The influence of pressure and composition on the viscosity of andesitic melts

The effect of pressure and composition on the viscosity of both anhydrous and hydrous andesitic melts was studied in the viscosity range of 10⁸ to 10^11.5 Pa · s using parallel plate viscometry. The pressure dependence of the viscosity of three synthetic, iron-free liquids (andesite analogs) containing 0.0, 1.06, and 1.96 wt.% H₂O, respectively, was measured from 100 to 300 MPa using a high-P-T viscometer. These results, combined with those from Richet et al. (1996), indicate that viscosities of anhydrous andesitic melts are independent of pressure, whereas viscosities of hydrous melts slightly increase with increasing pressure. This trend is consistent with an increased degree of depolymerization in the hydrous melts. Compositional effects on the viscosity were studied by comparing iron-free and iron-bearing compositions with similar degrees of depolymerization. During experiments at atmospheric and at elevated pressures (100 to 300 MPa), the viscosity of iron-bearing anhydrous melts preequilibrated in air continuously increased, and the samples became paramagnetic. Analysis of these samples by transmission electron microscopy showed a homogeneous distribution of crystals (probably magnetite) with sizes in the range of 10 to 50 nm. No significant difference in the volume fractions of crystals was found in samples after annealing for 170 to 830 min at temperatures ranging from 970 to 1122 K. An iron-bearing andesite containing 1.88 wt.% H₂O, which was synthesized at intrinsic fO₂ conditions in an internally heated pressure vessel, showed a similar viscosity behavior as the anhydrous melts. The continuous increase in viscosity at a constant temperature is attributed to changes of the melt structure due to exsolution of iron-rich phases. By extrapolating the time evolution of viscosity down to the time at which the run temperature was reached, for both the anhydrous (at 1055 K) and the hydrous (at 860 K) iron-bearing andesite, the viscosity is 0.7 log units lower than predicted by the model of Richet et al. (1996). This may be explained by differences in structural properties of Fe²⁺ and Fe³⁺ and their substitutes Mg²⁺, Ca²⁺, and Al³⁺, which were used in the analogue composition.The effect of iron redox state on the viscosity of anhydrous, synthetic andesite melts was studied at ambient pressure using a dilatometer. Reduced iron-bearing samples were produced by annealing melts in graphite crucibles in an Ar/CO atmosphere for different run times. In contrast to the oxidized sample, no variation of viscosity with time and no exsolution of iron oxide phases was observed for the most reduced glasses. This indicates that trivalent iron promotes the exsolution of iron oxide in supercooled melts. With decreasing Fe³⁺/ΣFe ratio from 0.58 to 0.34, the viscosity decreases by ∼1.6 log units in the investigated temperature range between 964 and 1098 K. A more reduced glass with Fe³⁺/ΣFe = 0.21 showed no additional decrease in viscosity. Our conclusion from these results is that the viscosity of natural melts may be largely overestimated when using data obtained from samples synthesized in air.     

Interactions between human communities and estuaries in the Pacific Northwest: Trends and implications for management

This paper explores social, and economic aspects of coastal communities crucial to the management of estuaries in the Pacific Northwest. These aspects include the changing demographics and economies of coastal communities, and the public perceptions, attitudes, and values pertaining to estuarine ecosystems. Information from Willapa Bay and Grays Harbor in Washington and Tillamook, Yaquina, and Coos Bays in Oregon shows that the coastal communities are growing more slowly than the states overall., that the populations are relatively old, and that, although the local economies continue to rely on them, the extractive natural resource industries (fishing, aquaculture, agriculture, forest products) are declining in importance relative to tourism, recreation, and retirement industries. These trends suggest that human uses of the estuaries are changing in character, and altering the management problems. Coastal residents choose to live in these communities to enjoy the views and scenery, to experience rural living, to be near the ocean, and to recreate outdoors. People express coherent perceptions of risks to the estuaries, especially the threats of declining fish habitats, oil spills, shoreline development, invasive species, and logging in upland areas> Residential land values are enhanced by the presence of wetlands and forests and are diminished by the presence of hazardous waste sites. We conclude that, if recent trends in population age structure, income sources, and employment status continue, public attitudes and values will move towards stronger environmental protection. Because ecosystem management involves local public participation and collaboration, estuarine managers will be faced with both increased demands and opportunities.     

