Paleolithospheric structure revealed by continental geoid anomalies

Lithospheric geoid anomalies record changes in elevation and potential energy experienced by continental lithosphere. Estimates of local isostatic equilibration and potential energy, in tandem with lithosphere-related geoid anomalies, can be used to estimate paleolithospheric thickness, providing a clearer understanding of how and why continental topography is developed. We employ several simplifying assumptions about the crustal and mantle lithosphere density and structure (and readily acknowledge that our results are therefore first-order approximations) to predict the pre-orogenic structure of the lithosphere. At the outset we emphasize that while this approach does not provide an exhaustive evaluation of the deformation mechanism, it does serve to quantify the relative role played by the variations in the crustal and upper mantle components of the lithosphere. In this way we are able to use independent measurement of lithospheric geoid anomalies, current (post-orogenic) elevation and lithospheric structure, and paleoelevation information to estimate topographic development and structural support over time. Application of this technique to the southwestern United States indicates that the uplift of the Colorado Plateau is the result of processes in both the crust and mantle lithosphere and that the lithosphere of the pre-orogenic Southern Basin and Range was thinned relative to the Northern Basin and Range and Colorado Plateau. Although we use the southwestern U.S. as an example, this method can help constrain uplift mechanisms for any region for which the structure and geoid anomaly of the modern lithosphere is well understood.     

Spatial and temporal dynamics of epiphytic microalgae on the cordgrassSpartina alterniflora in North Inlet Estuary, South Carolina

Epiphytic microbial biomass (as chlorophylla) was measured monthly in North Inlet Estuary, South Carolina, for 16 months on spatially distinct stem sections (bottom and middle) of dead and livingSpartina alterniflora growth forms (tall, medium, and short) exposed at low tide. The highest biomass was located on the bottom section of tall plants, presumably due to their relatively longer contact with creek water and associated phytoplankton, and their closer proximity to marsh sediments with associated benthic microalgae, both recruitment sources for epiphytes. Dead plants left standing from the previous year’s growth cycle had higher epiphytic biomass than living plants, which occurred mostly in late spring through fall. Epiphytic biomass was highest in the winter (mean of 1.77 mg chla (m² marsh)⁻¹) and lowest in the summer (mean of 0.34 mg chla (m² marsh)⁻¹). Because phytoplankton andSpartina production are lowest in the winter, the results emphasize the relative importance of epiphytes to growth of herbivores in this season.     

A New Multi-Mineral Age Reference Material for 40Ar/39Ar, (U-Th)/He and Fission Track Dating Methods: The Limberg t3 Tuff

The phonolitic Limberg t3 tephra (Kaiserstuhl Volcanic Complex, Germany) was previously dated by the conventional K/Ar method yielding inconsistent results. We have re-dated this tephra layer with three independent methods. Fission Track (FT) external detector analyses on single apatite crystals (16.8 ± 1.3 Ma, 2s) and (U-Th)/He measurements on titanite and apatite (16.5 ± 1.0 Ma, 2s and 16.8 ± 1.0 Ma, 2s, respectively) are in close agreement with laser Ar/Ar dates on incrementally heated single crystals of sanidine (16.3 ± 0.4 Ma, 2s). Due to very rapid cooling, the He, FT and Ar thermochronometers provide one single age representing the eruption event. The different minerals are characterised by favourable properties with respect to their chemical composition, grain size and shape. In particular for the t3 sanidine, homogeneity has been demonstrated by electron microprobe analysis and on a grain-to-grain and grain-internal scale by single crystal incremental laser heating. Based on the agreement between independent methods and the mineral yield of this unit, the Limberg t3 tephra is proposed as multi-method age reference material for single grain laser Ar/Ar, FT and (U-Th)/He dating.     

Characterization and quantification of inorganic constituents of tropical peats and organic-rich deposits from Tasek Bera (Peninsular Malaysia): implications for coals

Since the Carboniferous, tropical latitudes have been the site of formation of many economic coal deposits, most of which have a restricted range of mineralogical composition as a result of their depositional environment, climatic conditions, and diagenesis. Mineralogical and microscopic investigations of tropical peats from Tasek Bera, Peninsular Malaysia, were performed in order to better understand some of these factors controlling the nature, distribution and association of inorganic matter in peat-forming environments. Distribution and nature of the inorganic fraction of peat deposits give insight into the weathering conditions and detrital input into the mire system. Because the inorganic composition of peat deposits is determined by plant communities, height of water table, and climate, the results of the quantitative and qualitative analysis can be used to reconstruct palaeoclimatic conditions.Tasek Bera is a peat-accumulating basin in humid tropical Malaysia with organic deposits of low- to high-ash yield and thus representative of many ancient peat-forming environments. Clay minerals dominate the mineralogical composition of the peat and organic-rich sediments, while quartz and clays dominate the underlying siliciclastic deposits. Kaolinite is the most abundant clay mineral in the organic deposits with minor amounts of illite and vermiculite. Particle size analyses indicate that >50% of the inorganic detrital fraction is <2 μm. Most detrital quartz grains range in size from fine silt to fine sand. The fine sand fraction accounts for a maximum of 5 wt.% of the inorganic constituents. In addition, abundant biogenic and non-biogenic, Al- and Si-rich amorphous matter occur. In the ombrotrophic (low-nutrient) environment, biogenic inorganic material contributes up to >75% of the ash constituents. As a consequence, the vegetational communities make an important contribution to the inorganic and overall ash composition of peats and coals. The ash content of the often inundated peat consists on average of 10% opaline silica from diatoms and sponge spicules, while the ash of the top deposits may have up to 50% biogenic silica. Hence, Al- and Si-hydroxides and the opaline silica from diatoms and sponges represent a large repository of Al and Si, which may form the basis of mineral transformation, neoformation and alteration processes during coalification of the peat deposits. As a result, most coal deposits from paleotropical environments are anticipated to have little to no biogenic inorganic material but high amounts of secondary clays, such as kaolinite (detrital kaolinite, resilisified kaolinite, or desilisified gibbsite) or illite, and various amounts of detrital and authigenetic quartz.     

Redox and nonredox reactions of magnetite and hematite in rocks

Redox and nonredox reactions causing pseudomorphic replacement of hematite by magnetite and magnetite by hematite are compared.Pseudomorphic replacements resulting from redox reactions are known as martitization [replacement of magnetite by hematite due to oxidation; reaction (1)] and mushketovitization [replacement of hematite by magnetite due to reduction; reaction (2)]. These two replacements cause characteristic ore textures and volume changes (reaction (1): increase of 1.66%; reaction (2): decrease of 1.64%). These small volume changes are the reason that martitization and mushketovitization are widespread in many rocks under condition, however, that oxidizing or reducing fluids (solutions) are present.The same initial and end products may also be involved in nonredox reactions. Reaction (3) is the replacement of hematite by magnetite due to simple addition of Fe²⁺ atoms under basic conditions. This reaction causes an increase of the volume of 47.6%. Reaction (4), causing a volume decrease of 32.2%, is the replacement of magnetite by hematite due to leaching of Fe²⁺ atoms under acidic conditions. From these volume changes it is concluded that reaction (4) may occur in many rock types, whereas reaction (3) is restricted to unlithified sediments only. However, ore textures caused by nonredox reactions are unknown and therefore their occurrence in rocks is hypothetical.