Automated AF-demagnetization on the 2G-Enterprises through-bore,cryogenic magnetometer

Since the early sixties, alternating field demagnetization (AFD) has been a standard laboratory technique for demagnetizing rocks to expose the multicomponent structure of their natural remanent magnetization (NRM). In the majority of AFD implementations, however, the procedure remains as labour-intensive as ever. The implementation that we have developed at the Australian Geological Survey Organisation, automates the procedure for AFD based on the static method, and results in significant productivity and efficiency gains without compromising data quality. A properly formulated procedure for static AFD may be the only method of retrieving higher-coercivity components of natural remanence in samples prone to developing gyroremanence at higher alternating fields (AFs). Our AFD environment comprises: a 2G-Enterprises through-bore, cryogenic magnetometer; 2G AF-coils and control equipment; and personal computer software, developed by us, to control all procedural aspects for a complete AFD of a sample including, importantly, a counteracting procedure to neutralize the effects of gyroremanence build-up at higher AFs. With our system, AFD of 8 samples/day, each of 20+ steps, requires only 20 min of user attention compared with a full day for conventional systems.     

Steady, annual, and monthly recharge implied by deep unconfined aquifer flow

We consider the response of a deep unconfined horizontal aquifer to steady, annual, and monthly recharge. A groundwater divide and a zero head reservoir constrain the aquifer, so that sinusoidal monthly and aperiodic annual recharge fluctuations create transient specific discharge near the reservoir and an unsteady water table elevation inland. One existing and two new long-term data sets from the Plymouth-Carver Aquifer in southeastern Massachusetts calibrate and confirm hydraulic properties in a set of analytical models. [Geohydrology and simulated groundwater flow, 1992] data and a new power law for tritiugenic helium to tritium ratios calibrate the steady recharge that drives the classical parabolic model of steady hydraulics [Applied Hydrogeology, 2001]. Observed water table and gradient fluctuations calibrate the transient recharge models. In the latter regard, monitoring wells within 1 km of Buttermilk Bay exhibit appreciable specific discharge and reduced water table fluctuations. We apply [Trans Am Geophys Union 32(1951)238] periodic model to the monthly hydraulics and a recharge convolution integral [J Hydrol 126(1991)315] to annual flow. An infiltration fraction of 0.79 and a consumptive use coefficient of 1.08×10⁻⁸ m/s °C relate recharge to precipitation and daylight weighted temperature across all three time scales. Errors associated with this recharge relation decrease with increasing time scale.     

Influence of the Mississippi River on <Emphasis Type="Italic">Pseudo-nitzschia</Emphasis> spp. Abundance and Toxicity in Louisiana Coastal Waters

The presence of domoic acid (DA) toxin from multiple species of Pseudo-nitzschia is a concern in the highly productive food webs of the northern Gulf of Mexico. We documented the Pseudo-nitzschia presence, abundance, blooms, and toxicity over three years along a transect ～100 km west of the Mississippi River Delta on the continental shelf. Pseudo-nitzschia were present throughout the year and occurred in high abundances (>10⁴ cells l^?1) in the early spring months during high Mississippi River (MSR) flow (～20,000 m³ s^?1) but were most abundant (>10⁶ cells l^?1) when MSR discharge was relatively lower among the spring months. A high particulate toxin production (maximum reaching 13 μg DA l^?1) was associated with the high cell abundances and exceeded, by an order of magnitude, prior reports of particulate DA concentrations in Louisiana coastal waters. Differences in Pseudo-nitzschia peak times and its toxicity were correlated mainly with the timing and magnitude of MSR discharge and changes in associated parameters such as nutrient stoichiometry and salinity. A negative relationship between high MSR discharge and Pseudo-nitzschia and particulate DA concentrations was documented. These riverine dynamics have the potential to influence DA contamination in pelagic and benthic food webs in the coastal waters of the northern Gulf of Mexico.     

