Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Metal and metalloid leaching from tailings into streamwater and sediments in the old Ag–Pb–Zn Terramonte mine,northern Portugal

Tailings deposited over the Castanheira, a stream which flows through the old Ag–Pb–Zn Terramonte mine area, showed a great potential environmental risk due to sulphide weathering, facilitated by the tailings–water interaction. The high concentrations of Al, Fe, Pb and Zn in the tailings are associated with the exchangeable, reducible and sulphide fractions and suggest sphalerite and pyrite occurrences. Oxidation of pyrite is responsible for the low pH values (3.38–4.89) of the tailings. The water from the Castanheira stream is not suitable for human consumption due to high concentrations of SO₄ ^2?, Mn, Al, Cd, Ni, and Pb. The lowest concentrations of metals and metalloids were detected in downstream stretches of the Castanheira. However, As, Fe and Zn in deeper sediments tend to increase downstream. Significant concentrations of trivalent forms of arsenic were detected in water samples. In downstream stretches of the Castanheira, some free ions (Fe²⁺, Mn²⁺ and Zn²⁺) also predominate and the water is saturated with ferrihydrite, goethite, hematite, lepidocrosite and magnetite.     

Study on Flow Field Around Vertical Breakwater Under Different Overtopping Conditions Based on Numerical Simulation

A numerical wave flume is constructed based on the Reynolds Averaged Navier-Stokes (RANS) equations with turbulence closure by a modified k-ε model to study the viscous interactions of waves with vertical breakwaters for different overtopping cases. The governing equations,the turbulence model,boundary conditions,and solution method for the numerical wave flume are introduced briefly. The reliability of the numerical wave flume is examined by comparing the numerical results with the experimental measurement...     

Long‐term final void salinity prediction for a post‐mining landscape in the Hunter Valley,New South Wales,Australia

Opencast mining alters surface and subsurface hydrology of a landscape both during and post‐mining. At mine closure, following opencast mining in mines with low overburden to coal ratios, a void is left in the final landform. This final void is the location of the active mine pit at closure. Voids are generally not infilled within the mines' lifetime, because of the prohibitive cost of earthwork operations, and they become post‐mining water bodies or pit lakes. Water quality is a significant issue for pit lakes. Groundwater within coal seams and associated rocks can be saline, depending on the nature of the strata and groundwater circulation patterns. This groundwater may be preferentially drawn to and collected in the final void. Surface runoff to the void will not only collect salts from rainfall and atmospheric fallout, but also from the ground surface and the weathering of fresh rock. As the void water level rises, its evaporative surface area increases, concentrating salts that are held in solution. This paper presents a study of the long term, water quality trends in a post‐mining final void in the Hunter Valley, New South Wales, Australia. This process is complex and occurs long term, and modelling offers the only method of evaluating water quality. Using available geochemical, climate and hydrogeological data as inputs into a mass‐balance model, water quality in the final void was found to increase rapidly in salinity through time (2452 to 8909 mg l⁻¹ over 500 years) as evaporation concentrates the salt in the void and regional groundwater containing high loads of salt continues to flow into the void. Copyright © 2004 John Wiley & Sons, Ltd.     

Pitfalls in Nonlinear Inversion

— We discuss and illustrate graphically with simple 2-D problems, four common pitfalls in geophysical nonlinear inversion. The first one establishes that the Lagrange multiplier, used to incorporate a priori information in the geophysical inverse problem, should be the largest value still compatible with a reasonable data fitting. This procedure should be used only when the interpreter is sure about the importance of the a priori information used to stabilize the inverse problem relative to the geophysical observations. Because this is rarely the case, the user should use the smallest Lagrange multiplier still producing stable solutions. The second pitfall is an attempt to automatically estimate the Lagrange multiplier by decreasing it along the iterative process used to solve the nonlinear optimization problem. Consequently, at the last iteration, the Lagrange multiplier may be so small that the problem may become ill-posed and any computed solution in this case is meaningless. The third pitfall is related to the incorporation of a priori information by a technique known as “Jumping.” This formulation, from the viewpoint of the class of Acceptable Gradient Methods, is incomplete and may lead to a premature halt in the iteration, and, consequently, to solutions far from the true one. Finally, the fourth pitfall is an inadequate convergence criterion which stops the iteration when the data misfit drops just below the noise level, irrespective of the fact that the functional to be minimized may not have attained its minimum. This means that the a priori information has not been completely incorporated, so that this stopping criterion partially neutralizes the effect of the stabilizing functional, and opens the possibility of obtaining unstable, meaningless estimates.     

