Quantifying groundwater discharge to a small perennial stream in southern Ontario, Canada

A study of the interaction between groundwater and surface water was undertaken within a small agricultural watershed in southern Ontario, Canada. Groundwater contributions to streamflow were measured along a section of stream during baseflow conditions and during rainfall events. Four techniques were used to estimate the contribution of groundwater to the stream along a 450 m reach (three during baseflow and one during stormflow conditions). Under baseflow conditions, streamflow measurements using the velocity–area technique indicated that the net groundwater flux to the stream during the summer months was 10 ml s⁻¹ m⁻¹. Hydrometric measurements (i.e. hydraulic gradient and hydraulic conductivity) taken using mini-piezometers installed in the sediments beneath the stream resulted in net groundwater flux estimates that were four to five times lower. Seepage meters failed to provide any measurements of water flux into or out of the stream. Therefore, based on these results, the velocity–area technique gives the best estimate of groundwater discharge. Hydrograph separations were conducted using isotopic ratios and electrical conductivity on two large rainfall events with different antecedent moisture conditions in the catchment. Both events showed that pre-event water (generally considered groundwater) dominated streamflow and tile drain flow with 64%–80% of the total discharge contributed by pre-event water. High water table conditions within the catchment resulted in greater stream discharge and a greater contribution of event water in the streamflow than that observed under low water table conditions for similar intensity storm events. The results also showed that differences in riparian zone width, vegetation and surface saturation conditions between the upper and lower catchment can influence the relative magnitude of streamflow response from the two catchment areas.     

Local disappearance of bivalves in the Azores during the last glaciation

The Pleistocene (Eemian) outcrops of Lagoinhas and Prainha, located at Santa Maria Island (Azores), were investigated and their fossil mollusc content reported. These studies revealed that the last glaciation affected two groups of molluscs: the ‘warm‐guest’ gastropods with West African or Caribbean affinities (e.g. Conus spp., Cantharus variegatus, Bulla amygdala, Trachypollia nodulosa) and shallow bivalve species mainly associated with sandy habitats (Ensis minor, Lucinella divaricata, and probably Laevicardium crassum). In this paper we focus on this group of bivalves, which has since locally disappeared from the Azores. We relate the local disappearance of these bivalves in the Azores with the lack of sand in the shelf. The specific characteristics of the Santa Maria shelf combined with the sea‐level drop during the Weichselian prevented deposition of the lowstand deposits and permitted erosion of the previous ones, leaving the shelf without a sediment cover. Copyright © 2008 John Wiley & Sons, Ltd.     

Irregular Satellites of Jupiter: a study of the capture direction

The irregular satellites of Jupiter are believed to be captured asteroids or planetesimals. In the present work is studied the direction of capture of these objects as a function of their orbital inclination. We performed numerical simulations of the restricted three-body problem, Sun-Jupiter-particle, taking into account the growth of Jupiter. The integration was made backward in time. Initially, the particles have orbits as satellites of Jupiter, which has its present mass. Then, the system evolved with Jupiter losing mass and the satellites escaping from the planet. The reverse of the escape direction corresponds to the capture direction. The results show that the Lagrangian points L1 and L2 mainly guide the direction of capture. Prograde satellites are captured through these two gates with very narrow amplitude angles. In the case of retrograde satellites, these two gates are wider. The capture region increases as the orbital inclination increases. In the case of planar retrograde satellites the directions of capture cover the whole 360° around Jupiter. We also verified that prograde satellites are captured earlier in actual time than retrograde ones. This paper was presented at the Asteriods, Comets and Meteors meeting held at Búzios, Rio de Janeiro, Brazil in August 2005 and could not be included in the special issue related to that conference.     

Pliocene extensional tectonics in the Eastern Central Patagonian Cordillera: geochronological constraints and new field evidence

Recent field work and review of radiometric data obtained from Neogene lavas and plutonic rocks exposed in the Eastern Central Patagonian Cordillera (46–48ºS), which overlie subducted segments of the South Chile Ridge, suggest important Late Miocene to Pleistocene morphological changes in relation to base level variations and/or tectonic events. We present new field observations from a region south of Lago General Carrera‐Buenos Aires, between the main Cordillera and the Meseta del Lago Buenos Aires, demonstrating that normal faulting controlled valley incisions and occurred during lava emplacement at 5–4 Ma and after 3 Ma. We also show that the 12 Ma basaltic flows of the Meseta del Lago Buenos Aires (∼2000 m a.s.l.) have been subjected to deep incision, with younger lavas dated at 1.2 Ma partially filling the valleys. These incisions are thought to reflect progressive eastward tilting of the entire meseta. Our new observations, together with additional features from Central Patagonia, strongly suggest that tectonic events led to a regional widespread morphological change after 5 Ma. The coincidence in time and space between the subduction of segments of the South Chile Ridge at 6 and 3 Ma causing opening of a slab window, and strong base level variations in the studied area, suggests a cause‐and‐effect relationship. In Central Patagonia, compressional tectonics ended well before extensional events reported here. Causes of uplift and further extension are probably completely disconnected. The uplift is purely tectonic in origin and occurred prior to the subduction of the South Chile Ridge. Extension should be a consequence of this subduction.     

