The effects of diagenesis on the reservoir characters in sandstones of the Late Cretaceous Pab Formation,Kirthar Fold Belt,southern Pakistan

The Maastrichtian Pab Formation in the southern part of Pakistan is composed of fine- to very coarse-grained texturally mature quartz arenite and subordinate sublitharenite varieties. The sandstones have undergone intense and complex diagenetic episodes due to burial and uplift. Diagenetic modifications were dependent mainly on the clastic composition of sandstone, burial depth and thrust tectonics. Diagenetic events identified include compaction, precipitation of calcite, quartz, clay minerals and iron oxide/hydroxide, dissolution and alteration of unstable clastic grains as feldspar and volcaniclithic fragments as well as tectonically induced grain fracturing. The unstable clastic grains like feldspar and lithic volcanic fragments suffered considerable alteration to kaolinite and chlorite. Dissolution and alteration of feldspar and volcanic lithic fragments and pressure solution were the main sources of quartz cements. Mechanical compaction and authigenic cements like calcite, quartz and iron oxide/hydroxide reduced the primary porosity, whereas dissolution of clastic grains and cements has produced secondary porosity. Chlorite coatings on clastic grains have prevented quartz cementation. Coarse-grained, thick bedded packages of fluviodeltaic, shelf delta lobe and submarine channels facies have higher average porosity than fine-grained, thin bedded and bioturbated sandstone of deeper shelf and abyssal plain environments and these facies are concluded to be possible future hydrocarbon prospects.     

Geochemistry of the mafic dykes in parts of the Singhbhum granitoid complex: petrogenesis and tectonic setting

Singhbhum granitoid complex has been intruded by numerous mafic dykes trending in different directions. The studied dykes were originated from subalkaline magma, ranging in composition from basalt through basaltic-andesite to andesite. In the present work, the studied dykes are divided into two groups on the bases of abundance of SiO₂, MgO, Al₂O₃, Ni, and Cr. The first one has higher Mg# than that of group II. These dykes have enriched incompatible trace element patterns. These are particularly enriched in the light rare earth elements and large ion lithophile elements with depleted high field strength elements (Nb, P, Ti). High Ba/Nb and Sr/P ratios of present mafic dykes are the indications of subduction signature. The geochemical characters of the back arc extension basalt tectonic setting is suggested for the studied dykes. Higher PM-normalized Th/Nb, Rb/Nb, and Ba/Nb ratios of studied samples support their non-plume source.     

THE USE OF GEOGRAPHIC INFORMATION SYSTEMS IN ANALYSIS OF URBAN AND RURAL LANDSCAPES

This paper reviews major concerns in the development of geographic information systems in Czechoslovakia (underlying theory, design and system requirements, data acquisition and classification, and mathematical-cartographic modeling), and describes the structure of two systems developed for the city of Brno and the surrounding semi-rural countryside. These systems are designed to permit the widest possible range of spatial information to be incorporated into their data bases, to allow maximum flexibility of response to changing user requirements, to produce a wide variety of graphic products, and to provide a capacity for automated forecasting and output of forecast maps. Presented at the Euro-Carto III Seminar sponsored by the International Cartographic Association at Graz, Austria, October 23-25, 1984 and submitted to the Editor-in-Chief for publication.     

Petrology of lower-middle Miocene Zoumi Flysch Fm. (Mesorif sub-domain,Rif belt,Morocco): first evidence of mixed mode provenance and geodynamic setting

The Zoumi Basin was generated in a collisional tectonic setting during the Lower-Middle Miocene. The syn-orogenic flysch deposits of the basin have been well investigated by petrographic and geochemical studies to characterize the composition, source to sink routing system, and tectonic setting of the Zoumi flysch. Forty-three sandstone samples and 45 mudstone samples have been gathered from six measured stratigraphic sections. These samples have been analyzed using XRD, XRF, inductively coupled plasma-mass spectrometry (ICP-MS) for mudrocks and petrographic investigation for sandstones. The Lower-Middle Miocene Zoumi flysch is defined as sublitharenites and quartzarenites according to mineralogical content. Detrital grains are commonly subangular to subrounded, poorly sorted, and rich in quartz grains. Point counting modal analysis leads to craton interior and recycled orogen provenance with significant first-cycle sediment supply and low sedimentary recycling. Several chemical ratios (Al₂O₃/TiO₂, La/Th, Cr/Th, Th/Sc, Zr/Sc) as well as chondrite-normalized REE patterns with flat HREE, LREE enrichment, and negative Eu anomaly suggest a dominant felsic rock sources. However, V-Ni-La*4, V-Ni-Th*10, and Th/Sc vs. Cr/Th plots do not exclude a mafic supply source nature which is evidenced by numerous ophiolitic outcrops scattered throughout the Mesorifan Subdomain (Mesorifan Ophiolitic Suture Zone).     