Seismogenic destruction of the Kamenka medieval fortress, northern Issyk-Kul region, Tien Shan (Kyrgyzstan)

A paleoseismological study of the medieval Kamenka fortress in the northern part of the Issyk-Kul Lake depression, northern Tien Shan in Kyrgyzstan, revealed an oblique slip thrust fault scarp offsetting the fortification walls. This 700 m long scarp is not related to the 1911 Kebin Earthquake (Ms 8.2) fault scarps which are widespread in the region. As analysis of stratigraphy in a paleoseismic trench and archaeological evidence reveal, it can be assigned to a major twelfth century a.d. earthquake which produced up to 4 m of oblique slip thrusting antithetic to that of the nearby dominant faults. The inferred surface rupturing earthquake apparently caused the fortress destruction and was likely the primary reason for its abandonment, not the Mongolian–Tatar invasions as previously thought.     

The convective boundary layer over pasture and forest in Amazonia

Summary The coupling between different types of surface (tropical forest or grass) and the Convective Boundary Layer (CBL) has been investigated using observational (rawinsoundings) data collected over Rondônia in southwest Amazonia. The data reported here support the notion that deforestation may modify the dynamics of the boundary layer, in particular during the dry season. In this period the sensible heat fluxes are very high over pasture, creating a CBL around 550m deeper compared to that over the forest. The measurements showed the height of the fully developed CBL for pasture to be 1650m, compared to around 1100m for forest. During the wet season the height of the CBL is lower than during the dry season and has the same height (around 1000m) for forest and pasture sites. The CBL over pasture is hotter and drier than over forest during the dry season, but during the wet season the air temperatures and humidities are similar. Comparing the CBL growth during the dry and wet season, there is evidence that the CBL properties over the forest are not dependent on the surface characteristics, but over the pasture they are.     

Studies of Plasma Dynamics in a Small Plasma Focus Operating in Hydrogen-Argon Mixtures

We report on experimental observations in PFP-I, a small 3.8 kJ plasma focus, which is operated in Hydrogen-Argon mixtures to investigate the effect of parameter modifications on the overall performance of the device. An extensive array of diagnostics is been used, which includes voltage and current probes in the external circuit, a novel small magnetic probes array located along the cathode rods, filtered PIN diodes located side and end on, and filtered multi-pinhole and slit-wire X-ray camera. Extended operating range from below 0.2 Torr upwards has been achieved. Hot spot formation has been investigated as a function of H₂-Ar mixing ratio. Hot spot sizes around 150 m in the soft X-ray region, have been inferred from the slit-wire measurements. Pin-hole time integrated X-ray pictures and time resolved PIN diode measurements have been used to determine characteristic hot-spot temperatures in the 350 to 450 eV range.     

Sediment yield and storage variations in the Négron River catchment (south western Parisian Basin,France) during the Holocene period

In the Négron River catchment area (162 km²), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 10⁶ t) and loess (21 × 10⁶ t), and Holocene alluvium (12·6 × 10⁶ t), peat (0·6 × 10⁶ t) and colluvium (18·5 × 10⁶ t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km^?2 a^?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km^?2 a^?1 from alluvium stores and 7·6 t km^?2 a^?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km^?2 a^?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km^?2 a^?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd.     

Development,urban planning and political decisions. A triad that built territories at risk

Natural Hazards - Chilean geography exposes the country to high-level risks such as earthquakes and tsunamis. The disasters of 1930, 1960, 2010, and 2014 testify to the continuous link between...