Stability analysis of the martian obliquity during the Noachian era

We performed numerical simulations of the obliquity evolution of Mars during the Noachian era, at which time the giant planets were on drastically different orbits than today. For the preferred primordial configuration of the planets we find that there are two large zones where the martian obliquity is stable and oscillates with an amplitude lower than 20°. These zones occur at obliquities below 30° and above 60°; intermediate values show either resonant or chaotic behaviour depending on the primordial orbits of the terrestrial planets.     

Stable sulfur isotopes in the water column of the Cariaco Basin

Previous geochemical and microbiological studies in the Cariaco Basin indicate intense elemental cycling and a dynamic microbial loop near the oxic-anoxic interface. We obtained detailed distributions of sulfur isotopes of total dissolved sulfide and sulfate as part of the on-going CARIACO time series project to explore the critical pathways at the level of individual sulfur species. Isotopic patterns of sulfate (δ³⁴S_SO4) and sulfide (δ³⁴S_H2S) were similar to trends observed in the Black Sea water column: δ³⁴S_H2S and δ³⁴S_SO4 were constant in the deep anoxic water (varying within 0.6‰ for sulfide and 0.3‰ for sulfate), with sulfide roughly 54‰ depleted in ³⁴S relative to sulfate. Near the oxic-anoxic interface, however, the δ³⁴S_H2S value was ∼3‰ heavier than that in the deep water, which may reflect sulfide oxidation and/or a change in fractionation during in situ sulfide production through sulfate reduction (SR). δ³⁴S_H2S and Δ³³S_H2S data near the oxic-anoxic interface did not provide unequivocal evidence to support the important role of sulfur-intermediate disproportionation suggested by previous studies. Repeated observation of minimum δ³⁴S_SO4 values near the interface suggests ‘readdition’ of ³⁴S-depleted sulfate during sulfide oxidation. A slight increase in δ³⁴S_SO4 values with depth extended over the water column may indicate a reservoir effect associated with removal of ³⁴S-depleted sulfur during sulfide production through SR. Our δ³⁴S_H2S and Δ³³S_H2S data also do not show a clear role for sulfur-intermediate disproportionation in the deep anoxic water column. We interpret the large difference in δ³⁴S between sulfate and sulfide as reflecting fractionations during SR in the Cariaco deep waters that are larger than those generally observed in culturing studies.     

Geotechnical Characterization by In situ and Lab Tests to the Back-Analysis of a Supported Excavation in Metro do Porto

This paper summarizes the geotechnical characterization conducted for the design and subsequent analysis of a strutted excavation in “Metro do Porto”. This region is geologically dominated by heterogeneous weathered granite masses with deep residual soil profiles. Local saprolitic soils exhibit, by their nature, a particular behavior characterized by very sensitive and weak relic micro-structures, due to their specific genesis. This study has included the interpretation of a significant volume of in situ test results, triaxial tests over undisturbed samples and monitoring data, giving rise to specific correlations between testing and design parameters. Real time monitoring enabled a back-analysis by FEM of a well instrumented section of the strutted excavation, which was calibrated taking into account the derived correlations and the deformability behavior of this specific geotechnical ambient. This geomaterial, although revealing very high initial stiffness values (for very small strain ranges) has shown low stiffness values for “medium to high” strain levels, reflecting a singular strong non-linearity in the stress-strain behavior.     

A Middle Miocene carbonate embankment on an active volcanic slope: Ilhéu de Baixo,Madeira Archipelago,Eastern Atlantic

Carbonate factories on insular oceanic islands in active volcanic settings are poorly explored. This case study illuminates marginal limestone deposits on a steep volcanic flank and their recurring interruption by deposits linked to volcaniclastic processes. Historically known as Ilhéu da Cal (Lime Island), Ilhéu de Baixo was separated from Porto Santo, in the Madeira Archipelago, during the course of the Quaternary. Here, extensive mines were tunnelled in the Miocene carbonate strata for the production of slaked lime. Approximately 10 000 m³ of calcarenite (−1 to 1ø) was removed by hand labour from the Blandy Brothers mine at the south end of the islet. Investigations of two stratigraphic sections at opposite ends of the mine reveal that the quarried material represents an incipient carbonate ramp developed from east to west and embanked against the flank of a volcanic island. A petrographic analysis of limestones from the mine shows that coralline red algae from crushed rhodoliths account for 51% of all identifiable bioclasts. This material was transported shoreward and deposited on the ramp between normal wave base and storm wave base at moderate depths. The mine's roof rocks are formed by Surtseyan deposits from a subsequent volcanic eruption. Volcaniclastic density flows also are a prevalent factor interrupting renewed carbonate deposition. These flows arrived downslope from the north and gradually steepened the debris apron westwards. Slope instability is further shown by a coral rudstone density flow that followed from growth of a coral reef dominated by Pocillopora madreporacea (Lamarck), partial reef collapse, and transport from a more easterly direction into a fore‐reef setting. The uppermost facies represents a soft bottom at moderate depths in a quiet, but shore‐proximal setting. Application of this study to a broader understanding of the relationship between carbonate and volcaniclastic deposition on oceanic islands emphasizes the susceptibility of carbonates to dilution and complete removal by density flows of various kinds, in contrast to the potential for preservation beneath less‐disruptive Surtseyan deposits. Copyright © 2013 John Wiley & Sons, Ltd.     

