of 15th order and odd degree, $\text{C}\text{?}{}_{\mathrm{l,15}}$ and $\text{S}\text{?}{}_{\mathrm{l,15}}$ (with l = 15, 17, 19, …) in the usual notation. Our analysis gives values of these coefficients up to l = 33 as follows:

     

137.

The Future Of Geography     

Richard L. Morrill 《The Professional geographer》1975,27(1):1-1

     

138.

Food Deserts in the Prairies? Supermarket Accessibility and Neighborhood Need in Edmonton,Canada*     

Karen E. Smoyer‐Tomic  John C. Spence  Carl Amrhein 《The Professional geographer》2006,58(3):307-326

The U.S. and U.K. literatures have discussed “food deserts,” reflecting populated, typically urban, low‐income areas with limited access to full‐service supermarkets. Less is known about supermarket accessibility within Canadian cities. This article uses the minimum distance and coverage methods to determine supermarket accessibility within the city of Edmonton, Canada, with a focus on high‐need and inner‐city neighborhoods. The results show that for 1999 both of these areas generally had higher accessibility than the remainder of the city, but six high‐need neighborhoods had poor supermarket accessibility. We conclude by examining potential reasons for differences in supermarket accessibility between Canadian, U.S., and U.K. cities.     

139.

ELF propagation parameters for uniform models of the Earth–ionosphere waveguide     

Vadim C. Mushtak  Earle R. Williams 《Journal of Atmospheric and Solar》2002,64(18)

Uniform models for the Earth–ionosphere cavity are considered with particular attention to the physical properties of the ionosphere for the extremely low frequency (ELF) range. Two consistent features have long been recognized for the range: the presence of two distinct altitude layers of maximum energy dissipation within the lower ionosphere, and a “knee”-like change in the vertical conductivity profile representing a transition in dominance from ion-dominated to electron-dominated conductivity. A simplified two-exponential version of the Greifinger and Greifinger (1978) technique widely used in ELF work identifies two slopes in the conductivity profile and, providing accurate results in the ELF communication band (45–75 Hz), simulates too flat a frequency dependence of the quality factor within the Schumann resonance frequency range (5–40 Hz). The problem is traced to the upward migration, with frequency increasing, of the lower dissipation layer through the “knee” region resulting in a pronounced decrease of the effective scale height for conductivity. To overcome this shortcoming of the two-exponential approximation and still retain valuable model analyticity, a more general approach (but still based on the Greifinger and Greifinger formalism) is presented in the form of a “knee” model whose predictions for the modal frequencies, the wave phase velocities and the quality factors reasonably represent observations in the Schumann resonance frequency range.     

140.

Finite-difference modelling of two-dimensional elastic wave propagation in cracked media     

Vincent A. van Antwerpen  Wim A. Mulder  Gérard C. Herman 《Geophysical Journal International》2002,149(1):169-178

     

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l	109C?l,15	109S?l,15
15	?23.5 ± 0.8	?7.7 ± 0.8
17	6.3 ± 1.5	5.6 ± 1.5
19	?25.1 ± 2.5	?7.3 ± 2.3
21	27.8 ± 3.6	?0.7 ± 3.4
23	17.1 ± 4.1	13.9 ± 4.8
25	?1.1 ± 3.0	8.5 ± 4.2
27	10.0 ± 3.3	6.7 ± 2.7
29	?9.4 ± 3.5	0.1 ± 4.7
31	10.1 ± 5.4	3.8 ± 5.6
33	1.1 ± 5.7	3.1 ± 5.8

Food Deserts in the Prairies? Supermarket Accessibility and Neighborhood Need in Edmonton,Canada*

The U.S. and U.K. literatures have discussed “food deserts,” reflecting populated, typically urban, low‐income areas with limited access to full‐service supermarkets. Less is known about supermarket accessibility within Canadian cities. This article uses the minimum distance and coverage methods to determine supermarket accessibility within the city of Edmonton, Canada, with a focus on high‐need and inner‐city neighborhoods. The results show that for 1999 both of these areas generally had higher accessibility than the remainder of the city, but six high‐need neighborhoods had poor supermarket accessibility. We conclude by examining potential reasons for differences in supermarket accessibility between Canadian, U.S., and U.K. cities.     

ELF propagation parameters for uniform models of the Earth–ionosphere waveguide

Uniform models for the Earth–ionosphere cavity are considered with particular attention to the physical properties of the ionosphere for the extremely low frequency (ELF) range. Two consistent features have long been recognized for the range: the presence of two distinct altitude layers of maximum energy dissipation within the lower ionosphere, and a “knee”-like change in the vertical conductivity profile representing a transition in dominance from ion-dominated to electron-dominated conductivity. A simplified two-exponential version of the Greifinger and Greifinger (1978) technique widely used in ELF work identifies two slopes in the conductivity profile and, providing accurate results in the ELF communication band (45–75 Hz), simulates too flat a frequency dependence of the quality factor within the Schumann resonance frequency range (5–40 Hz). The problem is traced to the upward migration, with frequency increasing, of the lower dissipation layer through the “knee” region resulting in a pronounced decrease of the effective scale height for conductivity. To overcome this shortcoming of the two-exponential approximation and still retain valuable model analyticity, a more general approach (but still based on the Greifinger and Greifinger formalism) is presented in the form of a “knee” model whose predictions for the modal frequencies, the wave phase velocities and the quality factors reasonably represent observations in the Schumann resonance frequency range.