The use of tracers to assess drill-mud penetration depth into sandstone cores during deep drilling: method development and application

For the utilization of deep saline aquifers in the frame of geotechnical use, such as geological sequestration of CO₂, H₂ or energy storage, a baseline characterization of pristine reservoir rock cores is required to monitor changes in the indigenous microbial communities and pore fluids, and to study alterations in rock characteristics resulting from interaction with geological storage technologies. However, drilling procedures and technical fluids, particularly drill mud, are sources of core contamination. To measure the penetration of drill mud into the cores, three tracers (fluorescein, microspheres, and 4′,6-diamidino-2-phenylindole stained bacteria) were tested under laboratory conditions. The flow of drill mud into core samples was induced by applying uniaxial pressure differentials to the core, and the penetration depth was microscopically determined for each tracer. Fluorescein was extracted from the rock samples and quantified fluorometrically. The results indicate that all tested tracers are suitable for tracking drill-mud penetration. The actual penetration depth seems to be related to differences in mineral composition and texture as well as microfractures. Among all tested tracers, fluorescein labelling is the simplest, cheapest and most accurate method for analyzing the contamination of rock cores by technical fluids. The application of this tracer was successfully applied during two deep drilling campaigns at the CO₂ storage pilot site in Ketzin, Germany. The results highlight that the use of tracers is indispensable to ensure the quality of core samples for microbiological and biogeochemical analysis.     

Utility of the 2-D Multi-Electrode Resistivity Imaging Technique in Groundwater Exploration in the Voltaian Sedimentary Basin, Northern Ghana

Guinea worm and other water borne diseases associated with untreated surface water use have necessitated that communities are supplied with groundwater in the Northern Region of Ghana. The Electrical Resistivity Survey (ERS) method is one of the common geophysical survey techniques used for borehole siting in Ghana. Various groundwater exploration programs have utilized it by employing the four electrode system. However, the ERS has not been able to locate potential borehole sites successfully in the Voltaian Sedimentary Basin (VSB) in the Northern Region of Ghana although it has been successful in other geological formations. Unsatisfactory results obtained from the employment of the ERS system in the VSB therefore necessitated an experiment with the 2-D Multi-Electrode Resistivity Imaging (2-D MERI) technique. Field results show that the 2-D MERI is a robust and efficient technique: an improvement on the four electrode ERS system in terms of amount and quality of data obtained. The 2-D MERI interpretations were confirmed with a much improved borehole drilling success rate of 60% compared to 38% obtained using the ERS within the mudstone and shale formations. The 2-D MERI also indicated that very low resistivity layers in the VSB may not necessarily be good targets for borehole drilling and the generally held notion that groundwater cannot be found at depths more than 25 m is no longer tenable.     

Solar radio spectrography in Europe

Recent technical progress of solar radio spectrography is concerned with digital data recording, the achievement of high time and frequency resolution, and with an improved coverage of the radio range at short and long wavelengths. A spatially-distributed network of radio spectrographs allows for complementary information about solar events and periods of activity selected for detailed investigation.By modern radio spectrographs a wealth of not yet adequately classified spectral fine structures can be observed, some of them potentially intimately related to effects of fragmentation of flare energy and/or to processes related to coronal heating. Requirements for the choice of technical parameters of solar spectrographs for checking theoretical models of fundamental processes of energy release are reflected in modern instruments. Prospects for future observations are briefly included.     

Electrical conductivity measurements on olivines and pyroxenes under defined thermodynamic activities as a function of temperature and pressure

Electrical conductivities of Ni₂SiO₄, Fe₂SiO₄, and MgSiO₃ were measured on synthetic powders in the temperature range 340° to 1,100° C and at pressures up to 20 kbars. For ternary compounds such as olivines and pyroxenes the control of two further variables, like the chemical activities of two components are needed, besides temperature and pressure. The activities of the corresponding binary oxides were controlled by equilibrating the samples with their neighbour-phases. Control of the oxygen partial pressure was achieved by buffer techniques. From the slopes of the lg σ vs. 1/T lines the activation energies were calculated for 10 kbar: 0.56 eV and 2.7 eV for Ni₂SiO₄ in equilibrium with SiO₂ and Ni/NiO-buffer for the temperature range 500°–800°C and 800°–1,000°C resp. 0.52 eV for Fe₂SiO₄ in equilibrium with SiO₂ and metallic iron, and 0.38 eV in equilibrium with SiO₂ and magnetite; 1.11 eV for MgSiO₃ in equilibrium with SiO₂, and 1.25 eV in equilibrium with Mg₂SiO₄.     

Assessment of groundwater residence times in the pore aquifers of the River Elbe Basin

An area covering assessment of the groundwater residence times for the upper pore aquifers in the River Elbe Basin was performed. Residence times were determined by combining groundwater velocities and flow distances along each flow-path to the surface waters using a two-dimensional model approach. Groundwater velocity was calculated as a function of hydraulic conductivity, hydraulic gradient and effective yield of pore space. Flow paths were obtained by an analysis of the morphology of the groundwater table. The mean groundwater residence time in the pore aquifers of the River Elbe Basin was quantified to about 25 years. A strong temporal blurring in the different regions between less than one year and more than 250 years was obtained. For the regional groundwater management in the Elbe Basin the groundwater residence times are an important parameter, which helps to take into account the temporal dimension in the assessment of the impact of political measures aiming at the improvement of groundwater quality with regard to diffuse pollutants (e.g. nitrate).     

