Spatial variation in fluid flow and geochemical fluxes across the sediment-seawater interface at the Carlos Ribeiro mud volcano (Gulf of Cadiz)

Submarine mud volcanism is an important pathway for transfer of deep-sourced fluids enriched in hydrocarbons and other elements into the ocean. Numerous mud volcanoes (MVs) have been discovered along oceanic plate margins, and integrated elemental fluxes are potentially significant for oceanic chemical budgets. Here, we present the first detailed study of the spatial variation in fluid and chemical fluxes at the Carlos Ribeiro MV in the Gulf of Cadiz. To this end, we combine analyses of the chemical composition of pore fluids with a 1-D transport-reaction model to quantify fluid fluxes, and fluxes of boron, lithium and methane, across the sediment-seawater interface. The pore fluids are significantly depleted in chloride, but enriched in lithium, boron and hydrocarbons, relative to seawater. Pore water profiles of sulphate, hydrogen sulphide and total alkalinity indicate that anaerobic oxidation of methane occurs at 34-180 cm depth below seafloor. Clay mineral dehydration, and in particular the transformation of smectite to illite, produces pore fluids that are depleted in chloride and potassium. Profiles of boron, lithium and potassium are closely related, which suggests that lithium and boron are released from the sediments during this transformation. Pore fluids are expelled into the water column by advection; fluid flow velocities are 4 cm yr⁻¹ at the apex of the MV but they rapidly decrease to 0.4 cm yr⁻¹ at the periphery. The associated fluxes of boron, lithium and methane vary between 7-301, 0.5-6 and 0-806 mmol m⁻² yr⁻¹, respectively. We demonstrate that fluxes of Li and B due to mud volcanism may be important on a global scale, however, release of methane into the overlying water column is suppressed by microbial methanotrophy.     

The contribution of agricultural and urban activities to inorganic carbon fluxes within temperate watersheds

The lateral transport of bicarbonate as dissolved inorganic carbon (DIC) to the oceans is an integral component of the global carbon budget and can represent the sequestration of CO₂ from the atmosphere. Recently studies have implicated land use change, in particular agricultural development, as an accelerator of bicarbonate export. However, due to the co-variation of land use, bedrock and surficial geologies, and the relationship between bicarbonate export and climate, the impact of anthropogenic activities on DIC export remains an important research question. In order to examine the land use controls on DIC export from small temperate watersheds we sampled 19 streams draining catchments of varying land uses with similar bedrock and surficial geologies. In addition to an agricultural effect, there was a strong correlation between the percent of watershed in urban development and DIC concentrations and DIC yields. Urban watersheds exported 7.8 times more DIC than their nearby forested counterparts and 2.0 times more DIC than nearby agricultural catchments. Isotopic data suggest that excess DIC export from altered systems results from increased chemical weathering, enhanced CO₂ production within urban green spaces, and as a result of organic matter loading from septic systems and leaky sewer lines. Furthermore, we found that nitrogen additions (e.g. fertilizers and manure) are aiding in the dissolution of lime, increasing the total export of DIC from agricultural watersheds. Calculated anthropogenic loading rates ranged from 0.43 to 0.86 mol C m^− 2 yr^− 1. These loading rates suggest that a significant portion of global DIC export might be attributable to human activities, although the impacts on CO₂ sequestration are difficult to determine.     

Physical criteria for distinguishing sandy tsunami and storm deposits using modern examples

Modern subaerial sand beds deposited by major tsunamis and hurricanes were compared at trench, transect, and sub-regional spatial scales to evaluate which attributes are most useful for distinguishing the two types of deposits. Physical criteria that may be diagnostic include: sediment composition, textures and grading, types and organization of stratification, thickness, geometry, and landscape conformity.

Published reports of Pacific Ocean tsunami impacts and our field observations suggest that sandy tsunami deposits are generally < 25 cm thick, extend hundreds of meters inland from the beach, and fill microtopography but generally conform to the antecedent landscape. They commonly are a single homogeneous bed that is normally graded overall, or that consists of only a few thin layers. Mud intraclasts and mud laminae within the deposit are strong evidence of tsunami deposition. Twig orientation or other indicators of return flow during bed aggradation are also diagnostic of tsunami deposits. Sandy storm deposits tend to be > 30 cm thick, generally extend < 300 m from the beach, and will not advance beyond the antecedent macrotopography they are able to fill. They typically are composed of numerous subhorizontal planar laminae organized into multiple laminasets that are normally or inversely graded, they do not contain internal mud laminae and rarely contain mud intraclasts. Application of these distinguishing characteristics depends on their preservation potential and any deposit modifications that accompany burial.