Design principles for origin-destination flow maps

Origin-destination flow maps are often difficult to read due to overlapping flows. Cartographers have developed design principles in manual cartography for origin-destination flow maps to reduce overlaps and increase readability. These design principles are identified and documented using a quantitative content analysis of 97 geographic origin-destination flow maps without branching or merging flows. The effectiveness of selected design principles is verified in a user study with 215 participants. Findings show that (a) curved flows are more effective than straight flows, (b) arrows indicate direction more effectively than tapered line widths, and (c) flows between nodes are more effective than flows between areas. These findings, combined with results from user studies in graph drawing, conclude that effective and efficient origin-destination flow maps should be designed according to the following design principles: overlaps between flows are minimized; symmetric flows are preferred to asymmetric flows; longer flows are curved more than shorter or peripheral flows; acute angles between crossing flows are avoided; sharp bends in flow lines are avoided; flows do not pass under unconnected nodes; flows are radially distributed around nodes; flow direction is indicated with arrowheads; and flow width is scaled with represented quantity.     

Chemical oceanographic influences on sediment accumulations of a carbonate ramp: Holocene Yucatan Shelf,Mexico

Global controls on the oceanographic influences on the nature of carbonate factories are broadly understood. The details of the influences of changes in temperature and nutrients across individual carbonate shelves are less well constrained, however. This study explores spatial and temporal variations in chemical oceanography along and across the Yucatan Shelf, a modern carbonate ramp, and how these factors relate to variable bottom character, sediment and sediment geochemistry. In‐situ sensors and remote‐sensing data indicate the sporadic presence of cool, upwelled water with low dissolved oxygen and elevated Chlorophyll‐a. This current‐driven, westward flow of upwelled water is most evident in a zone just offshore of the northern peninsular shoreline, but its influence wanes ca 75 km offshore and as the shore turns southward. The impacts of this water mass include a transitional photozoan–heterozoan assemblage with biosiliceous components, relict grains and common thin Holocene sediment accumulations nearshore; further offshore are coralgal reefs and expansive sand plains. Geochemical proxies of bulk sediment, including high δ¹⁸O and elevated HREE/LREE (heavy rare‐earth element/light rare‐earth element) ratios near, and downcurrent of, the upwelling source, are interpreted to represent the signal of nearshore, westward movement of the cool and nutrient‐rich, upwelled water. Collectively, these data emphasize how local processes such as upwelling and longshore transport can variably influence carbonate sediment accumulations and their geochemical signatures, both along and across individual shelves. These data and insights provide an analogue for the influences of spatial variability of water masses in the geological record, and for accurate interpretation of stratigraphic changes of sedimentary and geochemical proxy data in carbonate archives.     

Intraseasonal and interannual climate variability

Major advances in our understanding of intraseasonal-interannual climate variability during the past three decades are reviewed. Prospects for prediction on these time-scales are briefly discussed.Paper based on talk presented at the session honoring J. Murray Mitchell at the December 1986 AGU meeting in San Francisco, CA.     

Rare-Earth Element Reference Samples for Electron Microprobe Analysis

Fourteen rare-earth (plus scandium and yttrium) orthophosphates have been synthesized and characterized for use as electron microprobe reference samples. These reference samples are single-element phosphates that are homogeneous, stable under the electron beam, and free of interfering elements. They have a stoichiometric composition (RPO4) with the element of interest (R) ranging from 32 to 64 weight percent.     

Tide gauge records,water level rise,and subsidence in the Northern Gulf of Mexico

Long-term water level changes in the northern Gulf of Mexico were examined using tide gauge records for this century. Strong coherence exists between the annual mean water changes at Galveston, Texas, and (1) the relatively geologically-stable west coast of Florida, (2) global mean sea level, and 93) the subsiding Louisiana coast. Water levels at the Galveston gauge, one of the longest records (81 yr), have risen steadily, but not accelerated over the long-term. The apparent acceleration of water rise in the recent two decades is within the historical pattern, and is probably driven by regional or global, but not local climatic factors. Because eustatic sea level has risen steadily this century, the analysis supports the conclusion that regional geologic subsidence has not varied significantly over the tide gauge record (1909–1988). Variations in the estimates of subsidence in the surface layers are generally consistent with the generally accepted understanding of the geology of deltaic processes on this coast.