Assessment of troposphere mapping functions using three-dimensional ray-tracing

The troposphere delay is an important source of error for precise GNSS positioning due to its high correlation with the station height parameter. It has been demonstrated that errors in mapping functions can cause sub-annual biases as well as affect the repeatability of GNSS solutions, which is a particular concern for geophysical studies. Three-dimensional ray-tracing through numerical weather models (NWM) is an excellent approach for capturing the directional and daily variation of the tropospheric delay. Due to computational complexity, its use for positioning purposes is limited, but it is an excellent tool for evaluating current state-of-the-art mapping functions used for geodetic positioning. Many mapping functions have been recommended in the past such as the Niell Mapping Function (NMF), Vienna Mapping Function 1 (VMF1), and the Global Mapping Function (GMF), which have been adopted by most IGS analysis centers. A new Global Pressure Temperature model (GPT2) has also been developed, which has been shown to improve upon the original atmospheric model used for the GMF. Although the mapping functions mentioned above use the same functional formulation, they vary in terms of their atmospheric source and calibration approach. A homogeneous data set of three-dimensional ray-traced delays is used to evaluate all components of the mapping functions, including their underlying functional formulation, calibration, and compression method. Additionally, an alternative representation of the VMF1 is generated using the same atmospheric source as the truth data set to evaluate the differences in ray-tracing methods and their effect on the end mapping function. The results of this investigation continue to support the use of the VMF1 as the mapping function of choice when geodetic parameters are of interest. Further support for the GPT2 and GMF as reliable back-ups when the VMF1 is not available was found due to their high consistency with the NWM-derived mapping function. Additionally, a small latitude-dependent bias in station height was found in the current mapping functions. This bias was identified to be due to the assumption of a constant radius of the earth and was largest at the poles and at the equator. Finally, an alternative version of the VMF1 is introduced, namely the UNB-VMF1 which provides users with an independent NWM-derived mapping function to support geodetic positioning.     

A contribution to regional stratigraphic correlations of the Afro-Brazilian depression – The Dom João Stage (Brotas Group and equivalent units – Late Jurassic) in Northeastern Brazilian sedimentary basins

The Dom João Stage comprises an interval with variable thickness between 100 and 1200 m, composed of fluvial, eolian and lacustrine deposits of Late Jurassic age, based mainly on the lacustrine ostracod fauna (although the top deposits may extend into the Early Cretaceous). These deposits comprise the so-called Afro-Brazilian Depression, initially characterized as containing the Brotas Group of the Recôncavo Basin (which includes the Aliança and the Sergi Formations) and subsequently extended into the Tucano, Jatobá, Camamu, Almada, Sergipe, Alagoas and Araripe Basins in northeastern Brazil, encompassing the study area of this paper. The large occurrence area of the Dom João Stage gives rise to discussions about the depositional connectivity between the basins, and the real extension of sedimentation. In the first studies of this stratigraphic interval, the Dom João Stage was strictly associated with the rift phase, as an initial stage (decades of 1960–70), but subsequent analyses considered the Dom João as an intracratonic basin or pre-rift phase – without any relation to the active mechanics of a tectonic syn-rift phase (decades of 1980–2000). The present work developed an evolutionary stratigraphic and tectonic model, based on the characterization of depositional sequences, internal flooding surfaces, depositional systems arrangement and paleoflow directions. Several outcrops on the onshore basins were used to build composite sections of each basin, comprising facies, architectural elements, depositional systems, stratigraphic and lithostratigraphic frameworks, and paleocurrents. In addition to that, over a hundred onshore and offshore exploration wells were used (only 21 of which are showed) to map the depositional sequences and generate correlation sections. These show the characteristics and relations of the Dom João Stage in each studied basin, and they were also extended to the Gabon Basin. The results indicate that there were two main phases during the Dom João Stage, in which distinctive sedimentary environments were developed, reflecting depositional system arrangements, paleoflow directions were diverse, and continuous or compartmented basins were developed.