Climatic significance of seasonal trace element and stable isotope variations in a modern freshwater tufa

We present a continuous ∼14-yr-long (1985 to 1999) high-resolution record of trace element (Mg, Sr, Ba, U) and stable isotope (δ¹³C, δ¹⁸O) variations in a modern freshwater tufa from northwestern Queensland, Australia. By utilizing the temperature dependence of the δ¹⁸O signal, an accurate chronology was developed for the sampled profile, which allowed a comparison of the chemical records with hydrological and meteorological observations. As a consequence, it was possible to constrain the relevant geochemical processes relating climate variables, such as temperature and precipitation, to their chemical proxies in the tufa record. Temperatures calculated from the Mg concentrations of the tufa samples provide close approximations of average annual water temperature variations. Furthermore, we demonstrate that temporal changes in (Mg/Ca)_water can be estimated using an empirically derived equation relating (Mg/Ca)_water to the (Sr/Ba) ratio measured in the tufa samples. By means of this relationship, it is theoretically possible to determine the (Mg/Ca) ratio of paleowaters, and hence to derive reliable estimates of former water temperatures from the Mg concentrations of fossil tufas from the study area. Sympathetic variations in Sr, Ba, and δ¹³C along the sampled profile record changes in water chemistry, which are most probably caused by variable amounts of calcite precipitation within the vadose zone of the karst aquifer. This process is thought to be markedly subdued whenever the amount of wet-season precipitation exceeds a given threshold. Accordingly, distinct minima in Sr, Ba, and δ¹³C are interpreted to reflect years with above-average rainfall. The pronounced seasonal and annual variability of the U concentration along the profile is thought to primarily record changes in the U flux from the soil to the water table. We suggest that during intensive rain events U is transported to the phreatic zone by complexing organic colloids, giving rise to conspicuous U maxima in the tufa after above-average wet seasons. This study demonstrates the potential of freshwater tufas to provide valuable information on seasonal temperature and rainfall variations. If tufa deposits turn out to be reasonably resistant to secondary processes, combined investigation of speleothems and tufas from the same area could become a promising approach in future research. While speleothems offer continuous records of long-term paleoenvironmental changes, tufas could provide high-resolution time windows into selected periods of the past.     

Syria and Iraq —the geopathology of a relationship

The decision by Syria to support the anti-Iraq coalition during the Gulf War has to be understood within the wider political geographic and historical regional context. While the two states have many common characteristics, such as the respective power of the Ba'th Party in each country, mutual feelings of territorial injury in the demarcation of the states' territory and centrifugal forces threatening the continued integrity of the state, intense ideological and territorial disputes have resulted in bitter inter-state enmity. Disputes have arisen over Syrian closure of Iraqi oil pipelines, the allocation of water flowing from the Euphrates and Syrian support of Iran during the Iraq-Iran war. The collapse of Syria's superpower ally, the Soviet Union, resulted in Syria supporting the anti-Iraq international coalition during the 1991 Gulf War, in an attempt to regain wider international legitimacy.     

Melting of a Hydrous Mantle: I. Phase Relations of Natural Peridotite at High Pressures and Temperatures with Controlled Activities of Water, Carbon Dioxide, and Hydrogen

Four natural peridotite nodules ranging from chemically depletedto Fe-rich, alkaline and calcic (SiO₂=43?7–45?7 wt. percent, Al₂O3=1?6O–8?21 wt. per cent, CaO=0?70–8?12wt. per cent,alk=0?10–0?90 wt. per cent and Mg/(Mg+Fe²⁺)=0?94–0?85)have been investigated in the hypersolidus region from 800?to 1250?C with variable activities of H₂O, CO₂, and H₂. Thevapor-saturated peridotite solidi are 50–200?C below thosepreviously published. The temperature of the beginning of meltingof peridotite decreases markedly with decreasing Mg/(Mg+Fe)of the starting material at constant CaO/Al₂O₃. Conversely,lowering CaO/Al₂O₃ reduces the temperature at constant Mg/(Mg+Fe)of the starting material. Temperature differences between thesolidi up to 200?C are observed. All solidi display a temperatureminimum reflecting the appearance of garnet. This minimum shiftsto lower pressure with decreasing Mg/(Mg+Fe) of the startingmaterial. The temperature of the beginning of melting decreasesisobarically as approximately a linear function of the mol fractionof H₂O in the vapor (X_H2O). The data also show that some CO₂may dissolve in silicate melts formed by partial melting ofperidotite. Amphibole (pargasitic hornblende) is a hypersolidus mineralin all compositions, although its P/T stability field dependson bulk rock chemistry. The upper pressure stability of amphiboleis marked by the appearance of garnet. The vapor-saturated (H₂O) liquidus curve for one peridotiteis between 1250? and 1300?C between 10 and 30 kb. Olivine, spinel,and orthopyroxene are either liquidus phases or coexist immediatelybelow the temperature of the peridotite liquidus. The data suggest considerable mineralogical heterogeneity inthe oceanic upper mantle because the oceanic geotherm passesthrough the P/T band covering the appearance of garnet in variousperidotites. The variable depth to the low-velocity zone is explained byvariable a_H2O conditions in the upper mantle and possibly alsoby variations in the composition of the peridotite itself. It is suggested that komatiite in Precambrian terrane couldform by direct melting of hydrous peridotite. Such melting requiresabout 1250?C compared with 1600?C which is required for drymelting. The genesis of kimberlite can be related to partial meltingof peridotite under conditions of (). Such activities of H₂Oresult in melting at depths ranging between 125 and 175 km inthe mantle. This range is within the minimum depth generallyaccepted for the formation of kimberlite.     

