Characteristics of aerosol optical depth and Ångström parameters over Mohal in the Kullu Valley of Northwest Himalayan Region,India

The measurements using a ground based multi wavelength radiometer (MWR) at Mohal (31°54′N, 77°07′E, 1154 m AMSL) in the Kullu valley of Northwestern Himalayan region show that the spectral aerosol optical depth (AOD) and turbidity coefficient, β, are high in summer, moderate in monsoon season, low in winter and lowest in autumn, while wavelength exponent, α, has an opposite trend. Average annual value of AOD at 500 nm is 0.24±0.01, 0.43±0.02, and 0.28±0.02; that of β is 0.14±0.01, 0.22±0.02, and 0.17±0.03; and that of α is 1.06±0.09, 1.16±0.10, and 0.86±0.13, respectively, for clear, hazy and partially clear sky days. The considerably greater value of β on hazy days indicates more coarse particles in mountain haze. The fractional asymmetry factor (AF) is more negative in summer and autumn months. The AOD and β have significantly positive correlation with temperature and wind speed, suggesting high AODs and turbidity on hot and windy days.     

Holocene climate variability from lake sediment core in Larsemann Hills,Antarctica

A sediment core (L2) from Larsemann Hills, Antarctica was analyzed for Biogenic Silica (BSi), Sand (%) and Total Organic Carbon (TOC). The 78 cm core length represents the time span of ∼8.3 cal ka BP. The values of BSi from the core show prominent high productivity from ∼8.3 to ∼6 cal ka BP in comparison to less productivity in mid-late Holocene (∼6 cal ka BP to recent). Moreover, high sand (%) infers the glacio-fluvial deposition from ∼8.3 to ∼5 cal ka BP TOC shows little variation through out the core, except in the upper ∼10 cm (∼4 cal ka BP) part wherein it is comparatively high. The increased TOC in the upper part of the core possibly indicates presence of algal mat due to exposure of the lake to the ice free (glacier free) conditions.     

Groundwater resources management through flow modeling in lower part of Bhagirathi — Jalangi interfluve,Nadia, West Bengal

Groundwater utilization in Nadia district, West Bengal has been subjected to rapid exploitation in the wake of increasing urbanization and production of agricultural commodities. It is, therefore, necessary to evaluate the existing trend and availability of groundwater in time and space and its movement for proper planning in future. In the present study, an attempt has been made develop a groundwater management model using Visual MODFLOW software. The groundwater flow model for the study area was formulated by using input hydrogeological data and appropriate boundary conditions. The groundwater flow pattern of the study area indicates the occurrence of base flow which feed both the Rivers Bhagirathi and Jalangi throughout the year. The computed hydraulic heads were calibrated by comparing with observed groundwater level data for years 2004 to 2006 and were verified with the data of 2007. The outcome of modeling shows that this model can be used for prediction purpose in the future by updating input boundary conditions and hydrologic stresses during the preceding year. The model optimized unit draft for deep tube well as 556.5 m³/day and the same for shallow tube well as 41 m³/day keeping the existing tube well structures in running condition and maintaining the present and recent past trends of groundwater level. The model can be further improved if more spatial and temporal input parameters are available and can be incorporated into the model for more realistic characterization of groundwater flow.     

Chemical weathering of the Indo-Gangetic alluvium with special reference to release of fluoride in the groundwater,Unnao district,Uttar Pradesh

In the central part of Indo-Gangetic alluvium in the Unnao district, Uttar Pradesh there are many pockets where groundwater shows high fluoride content. Drinking of fluorinated ground water has effected a large population and in many villages more than 80% of the population is suffering from fluorosis. The source of this fluoride appears to be the alluvial sediments deposited in the geological past as no hard rock terrain is present in the nearby areas. The area is dominantly made up of mud with pockets of sand. The sand fraction is made up of quartz, plagioclase, microcline, muscovite and biotite along with some accessory minerals like garnet, epidote, chlorite, tourmaline, hornblende, kyanite and a few opaque minerals. Moreover, the fluoride content in the groundwater varies both spatially and with depth indicating a sporadic occurrence. The surface water is devoid of high content of fluoride but is reported in hand pumps and in the dug wells. This paper deals with the geochemical study of the sediments up to a depth of 45m as most of the hand pumps are up to this depth to understand the source of fluoride. ¹⁴C dates of calcretes have suggested that the 45 m thick succession must have been formed in about 45000 years.     