Climate variability and rural livelihoods: assessing the impact of seasonal climate forecasts in Lesotho

Climate variability acutely affects rural livelihoods and agricultural productivity, yet it is just one of many stresses that vulnerable rural households have to cope with. A livelihood approach is used to assess the potential role that seasonal climate forecasts might play in increasing adaptive capacity in response to climate variability, using Lesotho as a case study. An examination of the assets and strategies that rural households employ enables a holistic assessment of the impact seasonal forecasts could have on rural livelihoods. This research thereby bridges macro-level variability with local-level impacts and adaptation to provide insight into the dynamics of forecast use and impact among vulnerable groups.     

Two serendipitous low-mass LMC clusters discovered with HST1

We present V and I photometry of two open clusters in the LMC down to V ∼26. The clusters were imaged with the Wide Field and Planetary Camera 2 (WFPC2) on board the Hubble Space Telescope ( HST ), as part of the Medium Deep Survey Key Project. Both are low-luminosity ( M_V ∼−3.5), low-mass ( M ∼10³ M⊙) systems. The chance discovery of these two clusters in two parallel WFPC2 fields suggests a significant incompleteness in the LMC cluster census near the bar. One of the clusters is roughly elliptical and compact, with a steep light profile, a central surface brightness μ _V (0)∼20.2 mag arcsec⁻², a half-light radius r _hl∼0.9 pc (total visual major diameter D ∼3 pc) and an estimated mass M ∼1500 M⊙. From the colour–magnitude diagram and isochrone fits we estimate its age as τ∼(2–5)×10⁸ yr. Its mass function has a fitted slope of Γ=Δlogφ( M )/Δlog M =−1.8±0.7 in the range probed (0.9≲ M /M⊙≲4.5). The other cluster is more irregular and sparse, having shallower density and surface brightness profiles. We obtain Γ=−1.2±0.4, and estimate its mass as M ∼400 M⊙. A derived upper limit for its age is τ≲5×10⁸ yr. Both clusters have mass functions with slopes similar to that of R136, a massive LMC cluster, for which HST results indicate Γ∼−1.2. They also seem to be relaxed in their cores and well contained in their tidal radii.     

Strength Behavior of Marine Sands at Elevated Confining Stresses

A testing program was initiated to determine the stress-strain and strength behavior of two very different marine sands (a calcareous sediment from South Australia and a siliceous sediment from the United Kingdom) at elevated confining pressures. The testing matrix consisted of a series of isotropically consolidated, undrained (CIU) and drained (CID), triaxial compression tests on samples of naturally deposited calcareous and siliceous sediment and remolded calcareous sediment. It was found that the calcareous samples displayed little cemented behavior during shear. For tests conducted at pressures up to 1.5 MPa, a significant amount of particle crushing occurred in the calcareous samples but not in the siliceous samples. Particle degradation and reorientation facilitates transitions from dilative to contractive behavior with increases in confining stress. The calcareous sediment exhibited contractive behavior at confining pressures above approximately 500 kPa and the siliceous sediment remained dilative at stresses up to 1 MPa during undrained loading. Comparison with data collected by the University of Sydney (CID tests with confining pressures up to 60 MPa) showed that most of the variations in strength behavior occurred within the low stress range (up to 2 MPa) tests conducted at URI. This was evident in the friction angle data and in the reloading Young's modulus data.     