The distinctions between tsunami and storm deposits are related to differences in the hydrodynamics and sediment-sorting processes during transport. Tsunami deposition results from a few high-velocity, long-period waves that entrain sediment from the shoreface, beach, and landward erosion zone. Tsunamis can have flow depths greater than 10 m, transport sediment primarily in suspension, and distribute the load over a broad region where sediment falls out of suspension when flow decelerates. In contrast, storm inundation generally is gradual and prolonged, consisting of many waves that erode beaches and dunes with no significant overland return flow until after the main flooding. Storm flow depths are commonly < 3 m, sediment is transported primarily as bed load by traction, and the load is deposited within a zone relatively close to the beach.     

Long-term effects of anthropogenic CO<Subscript>2</Subscript> emissions simulated with a complex earth system model

A new complex earth system model consisting of an atmospheric general circulation model, an ocean general circulation model, a three-dimensional ice sheet model, a marine biogeochemistry model, and a dynamic vegetation model was used to study the long-term response to anthropogenic carbon emissions. The prescribed emissions follow estimates of past emissions for the period 1751–2000 and standard IPCC emission scenarios up to the year 2100. After 2100, an exponential decrease of the emissions was assumed. For each of the scenarios, a small ensemble of simulations was carried out. The North Atlantic overturning collapsed in the high emission scenario (A2) simulations. In the low emission scenario (B1), only a temporary weakening of the deep water formation in the North Atlantic is predicted. The moderate emission scenario (A1B) brings the system close to its bifurcation point, with three out of five runs leading to a collapsed North Atlantic overturning circulation. The atmospheric moisture transport predominantly contributes to the collapse of the deep water formation. In the simulations with collapsed deep water formation in the North Atlantic a substantial cooling over parts of the North Atlantic is simulated. Anthropogenic climate change substantially reduces the ability of land and ocean to sequester anthropogenic carbon. The simulated effect of a collapse of the deep water formation in the North Atlantic on the atmospheric CO₂ concentration turned out to be relatively small. The volume of the Greenland ice sheet is reduced, but its contribution to global mean sea level is almost counterbalanced by the growth of the Antarctic ice sheet due to enhanced snowfall. The modifications of the high latitude freshwater input due to the simulated changes in mass balance of the ice sheet are one order of magnitude smaller than the changes due to atmospheric moisture transport. After the year 3000, the global mean surface temperature is predicted to be almost constant due to the compensating effects of decreasing atmospheric CO₂ concentrations due to oceanic uptake and delayed response to increasing atmospheric CO₂ concentrations before.     

Diapycnal heat flux and mixed layer heat budget within the Atlantic Cold Tongue

Sea surface temperatures (SSTs) in the eastern tropical Atlantic are crucial for climate variability within the tropical belt. Despite this importance, state-of-the-art climate models show a large SST warm bias in this region. Knowledge about the seasonal mixed layer (ML) heat budget is a prerequisite for understanding SST mean state and its variability. Within this study all contributions to the seasonal ML heat budget are estimated at four locations within the Atlantic cold tongue (ACT) that are representative for the western (0°N, 23°W), central (0°N, 10°W) and eastern (0°N, 0°E) equatorial as well as the southern (10°S, 10°W) ACT. To estimate the contribution of the diapycnal heat flux due to turbulence an extensive data set of microstructure observations collected during ten research cruises between 2005 and 2012 is analyzed. The results for the equatorial ACT indicate that with the inclusion of the diapycnal heat flux the seasonal ML heat budget is balanced. Within the equatorial region, the diapycnal heat flux is essential for the development of the ACT. It dominates over all other cooling terms in the central and eastern equatorial ACT, while it is of similar size as the zonal advection in the western equatorial ACT. In contrast, the SST evolution in the southern ACT region can be explained entirely by air-sea heat fluxes.     

Molecular simulation of humic substance-Ca-montmorillonite complexes

An understanding of the processes that lead to long-term stabilization of organic matter in soils is essential to the effective implementation of strategies designed to mitigate CO₂ loss from the soil carbon reservoir in temperate climatic zones. Decomposition studies indicate that montmorillonite, a smectite that often forms with interlayers rich in Ca²⁺, greatly retards the microbial mineralization of soil organic matter. We performed a series of atomistic simulations designed to identify favorable molecular-scale organo-mineral interactions within nanoscale, hydrated complexes consisting of a humic substance and Ca-montmorillonite. Both protonated and Ca-saturated forms of the model humic molecule, representing acidic and circumneutral solution conditions, respectively, were studied within the hydrated interlayer region of a rigid-atom model of Ca-montmorillonite. The protonated humic substance formed direct hydrophobic and hydrogen bonding (H-bonding) interactions with the clay mineral. A few polar organic groups adsorbed via water bridging interactions. The Ca-saturated humic substance adsorbed via numerous cation bridges, less numerous water bridges, and indirect H-bonding interactions mediated by water molecules. Application of molecular modeling techniques to this complex organo-mineral system thus allowed identification of interactions favorable to carbon sequestration under both acidic and circumneutral conditions.     