Numerical Modeling and Spatial Moment Analysis of Thermal Fronts in a Coupled Fracture-Skin-Matrix System

In this study, the behavior of thermal fronts along the fracture is studied in the presence of fracture-skin in a coupled fracture-matrix system. Cold water is injected into the fracture, which advances gradually towards production well, while extracting heat from the surrounding reservoir matrix. The heat conduction into the fracture-skin and the rock-matrix from the high permeability fracture is assumed to be one dimensional perpendicular to the axis of fluid flow along the fracture. Constant temperature cold water is injected through an injection well at the fracture inlet. The fluid flow takes place along the horizontal fracture which ensures connectivity between the injection and production wells. Since the rock-matrix is assumed to be tight, the permeability of fracture-skin as well as the rock-matrix is neglected. The present study focuses on the heat flux transfer at the fracture-skin interface as against the earlier studies on fracture-matrix interface, and the sensitivity of additional heterogeneity in the form of fracture skin in a conventional fracture-matrix coupled system is studied. The behavior of thermal fronts for various thermal conductivity values of the fracture-skin and rock-matrix is analyzed. Spatial moment analysis is performed on the thermal distribution profiles resulting from numerical studies in order to investigate the impact on mobility and dispersion behavior of the fluid in the presence of fracture-skin. The presence of fracture skin affects the heat transfer significantly in the coupled fracture-matrix system. The lower order spatial moments indicate that the effective thermal velocity increases with increase in skin thermal conductivity and a significant thermal dispersion is observed at the inlet of the fracture owing to the high thermal conductivity of the fracture-skin at the early stages. Furthermore the higher spatial moments indicate that the asymmetricity increases with decrease in skin thermal conductivity unlike the case with half fracture aperture and fluid velocity and the kurtosis is maximum with higher skin thermal conductivity which implies enhanced heat extraction from the fracture-skin into the fracture. Results suggest that the amount of heat extraction by the circulating fluid within the fracture from the reservoir not only depends on the rock-matrix module of the reservoir characteristics but also the fracture-skin characteristics of the system and subsequently influence the reservoir efficiency.     

Significance of biofilm proteins in modulating cyprid metamorphosis of Balanus amphitrite (Cirripedia: Thoracica)

The role of biofilm proteins in modulating cyprid metamorphosis is not well understood. In the present investigation this possibility was explored by disrupting biofilm proteins using commercially available protease. The influence of natural biofilm and artificial biofilms of Aeromonas salmonicida salmonicida and Bacillus brevis and their culture supernatants and exopolysaccharides obtained under different nutritional conditions was evaluated. Natural biofilm facilitated cyprid metamorphosis in Balanus amphitrite, whereas monospecies biofilms did not. The treatment of biofilms with protease resulted in a decline in metamorphosis, except in B. brevis, where although metamorphosis was negated initially, it increased with the protease concentration and observation days. As the response of cyprids to exopolysaccharides produced by A. salmonicida salmonicida was dependent on protein concentration, protease treatment resulted in a decrease in metamorphosis, whereas in case of B. brevis biofilms, protease hydrolysis products could be important in providing settlement cues. Thus, biofilm bacterial components play an important role in the cyprid metamorphosis of Balanus amphitrite.     

Assessment of future climate variability and potential adaptation strategies on yield of peanut and Kharif rice in eastern India

Theoretical and Applied Climatology - Temperature and CO2 are the two most important climate parameters that affect crop yield directly. In this study, the impact of these two parameters on the...     