Lithological controls on biological activity and groundwater chemistry in Quaternary sediments

Depth profiles of solute chemistry and sulfate isotopic compositions are presented for groundwater and pore water in a sequence of Quaternary glacial outwash sediments. Sand units show evidence for hydraulic connection to the surface and thus modern sources of solutes. Finer‐grained sediments show a general pattern of increasing solute concentrations with depth, with sulfate derived from ancient rainwater and pyrite oxidation in the soil/drift. In these sediments sulfate has undergone bacterial sulfate reduction (BSR) to produce biogenic sulfide. In clay sediments, with d₁₀ ≤ 1·6 µm, high concentrations of sulfate and acetate now co‐exist, implying that BSR is inhibited. The correlation with smaller sediment grain size indicates that this is due to pore size exclusion of the sulfate reducing bacteria. Mechanical restriction of microbial function thus provides a fundamental limitation on microbial respiration in buried clay‐rich sediments, which acts as a control on the chemical evolution of their pore waters. Copyright © 2009 John Wiley & Sons, Ltd.     

Exploiting radiation damage control on apatite (U–Th)/He dates in cratonic regions

Apatites from four pairs of samples of Precambrian basement from the western Canadian shield were analyzed by (U–Th)/He thermochronometry to test for the influence of radiation damage on apatite (U–Th)/He dates in this cratonic region. Recent studies have demonstrated that the accumulation of radiation damage increases the apatite He retentivity, so that apatites with a span of effective U concentrations, eU, that experienced the same thermal history may be characterized by a range of closure temperatures. In this investigation, each sample pair consisted of a mafic dike cross-cutting felsic gneisses from a single outcrop or nearby outcrops that contained apatites with a span of eU. The apatites yielded (U–Th)/He dates from 846 to 123 Ma, and were positively correlated with eU within each sample pair. These results can be explained using a model that tracks the evolution of He mobility in response to the accumulation of radiation damage. When coupled with regional geological constraints, the data appear to require partial to complete He loss due to burial and reheating in Phanerozoic time. New apatite fission- track dates and length data were obtained for five of these samples. The apatite fission- track dates are Proterozoic regardless of apatite eU. Thermal history simulations indicate that the apatite fission-track data are compatible with the (U–Th)/He results, although the thermal histories are not identical in detail and the fission-track results alone do not require Phanerozoic heating. Together the data are consistent with burial of this region by ≥ 1 km of Phanerozoic strata that were subsequently denuded, thus pointing toward significant Phanerozoic deposition in the North American cratonic interior hundreds of kilometers east of where previously documented. The results suggest that exploiting radiation damage control on apatite (U–Th)/He dates through investigation of surface sample apatites with a span of closure temperatures can impose tighter restrictions on thermal histories in low relief cratonic landscapes than was previously possible.     

Spatial and temporal growth rate variation of Bay Anchovy (Anchoa mitchilli) larvae in the Mid Hudson River estuary

Estuaries are critical habitats for larvae and juveniles of many marine fishes, possibly because they promote high growth rates and survival rates. We investigated spatial and temporal changes in growth rate of larval bay anchovy (Anchoa mitchilli), in the middle Hudson River estuary where abundance of larvae is high. In two consecutive summer seasons, we sampled larvae at 4 sites evenly spaced over 45 km, at weekly intervals for up to a month. We examined otoliths to determine age in days and then used age-length regressions to estimate growth rate. In 1995, larval anchovy growth rates varied from 0.39 to 0.88 mm d⁻¹ (median=0.48 mm d⁻¹). In 1996, growth rates varied from 0.41 to 0.77 mm d⁻¹ (median=0.55 mm d⁻¹). In both years, we found significant spatial and temporal variation in growth rate. Larvae collected in the upper portion of Haverstraw Bay tended to grow more slowly than larvae collected in other sites. The dates on which the most rapidly growing larvae were collected varied from site to site. Neither temperature nor salinity variations explained growth rate differences. Growth rate variation, probably governed by patches of zooplankton, occurred on temporal scales of a week and spatial scales of 15 km.