Laboratory condensation of refractory dust in protosolar and circumstellar conditions

In order to better understand condensation processes that took place in the solar nebula and to evaluate the effect of kinetics on the condensed matter, we have built an experimental apparatus for studying condensation of multi-elemental refractory gases at high-temperature and low-pressure. The condensation of a Mg-Si-rich gas, with solar interelement ratios of Ca, Al, Mg and Si, and of a Ca-Al-rich gas under a total pressure of ∼4 × 10⁻³ bar at temperatures from 1045 to 1285 °C and for run times of 4-60 min results in direct formation of crystalline oxides or silicates such as corundum, spinel, anorthite, melilite, Al-diopside, forsterite and enstatite. The mineralogy of the condensates, close to that predicted at equilibrium, varies with the duration of an experiment and the temperature of condensation. The chemical reactions between gas and condensates are rapid enough to attain a steady state in less than one hour. The condensation results in chemical fractionation of the gas, i.e. a depletion of the gas in refractory elements at high temperature. Finally, besides revealing the textures of refractory crystals, which condense from a gas of complex chemical composition, this study shows that certain phases, such as spinel, have favored kinetics of condensation. Our experimental results confirm that refractory inclusions in primitive meteorites could have formed by condensation from a hot nebular gas. Similarly, we confirm that crystalline grains can condense at high temperature in the outflows of evolved stars. In both cases, our results indicate that kinetic processes certainly influence grain mineralogy. Kinetic processes must thus be taken into account in modeling the pressure-temperature conditions of circumstellar environments.     

Évolution de l'onde semi-diurne M2 de la marée à Brest de 1846 à 2005

The work of searching, recovering and quality control of ancient sea-level measurements at Brest is presented. This work enables us to complete a study carried out by Cartwright in 1972, which showed a decrease in the tidal M2 semi-diurnal amplitude of 1% per century. After including these ancient data, as well as the last four decades of observations in the analysis, our results show an increase of the amplitude of M2 after 1960 and a decrease before 1880, suggesting a long-period oscillation rather than a steady secular trend. To cite this article: N. Pouvreau et al., C. R. Geoscience 338 (2006).     

The degree of urbanization across the globe is not reflected in the δN of seagrass leaves

Many studies show that seagrass δ¹⁵N ratios increase with the amount of urbanization in coastal watersheds. However, there is little information on the relationship between urbanization and seagrass δ¹⁵N ratios on a global scale. We performed a meta-analysis on seagrass samples from 79 independent locations to test if seagrass δ¹⁵N ratios correlate with patterns of population density and fertilizer use within a radius of 10–200 km around the sample locations. Our results show that seagrass δ¹⁵N ratios are more influenced by intergeneric and latitudinal differences than the degree of urbanization or the amount of fertilizer used in nearby watersheds. The positive correlation between seagrass δ¹⁵N ratios and latitude hints at an underlying pattern in discrimination or a latitudinal gradient in the ¹⁵N isotopic signature of nitrogen assimilated by the plants. The actual mechanisms responsible for the correlation between δ¹⁵N and latitude remain unknown.     

Estimating uncertainty associated with water stages from a single SAR image

It is the goal of remote sensing to infer information about objects or a natural process from a remote location. This invokes that uncertainty in measurement should be viewed as central to remote sensing. In this study, the uncertainty associated with water stages derived from a single SAR image for the Alzette (G.D. of Luxembourg) 2003 flood is assessed using a stepped GLUE procedure. Main uncertain input factors to the SAR processing chain for estimating water stages include geolocation accuracy, spatial filter window size, image thresholding value, DEM vertical precision and the number of river cross sections at which water stages are estimated. Initial results show that even with plausible parameter values uncertainty in water stages over the entire river reach is 2.8 m on average. Adding spatially distributed field water stages to the GLUE analysis following a one-at-a-time approach helps to considerably reduce SAR water stage uncertainty (0.6 m on average) thereby identifying appropriate value ranges for each uncertain SAR water stage processing factor. For the GLUE analysis a Nash-like efficiency criterion adapted to spatial data is proposed whereby acceptable SAR model simulations are required to outperform a simpler regression model based on the field-surveyed average river bed gradient. Weighted CDFs for all factors based on the proposed efficiency criterion allow the generation of reliable uncertainty quantile ranges and 2D maps that show the uncertainty associated with SAR-derived water stages. The stepped GLUE procedure demonstrated that not all field data collected are necessary to achieve maximum constraining. A possible efficient way to decide on relevant locations at which to sample in the field is proposed. It is also suggested that the resulting uncertainty ranges and flood extent or depth maps may be used to evaluate 1D or 2D flood inundation models in terms of water stages, depths or extents. For this, the extended GLUE approach, which copes with the presence of uncertainty in the observed data, may be adopted.