Isotope geochemistry of drainage from an acid mine impaired watershed,Oakland, California

Oxidation of sulfides at the Leona Heights Sulfur Mine has resulted in the liberation of acid, SO₄ and metals to Leona Creek. Previous research at the site has indicated Fe(II) oxidation at rates faster than would be predicted by abiotic oxidation alone, particularly in the segment of stream between the Adit and Leona Street sample stations. In order to assess the mechanisms responsible for sulfide oxidation, samples were collected for isotopic analysis of water and SO₄, the results of which were used to develop a stoichiometric isotope-balance model. This exercise indicated that the percentage of water-derived oxygen in SO₄ increased spatially from between 56% and 64% at the Adit to between 71% and 72% at Leona Street, illustrating that increased sulfide oxidation via Fe(III) was occurring within, or as water flows over, the waste rock, relative to water emanating directly from the former mine. The incorporation of water-derived oxygen in SO₄ during pyrite oxidation is a process controlled by Fe oxidizing bacteria such as A. ferrooxidans at low pH. The role of bacteria was further supported by estimates of the rate constant for Fe oxidation between sampling stations, yielding values that were approximately 10⁶ faster than abiotic Fe oxidation alone. Stable isotopic analysis of water further indicates a close correlation of adit spring water to the local meteoric water line, while ³H data indicate a groundwater apparent age, or time of travel from its primary zone of recharge, of <5–18 a. Additionally, the δ³⁴S data, in conjunction with reported albitized feldspars within the Leona Rhyolite host rock, indicate a magmatic origin of ore sulfur, contrary to previous interpretations at the site.     

The restoration of thrust systems and displacement continuity around the Mont Blanc massif,NW external Alpine thrust belt

Foreland-propagating external thrust belts may be considered as essentially plane strain phenomena so that displacements can be correlated throughout their linked, three-dimensional fault geometry. This approach has been applied to part of the northwest external French-Swiss Alps, around the Mont Blanc basement massif. Imbricates of basement and cover sequences on the SW margin of this massif restore to a width in excess of 77 km with an implicit shortening of at least 67 km. These displacements can be correlated with those in the neighbouring Helvetic nappes by transferring movements, via lateral branch lines, onto the Mont Blanc thrust. By reappraising thrust geometries, the Helvetic/Ultrahelvetic nappe complex has been restored to a width of 114 km to the ESE of the Aiguilles Rouges basement massif. Displacements on the internal (SE) margin of the Mont Blanc massif, estimated by balanced sections and a restoration of the Ultrahelvetic klippen in the sub-alps, exceed 59 km. Thrust continuity, incorporating the restorations of nappes and imbricate geometries around the Mont Blanc massif, is illustrated on a crude, restored branch-line map which also serves as a preliminary palaeogeographic reconstruction. External thrust systems, to the east of the external Belledonne/Aiguilles Rouges massif, restore to a width of at least 140 km in the footwall to the Frontal Pennine thrust.     

Paleomagnetic evidence for Jurassic deformation of the McCoy Mountains Formation,southeastern California and southwestern Arizona

The Mesozoic McCoy Mountains Formation is a 7.3-km-thick deformed clastic sequence exposed in six mountain ranges in southeastern California and southwestern Arizona. Interbedded with Jurassic volcanic rocks at its base, the McCoy Mountains Formation had been assigned a Cretaceous age based upon fossil angiosperm wood found in the upper third of the section. Characteristic natural remanent magnetism (NRM) from 145 oriented samples from 18 sites within the sedimentary terrane yield an in situ mean direction:I = 20.6°, D = 335.1°, α₉₅ = 7.7° (uncorrected for structural tilting). Opaque mineralogy and a failed fold test indicate that the NRM is a chemical remanence acquired post-folding. The paleomagnetic pole position calculated from the in situ mean direction falls adjacent to poles from the Summerville Formation and Canelo Hills Volcanics. We interpret these data to indicate that deformation, mild metamorphism, and resultant magnetization of the McCoy Mountains Formation occurred during Jurassic time. It is suggested that the McCoy Mountains Formation and underlying Jurassic volcanics were deposited adjacent to, and then deformed between, the North American craton and an outlying allochthonous terrane during Jurassic time.     

