Arctic ocean shelf–basin interaction: An active continental shelf CO2 pump and its impact on the degree of calcium carbonate solubility

The Arctic Ocean has wide shelf areas with extensive biological activity including a high primary productivity and an active microbial loop within the surface sediment. This in combination with brine production during sea ice formation result in the decay products exiting from the shelf into the deep basin typically at a depth of about 150 m and over a wide salinity range centered around S ～33. We present data from the Beringia cruise in 2005 along a section in the Canada Basin from the continental margin north of Alaska towards the north and from the International Siberian Shelf Study in 2008 (ISSS-08) to illustrate the impact of these processes. The water rich in decay products, nutrients and dissolved inorganic carbon (DIC), exits the shelf not only from the Chukchi Sea, as has been shown earlier, but also from the East Siberian Sea. The excess of DIC found in the Canada Basin in a depth range of about 50–250 m amounts to 90±40 g C m^?2. If this excess is integrated over the whole Canadian Basin the excess equals 320±140×10¹² g C. The high DIC concentration layer also has low pH and consequently a low degree of calcium carbonate saturation, with minimum aragonite values of 60% saturation and calcite values just below saturation. The mean age of the waters in the top 300 m was calculated using the transit time distribution method. By applying a future exponential increase of atmospheric CO₂ the invasion of anthropogenic carbon into these waters will result in an under-saturated surface water with respect to aragonite by the year 2050, even without any freshening caused by melting sea ice or increased river discharge.     

Influence of cation distribution on the optical absorption spectra of Fe3+-bearing spinel s.s.–hercynite crystals: evidence for electron transitions in VIFe2+–VIFe3+ clusters

Flux-grown Fe³⁺-bearing spinel s.s.–hercynite solid-solution crystals, (Mg _1-y Fe²⁺ _y )Al₂O₄ (0 < y≤ 1), have been investigated by means of electron microprobe technique and Mössbauer and electronic spectroscopy. Obtained results show that different electronic processes cause intense optical absorption bands in the near-infrared spectral region. In addition to an electronic d–d transition in single-ion ^IVFe²⁺, observed at 5200 cm^?1, intense and broad bands at 9500 and 14 500 cm^?1 are assigned to exchange-coupled pair (ECP) and intervalence charge-transfer (IVCT) transitions in ^VI Fe ^{2+ VI} Fe³⁺clusters, respectively. The net linear extinction coefficients of these bands (α) were calibrated against Fe²⁺ and Fe³⁺ concentrations and site distributions previously defined by combined microchemical, Mössbauer, and XRD structural refinement data. The following expressions were obtained: where α is measured in cm^?1 and concentrations are expressed in mol?l^?1. The present results show that optical absorption spectroscopy may be used as a probe to obtain high spatial resolution (?～ 10 μm) information on Fe²⁺ ordering as well as on Fe³⁺ concentrations in minerals belonging to the spinel group.     

A revised dynamic model for suspended particulate matter (SPM) in coastal areas

This paper presents a general, process-based model for suspended particulate matter (SPM) in defined coastal areas (the ecosystem scale). The model is based on ordinary differential equations and the calculation time (dt) is 1 month to reflect seasonal variations. The model has been tested using data from 17 Baltic coastal areas of different character and shown to predict mean monthly SPM-concentrations in water and Secchi depth (a measure of water clarity) very well (generally within the uncertainty bands given by the empirical data). The model is based on processes regulating inflow, outflow and internal fluxes. The separation between the surface-water layer and the deep-water layer is not done in the traditional manner from water temperature data but from sedimentological criteria (from the wave base which regulates where wind/wave-induced resuspension occurs). The model calculates the primary production of SPM (within the coastal areas), resuspension, sedimentation, mixing, mineralization and retention of SPM. The SPM-model is simple to apply in practice since all driving variables may be readily accessed from maps or regular monitoring programs. The model has also been extensively tested by means of sensitivity and uncertainty tests and the most important factor regulating model predictions of SPM-concentrations in coastal water is generally the value used for the SPM-concentration in the sea outside the given coastal area. The obligatory driving variables include four morphometric parameters (coastal area, section area, mean and maximum depth), latitude (to predict surface water and deep water temperatures, stratification and mixing), salinity, chlorophyll and the Secchi depth or SPM-concentration in the sea outside the given coastal area. Many of the structures in the model are general and could potentially be used for coastal areas other than those included in this study, e.g., for open coasts, estuaries or areas influenced by tidal variations.     