Theoretical studies on OH and Cl initiated hydrogen atom abstraction of HFE-227pc (CF3OCF2CHF2)

The kinetics of hydrogen atom abstraction reactions of HFE-227pc by OH and Cl was studied by ab initio method. The structural optimization and frequency calculation of the titled compound and the species formed during the abstraction reactions were performed with density functional theory using hybrid meta density functional MPWB1K with 6–31?+?G(d,p) basis set. The energy of the species was further refined by making a single point energy calculation at G3B3 level of theory. The standard enthalpies of formation of reactant and the radical formed after H-atom abstraction was calculated using isodesmic method. The rate constants of abstraction reactions were calculated using Conventional Transition State Theory (CTST) and were found to be 1.5?×?10^?15 and 0.53?×?10^?16 cm³molecule^?1 s^?1 for OH and Cl respectively. The calculated value for the abstraction by OH is close to the experimental value of 2.26?×?10^?15 cm³molecule^?1 s^?1 whereas the same for Cl is found to be about five times lower than that of 2.70?×?10^?16 cm³molecule^?1 s^?1. The theoretical studies yielded the enthalpies of formation and the rate constants that are vital in determining the lifetime of HFE-227pc.     

Comparison between urban aerosol products retrieved from collocated Cimel and Prede Sun/sky radiometers at Pune, India

To comprehend the characteristics of heterogeneous aerosols, apart from some thematic multi-institutional, multi-platform and multi-parameter campaigns conducted at several places over the globe, presently two major ground-based networks, involving Cimel (AERONET) and Prede (SKYNET) Sun/sky photometers/radiometers have been in progress. In this paper, we report the results of a study that has been undertaken to compare the performance and data products of Cimel and Prede instruments, which were operated concurrently for a period of about 2 years, at the Indian Institute of Tropical Meteorology, Pune, India. The results show a good agreement in the direct Sun observations (aerosol optical depth). The results are also substantiated by making comparison with surface-level black carbon aerosol mass concentration, apart from comparison of other parameters. With regard to the retrieved products such as aerosol size distribution, Prede shows more or less equal concentration of fine mode and relatively more concentration of coarse mode aerosol as compared to those measured by the Cimel. Moreover, the single scattering albedo values measured by the Prede overestimate those observed by the Cimel. These deviations are found to be primarily due to the nature of aerosol loading (turbidity) in the sensing region which is sensitive to the data retrieval techniques including model assumptions employed in both networks. The results of the present study are found useful for multidimensional mapping of aerosol characteristics by integrating the products from both AERONET and SKYNET monitoring stations and thereby help understanding better the impact of aerosols on climate.     

CFSv2 ensemble prediction of the wintertime Arctic Oscillation

Lagged ensembles from the operational Climate Forecast System version 2 (CFSv2) seasonal hindcast dataset are used to assess skill in forecasting interannual variability of the December–February Arctic Oscillation (AO). We find that a small but statistically significant portion of the interannual variance (>20 %) of the wintertime AO can be predicted at leads up to 2 months using lagged ensemble averages. As far as we are aware, this is the first study to demonstrate that an operational model has discernible skill in predicting AO variability on seasonal timescales. We find that the CFS forecast skill is slightly higher when a weighted ensemble is used that rewards forecast runs with the most accurate representations of October Eurasian snow cover extent (SCE), hinting that a stratospheric pathway linking October Eurasian SCE with the AO may be responsible for the model skill. However, further analysis reveals that the CFS is unable to capture many important aspects of this stratospheric mechanism. Model deficiencies identified include: (1) the CFS significantly underestimates the observed variance in October Eurasian SCE, (2) the CFS fails to translate surface pressure anomalies associated with SCE anomalies into vertically propagating waves, and (3) stratospheric AO patterns in the CFS fail to propagate downward through the tropopause to the surface. Thus, alternate boundary forcings are likely contributing to model skill. Improving model deficiencies identified in this study may lead to even more skillful predictions of wintertime AO variability in future versions of the CFS.