Revisiting problem of chilled margins associated with marginal reversals in mafic–ultramafic intrusive bodies

Numerous observations on mafic–ultramafic layered intrusions, sills and dykes show that chilled margins always develop as an integral part of their marginal reversals and possess the following features: (a) they are commonly much more evolved or primitive than bulk intrusion compositions, (b) evolved chilled margins are composed of the low temperature cotectic assemblages of relevant magmatic systems and (c) tend to be compositionally similar in intrusions formed from different parental magmas, (d) fine-grained chilled margins are notably absent in many intrusions, with contact rocks being represented by medium- to coarse-grained cumulates. The anomalous features of chilled margins can be partly attributed to contamination, intratelluric inhomogeneity of magma, changes in composition of intruding magma, loss of magma from the chamber, supercooling, etc. A major process still remains, however, illusive, but appears to be universally operating along the cooling margins of magmatic bodies in a liquid state, being gravity-independent and temperature gradient-driven. We recognize this not yet specified process as Soret fractionation and explain the above observations in the following way. Primary chilled margins do not commonly survive because of intensive remelting by heat flux from the interior of the chamber. The subsequently formed “secondary chilled margins” represent cumulates that crystallized from liquids produced by temperature gradient-driven Soret fractionation. At high temperature gradients the process tends to produce similar cotectic liquids crystallizing gabbronorite (or gabbro) from all parental magmas of a given magmatic system, resulting in compositionally similar “secondary chilled margins” that are more evolved than bulk compositions. At low temperature gradients the process produces liquids that are only slightly more fractionated than the parental magma and form “secondary chilled margins” that are more primitive than bulk compositions. This interpretation suggests that, apart from the rare cases of chilled margins that survived remelting, they should not be used as monitors for parental magma compositions of intrusive bodies, even if all conventional complicating factors were not operative.     

Solute movement through intact columns of cryoturbated Upper Chalk

Cryoturbated Upper Chalk is a dichotomous porous medium wherein the intra‐fragment porosity provides water storage and the inter‐fragment porosity provides potential pathways for relatively rapid flow near saturation. Chloride tracer movement through 43 cm long and 45 cm diameter undisturbed chalk columns was studied at water application rates of 0·3, 1·0, and 1·5 cm h^?1. Microscale heterogeneity in effluent was recorded using a grid collection system consisting of 98 funnel‐shaped cells each 3·5 cm in diameter. The total porosity of the columns was 0·47 ± 0·02 m³ m^?3, approximately 13% of pores were ≥ 15 µm diameter, and the saturated hydraulic conductivity was 12·66 ± 1·31 m day^?1. Although the column remained unsaturated during the leaching even at all application rates, proportionate flow through macropores increased as the application rate decreased. The number of dry cells (with 0 ml of effluent) increased as application rate decreased. Half of the leachate was collected from 15, 19 and 22 cells at 0·3, 1·0, 1·5 cm h^?1 application rates respectively. Similar breakthrough curves (BTCs) were obtained at all three application rates when plotted as a function of cumulative drainage, but they were distinctly different when plotted as a function of time. The BTCs indicate that the columns have similar drainage requirement irrespective of application rates, as the rise to the maxima (C/C_o) is almost similar. However, the time required to achieve that leaching requirement varies with application rates, and residence time was less in the case of a higher application rate. A two‐region convection–dispersion model was used to describe the BTCs and fitted well (r² = 0·97–0·99). There was a linear relationship between dispersion coefficient and pore water velocity (correlation coefficient r = 0·95). The results demonstrate the microscale heterogeneity of hydrodynamic properties in the Upper Chalk. Copyright © 2007 John Wiley & Sons, Ltd.     

Review: Assessment and modeling of seawater intrusion in coastal aquifers of the Arabian Peninsula

Hydrogeology Journal - Significant urbanization and industrialization, combined with strong population growth, have been witnessed in the Arabian Peninsula (Oman, United Arab Emirates, Saudi...     

KP Burgers shocks in a warm electronegative plasma with q-nonextensive distributed electrons

Nonlinear properties of ion-acoustic (IA) shock are studied by incorporating the effects of electron nonextensivity in a warm electronegative plasma, whose constituents are the inertial positive/negative ions and q-distributed electrons. For this purpose, the evolution equations are solved to obtain Kadomtsev-Petviashvili (KP) Burgers equation by using the reductive perturbation technique and its solution by the tanh method. Furthermore, the conditions for the existence of oscillatory and monotonic shocks are discussed. Numerically, it is found that IA shock propagation characteristics are significantly modified by the variation of plasma parameters, such as, the effects of electron nonextensivity, the positive and negative ion-to-electron temperature ratios (θ _i ,θ _n ), respectively. The former also affect the dispersion, dissipation and nonlinearity coefficients of the KPB equation involving the IA shocks. The present analyses could be useful for understanding the nonlinear shock wave excitations in space and laboratory plasmas, where two distinct groups of ions are present.     

Large amplitude acoustic solitons in a warm electronegative dusty plasma with q-nonextensive distributed electrons

Linear and nonlinear analysis are presented for an electronegative dusty plasma system. Linear analysis shows that the dispersive nature of the plasma system changes considerably due to the presence of nonthermal q-nonextensive distributed electrons. The presence of both compressive and rarefactive Sagdeev solitons is investigated and shown that the addition of even a small population of dust particles will significantly modify the large amplitude Sagdeev solitons. The coexistence of both compressive and rarefactive solitons for a certain set of parameters is also noticed in such system. The effect of variation of entropic index q, θ _i (ratio of positive ion temperature to electron temperature), θ _n (ratio of negative ion temperature to electron temperature) and dust particles concentration (R) is elaborated with the help of suitable parameters.