Cenomanian palaeotemperatures derived from the oxygen isotopic composition of brachiopods and belemnites: evaluation of Cretaceous palaeotemperature proxies

Sixty low-magnesium-calcite samples from Cenomanian articulate brachiopods, belemnites and oysters from the epicontinental shelf sea of Europe were geochemically and microscopically studied in order to evaluate their preservation and potential as carriers of palaeoenvironmental information. The sampled localities in northern Spain, Germany and southern England cover the transition between subtropical (25-30°N) and temperate (33-38°N) climates. Mean Cenomanian salinity-adjusted palaeotemperatures of diagenetically unaltered terebratulid and rhynchonellid brachiopods are 25.5ǃ.3 °C in Spain and 19.4ǃ.9 °C in southern England. The resulting low-to-mid-latitude meridional temperature gradient of ~0.7 °C per degree latitude is similar to the gradient today and suggests modern heat transport values for Cenomanian low latitudes. Oxygen isotopic composition of unaltered specimens of the Upper Cenomanian belemnite Praeactinocamax plenus (mean: 0.2‰) is enriched in ¹⁸O by 1‰ in comparison to brachiopod shells. Correspondingly, Upper Cenomanian palaeotemperatures derived from belemnite calcite (~13.0ǃ.3 °C) underestimate modelled mid-latitude sea surface temperatures by ~6 °C. Since P. plenus occurs as Boreal pulse fauna during a short interval in the Late Cenomanian, its heavy oxygen isotopic composition can be attributed either to migration from a cooler and/or deeper water mass or to unknown vital effects.     

Settlement History As Reflection Of Climate Change: The Case Study Of Lake Jues (Harz Mountains, Germany)

Postglacial sediments from Lake Jues, located at the SW margin of the Harz Mountains, were investigated for pollen, diatoms and sediment characteristics. The paper focuses on the time period between 7600 and 1200 y cal. BP (calibrated years before present), during which human impact began to influence the environnment of the lake. Climate variability was mainly inferred from sediment characteristics and changes in algal assemblages. The observed climatic changes coincide well with those recorded from other sites. Neolithic settlement started during the warm and dry Atlantic period. Intensive land use occurred under favourable climatic conditions during the Bronze and the Iron Ages, while human activities declined during cool and wet periods around 4000 and 2700 y cal. BP and after 2300 y cal. BP. The study shows that climate strongly influenced human settlement at remote locations like Lake Jues.     

A new probabilistic approach to estimating marine gastropod densities from baited traps

A new probabilistic approach is proposed to assess muricid species population abundances at scales relevant to both Ancient and Modern coastal fisheries. Motivated by the long‐term goal of reconstructing the dynamics of exploited murex populations during Antiquity, the objective was to estimate the population density of the banded dye‐murex, Hexaplex trunculus (Linnaeus, 1758) from successive captures with baited traps, using a method similar to the technique employed in the Mediterranean purple dye industry. The stochastic model developed simulates cumulative captures while accounting for high variability. It was calibrated with data acquired during a field trapping experiment (Crete Island, Greece). Traps’ catchability and Effective Area of Attraction (EAA) were estimated using the individual speed and behavioural response towards bait from laboratory experiments. Average density of H. trunculus was estimated as 2.2 ± 1.4 SE individuals per square metre, with no significant differences between seagrass and rocky habitats. The clearing time of successive capture experiments averaged 84 ± 6 SE hr. Clearing ca. 0.4 ha of subtidal area would be necessary to produce ca. 1.0 g of pure Tyrian purple pigment. The method described is generalizable to making population abundance estimates for similar groups, such as whelks, in modern fisheries.     

Sea-level change, carbon cycling and palaeoclimate during the Late Cenomanian of northwest Europe; an integrated palaeoenvironmental analysis

A new high resolution sea-level curve for the Late Cenomanian M. geslinianum Zone has been generated using sequence stratigraphic analysis on transects through the margins of the Anglo-Paris Basin in the UK and Saxony Basin in Germany. Transgressive sediments that bury a rocky shoreline in the Dresden area have proved particularly useful in determining both the absolute amount of sea-level change and the rate of rise. After a brief fall at the base of the M. geslinianum Zone, sea level rose rapidly through the higher part of the zone, resulting in an overall short term eustatic rise of 22–28 m. Biostratigraphy and carbon isotope stratigraphy have enabled detailed correlations to be made between marginal locations and thick, relatively complete, basinal successions. The basinal successions at Eastbourne, UK, and Gröbern, Germany, provide both geochemical proxies for palaeoenvironmental change, including oxygen and carbon isotope records, and an orbital timescale graduated in precession and eccentricity cycles. Integration of the sea-level history with palaeoclimate evolution, palaeoceanography and changes in carbon cycling allows a detailed reconstruction of events during the Late Cenomanian. Orbital forcing on long eccentricity maxima provides the underlying drive for these changes, but amplification by tectonic events and feedback mechanisms augmented the orbital effects and made the Cenomanian/Turonian Boundary Event distinctive. In particular, variations in atmospheric CO₂ caused by oceanic drawdown and a brief period of intense volcanic outgassing resulted respectively in short term cooling and warming events. The magnitude and high rates (up to 1 m/1 kyr) of sea-level rise are diagnostic of glacioeustasy, however improbable this may appear at the height of the Cretaceous greenhouse.