A method for automatic history matching of a compositional reservoir simulator with multipoint flux approximation

A method for history matching of an in-house petroleum reservoir compositional simulator with multipoint flux approximation is presented. This method is used for the estimation of unknown reservoir parameters, such as permeability and porosity, based on production data and inverted seismic data. The limited-memory Broyden–Fletcher–Goldfarb–Shanno method is employed for minimization of the objective function, which represents the difference between simulated and observed data. In this work, we present the key features of the algorithm for calculations of the gradients of the objective function based on adjoint variables. The test example shows that the method is applicable to cases with anisotropic permeability fields, multipoint flux approximation, and arbitrary fluid compositions.     

Strain release in relation to focal depth

Summary The world-wide strain release in relation to focal depth has been calculated for all shocks with magnitude 7 and over for the interval 1918–1952. The strain exhibits a strong maximum in the uppermost 75 km of the earth; it decreases exponentially with depth between 75 and 400 km, with an unimportant minimum corresponding to the asthenosphere low-velocity layer and another minimum at 275 km; after a pronounced minimum between 400 and 475 km it increases again approximately exponentially between 475 and 650 km, after which it drops rapidly to zero. The shape of the strain-depth curve is interpreted in terms of the physical conditions and the intensity of strain accumulation. In particular, the increase between 475 and 650 km is ascribed to a combined effect of temperature and pressure variation with depth with related phase changes and possible changes in composition. The depth curve for the number of shocks is nearly parallel to the strain-depth curve, and the average strain per earthquake shows only an insignificant decrease with depth.

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Zusammenfassung Es wird die Tiefenabhängigkeit der Deformationsauslösung in allen Erdbeben mit Magnitude 7 und darüber, im Zeitraum 1918–1952 untersucht. Die Deformationsauslösung hat ein ausgesprochenes Maximum in den obersten 75 km. Sie nimmt im Tiefenbereich zwischen 75 und 400 km exponential mit der Tiefe ab, wobei sich ein Minimum, das der Schicht mit niedriger Wellengeschwindigkeit entspricht, schwach andeutet, und ein zweites Minimum bei 275 km liegt. Nach einem ausgeprägten Minimum zwischen 400 und 475 km Tiefe, steigt die Deformationsauslösung erneut, etwa exponential, im Tiefenbereich zwischen 475 und 650 km an, und nimmt danach schnell ab. Der Verlauf der Deformationsauslösung in Abhängigkeit von der Tiefe wird an Hand der physikalischen Verhältnisse im Erdkörper, sowie der Intensität der Deformationsaufspeicherung gedeutet. Insbesondere wird der Anstieg zwischen 475 und 650 km einer Änderung der Temperatur und des Druckes mit der Tiefe, bei Phasensprung und möglicher Änderung in der Zusammensetzung des Materials zugeschrieben. Die Tiefenabhängigkeit der Anzahl der Beben und der Deformationsauslösung verlaufen annähernd parallel; die mittlere Deformationsauslösung pro Erdbeben zeigt lediglich eine unbedeutende Abnahme mit der Tiefe.

     

Reassignment of the absorption spectra of purple yoderite

Polarized spectra E∥X, E∥Y, and E∥Z of purple yoderite, taken at 295 and 100 K, result in a revised interpretation for the mineral. Major bands at around 16,900 (X>Y?Z), 18,600 (X?Y), and 20,600 cm^?1 (X≈Z>Y) may be attributed to spin-allowed transitions of Mn³⁺ in trigonal bipyramids (A2 or A3). Minor features may be assigned to single ion Fe³⁺. However, charge transfer possibilities for bands at 18,600 and 25,500 cm^?1 in yoderite cannot be ruled out and are discussed. The extremely high intensity of Mn³⁺ spin-allowed bands (?, 216 to 1,900 [1·g-atom^?1·cm^?1]) is attributed to fivefold coordination of the A2 and A3 position and to the covalency of the Mn³⁺-O bonds.     