Effects of instream processes,discharge, and land cover on nitrogen export from southern Appalachian Mountain catchments

Catchments with minimal disturbance usually have low dissolved inorganic nitrogen (DIN) export, but disturbances and anthropogenic inputs result in elevated DIN concentration and export and eutrophication of downstream ecosystems. We studied streams in the southern Appalachian Mountains, USA, an area dominated by hardwood deciduous forest but with areas of valley agriculture and increasing residential development. We collected weekly grab samples and storm samples from nine small catchments and three river sites. Most discharge occurred at baseflow, with baseflow indices ranging from 69% to 95%. We identified three seasonal patterns of baseflow DIN concentration. Streams in mostly forested catchments had low DIN with bimodal peaks, and summer peaks were greater than winter peaks. Streams with more agriculture and development also had bimodal peaks; however, winter peaks were the highest. In streams draining catchments with more residential development, DIN concentration had a single peak, greatest in winter and lowest in summer. Three methods for estimating DIN export produced consistent results. Annual DIN export ranged from less than 200 g ha^?1 year^?1 for the less disturbed catchments to over 2,000 g ha^?1 year^?1 in the catchments with the least forest area. Land cover was a strong predictor of DIN concentration but less significant for predicting DIN export. The two forested reference catchments appeared supply limited, the most residential catchment appeared transport limited, and export for the other catchments was significantly related to discharge. In all streams, baseflow DIN export exceeded stormflow export. Morphological and climatological variation among watersheds created complexities unexplainable by land cover. Nevertheless, regression models developed using land cover data from the small catchments reasonably predicted concentration and export for receiving rivers. Our results illustrate the complexity of mechanisms involved in DIN export in a region with a mosaic of climate, geology, topography, soils, vegetation, and past and present land use.     

Seasonal and interannual behaviour of groundwater catchment boundaries in a Chalk aquifer

Groundwater catchment boundaries and their associated groundwater catchment areas are typically assumed to be fixed on a seasonal basis. We investigated whether this was true for a highly permeable carbonate aquifer in England, the Berkshire and Marlborough Downs Chalk aquifer, using both borehole hydrograph data and a physics‐based distributed regional groundwater model. Borehole hydrograph data time series were used to construct a monthly interpolated water table surface, from which was then derived a monthly groundwater catchment boundary. Results from field data showed that the mean annual variation in groundwater catchment area was about 20% of the mean groundwater catchment area, but interannual variation can be very large, with the largest estimated catchment size being approximately 80% greater than the smallest. The flow in the river was also dependent on the groundwater catchment area. Model results corroborated those based on field data. These findings have significant implications for issues such as definition of source protection zones, recharge estimates based on water balance calculations and integrated conceptual modelling of surface water and groundwater systems. Copyright © 2015 John Wiley & Sons, Ltd.     

Coordinated Observations of Comet Hale–Bopp between 32 and 860 GHz

Earth, Moon, and Planets - The concept of simultaneous multifrequency continuum observations, successfully tested on Comet Hyakutake, was applied to Comet Hale-Bopp, using the Heinrich Hertz...     

Noise in pressure transducer readings produced by variations in solar radiation

Variations in solar radiation can produce noise in readings from gauge pressure transducers when the transducer cable is exposed to direct sunlight. This noise is a result of insolation-induced heating and cooling of the air column in the vent tube of the transducer cable. A controlled experiment was performed to assess the impact of variations in solar radiation on transducer readings. This experiment demonstrated that insolation-induced fluctuations in apparent pressure head can be as large as 0.03 m. The magnitude of these fluctuations is dependent on cable color, the diameter of the vent tube, and the length of the transducer cable. The most effective means of minimizing insolation-induced noise is to use integrated transducer-data logger units that fit within a well. Failure to address this source of noise can introduce considerable uncertainty into analyses of hydraulic tests when the head change is relatively small, as is often the case for tests in highly permeable aquifers or for tests using distant observation wells.     

Seasonal cycling of arsenic species in a stratified,microtidal estuary (Huon River,Tasmania)

A detailed study of arsenic cycling in the Huon estuary, south-east Tasmania, was undertaken October 1996–September 1998. Arsenic species data were obtained during eight 3-monthly spatial surveys, and a time-series study at a single site in the estuary over a 7-mo period. The data have been correlated with other chemical measurements, including nutrients, salinity, and dissolved oxygen, and also with biological information about the microalgal species present. In the Huon estuary, arsenic cycling is almost entirely biologically influenced. The seasonal cycle of reduced, methylated, and hydride refractory arsenic species was similar to that found in other temperate estuaries of the Northern hemisphere, with greatest production occurring during summer months. Inorganic arsenic concentrations in the Huon River were very low [As(V+III): 0.023–0.057 μg l⁻¹], even when compared with other pristine systems. Concentrations at the seaward end of the estuary were typical of those found in unpolluted coastal seawater. The behavior of As(V+III) in the estuary was nearly conservative in all surveys except those conducted during summer (February), when significant depletion was observed at higher salinity. During these surveys, up to 60% of inorganic arsenic was apparently depleted from the water column with only a small proportion (20–25%) recycled as methylated and UV-labile arsenic species. This was particularly the case in a high salinity side-arm of the estuary, Port Cygnet. The extent of inorganic arsenic depletion correlated with cell numbers of the phytoplanktonPseudo-nitzschia. The fate of the missing inorganic arsenic is unclear, but the co-existence ofPseudo-nitzschia blooms with commercial mussel leases in Port Cygnet could provide one explanation for the loss.