Ecological aspects of fin whale and humpback whale distribution during summer in the Norwegian Sea

The Norwegian Sea is a migration and feeding ground for fin whales (Balaenoptera physalus) and humpback whales (Megaptera novaeangliae) in summer. During the last decade, significant structural changes in the prey community, including northerly expansion and movement in the distribution of pelagic fish species, have been reported from this ecosystem. However, little information on whale feeding ecology exists in the Norwegian Sea and surrounding waters. A total of 59 fin whales and 48 humpback whales were sighted during 864 h of observation over an observation distance of about 8200 nmi (15,200 km) in the Norwegian Sea from 15 July to 6 August 2006 and 2007. The fin whale group size, as mean (±SD), varied between one and five individuals (2.1 ± 1.2 ind.) and humpback whale group size varied between one and six individuals (2.5 ± 1.7 ind.). Fin‐ and humpback whales were observed mainly in the northern part of the study area, and were only found correlated with the presence of macro‐zooplankton in cold Arctic water. Humpback whales were not correlated with the occurrence of adult Norwegian spring‐spawning herring (Clupea harengus) except for the northernmost areas. Despite changes in the whale prey communities in the Norwegian Sea, no apparent changes in fin‐ or humpback whale distribution pattern could be found in our study compared to their observed summer distribution 10–15 years ago.     

Fluid flow and methane occurrences in the Disko Bugt area offshore West Greenland: indications for gas hydrates?

The present study is the first to directly address the issue of gas hydrates offshore West Greenland, where numerous occurrences of shallow hydrocarbons have been documented in the vicinity of Disko Bugt (Bay). Furthermore, decomposing gas hydrate has been implied to explain seabed features in this climate-sensitive area. The study is based on archive data and new (2011, 2012) shallow seismic and sediment core data. Archive seismic records crossing an elongated depression (20×35 km large, 575 m deep) on the inner shelf west of Disko Bugt (Bay) show a bottom simulating reflector (BSR) within faulted Mesozoic strata, consistent with the occurrence of gas hydrates. Moreover, the more recently acquired shallow seismic data reveal gas/fluid-related features in the overlying sediments, and geochemical data point to methane migration from a deeper-lying petroleum system. By contrast, hydrocarbon signatures within faulted Mesozoic strata below the strait known as the Vaigat can be inferred on archive seismics, but no BSR was visible. New seismic data provide evidence of various gas/fluid-releasing features in the overlying sediments. Flares were detected by the echo-sounder in July 2012, and cores contained ikaite and showed gas-releasing cracks and bubbles, all pointing to ongoing methane seepage in the strait. Observed seabed mounds also sustain gas seepages. For areas where crystalline bedrock is covered only by Pleistocene–Holocene deposits, methane was found only in the Egedesminde Dyb (Trough). There was a strong increase in methane concentration with depth, but no free gas. This is likely due to the formation of gas hydrate and the limited thickness of the sediment infill. Seabed depressions off Ilulissat Isfjord (Icefjord) previously inferred to express ongoing gas release from decomposing gas hydrate show no evidence of gas seepage, and are more likely a result of neo-tectonism.     

An EELS study of near edge structures of the oxygen K-edge in spinels

Spectra of seven aluminate, ferrite and chromate spinels were collected at the oxygen K-edge in order to examine the effect of octahedral ion composition on the near edge structures and explore whether these may shed some light on previously reported major variations in the optical absorption coefficient (ε) for the spin-allowed d–d band transitions due to tetrahedrally coordinated Fe²⁺ in optical spectra of oxide spinels. Interpretation of the energy loss near edge structure (ELNES) spectra was aided using the multiple scattering code FEFF8.40. For the chromate samples spin polarised calculations were included. Gold’s iterative deconvolution method was utilized to improve on energy resolution, resulting in spectra equal in merit to those recorded by technically superior instruments. Results include absolute energy positions and interpretation of ELNES features in terms of transitions to available states. We conclude that the major causes of differences in the optical absorption coefficient mentioned above are hybridization between oxygen p- and octahedral metal orbitals. Our study does not support the idea presented by other authors that there exists a local antiferromagnetic ordering in MgCr₂O₄ at room temperature.