Melting of a Hydrous Mantle: II. Geochemistry of Crystals and Liquids Formed by Anatexis of Mantle Peridotite at High Pressures and High Temperatures as a Function of Controlled Activities of Water, Hydrogen, and Carbon Dioxide

The system peridotite-H₂O-CO₂ serves as a simplified model forthe phase relations of mantle peridotite involving more thanone volatile component. Run products obtained in a study ofphase relations of four mantle peridotites in the presence ofH₂O- and (H₂O+CO₂)-bearing vapors and with controlled hydrogenfugacity (f_H2) at high pressures and temperatures have beensubjected to a detailed chemical investigation, principallyby the electron microprobe. Mg/(Mg+Fe) of all phases generally increases with increasingtemperature and with increasing Mg/(Mg+Fe) of the starting material.This ratio appears to decrease with increasing pressure forolivine, and for amphibole coexisting with garnet. DecreasingfH₂from that of IW buffer to that of MH buffer decreases Mg/(Mg+Fe)of the partial melt from approximately 0?85 to approximately0?50, whereas the Fo content of coexisting olivine increasesslightly less than 3 per cent and the Mg/(Mg+Fe) of clinopyroxeneincreases about 4 per cent. However, the variations in Fo contentof olivines are within those observed in olivines from naturalmantle peridotite. The chemistry of other silicate mineralsdoes not significantly reflect variations of fH₂. Consequently,the peridotite mineralogy and/or chemistry is not a good indicatorfor the fH₂ conditions during crystallization. All crystalline phases, except amphibole, and to some extentgarnet, show increasing Cr content with increasing temperatureand increasing Cr content of the starting material, resultingin a positive correlation with Mg/(Mg+Fe). Partial melts aredepleted in Cr₂O₃ relative to the crystalline phases. High Mg/(Mg+Fe)and Cr₂O₃ are thus expected in crystal residues after partialmelting. The absolute values depend on degree of melting andthe composition of the parent peridotite.     

Melting of a Hydrous Mantle: II. Geochemistry of Crystals and Liquids Formed by Anatexis of Mantle Peridotite at High Pressures and High Temperatures as a Function of Controlled Activities of Water, Hydrogen, and Carbon Dioxide

The system peridotite-H₂O–CO₂ serves as a simplified modelfor the phase relations of mantle peridotite involving morethan one volatile component. Run products obtained in a studyof phase relations of four mantle peridotites in the presenceof H₂O- and (H₂O+CO₂)- bearing vapors and with controlled hydrogenfugacity (f_H2) at high pressures and temperatures have beensubjected to a detailed chemical investigation, principallyby the electron microprobe. Mg/(Mg+Fe) of all phases generally increases with increasingtemperature and with increasing Mg/(Mg+Fe) of the starting material.This ratio appears to decrease with increasing pressure forolivine, and for amphibole coexisting with garnet. Decreasingf_H2 from that of IW buffer to that of MH buffer decreases Mg/(Mg+Fe)of the partial melt from approximately 0-85 to approximately0.50, whereas the Fo content of coexisting olivine increasesslightly less than 3 per cent and the Mg/(Mg+Fe) of clinopyroxeneincreases about 4 per cent. However, the variations in Fo contentof olivines are within those observed in olivines from naturalmantle peridotite. The chemistry of other silicate mineralsdoes not significantly reflect variations of f_H2. Consequently,the peridotite mineralogy and/or chemistry is not a good indicatorfor the f_H2 conditions during crystallization. All crystalline phases, except amphibole, and to some extentgarnet, show increasing Cr content with increasing temperatureand increasing Cr content of the starting material, resultingin a positive correlation with Mg/(Mg+Fe). Partial melts aredepleted in Cr₂O₃ relative to the crystalline phases. High Mg/Mg+Fe)and Cr₂O₃ are thus expected in crystal residues after partialmelting. The absolute values depend on degree of melting andthe composition of the parent peridotite. Liquids formed by anatexis of mantle peridotite are andesiticunder conditions of X_H2O^v > 0.6 to at least 25 kb total pressureand to more than 200?C above the peridotite solidus. This observationsupports numerous suggestions that andesite genesis in islandarcs may result from partial melting of underlying peridotitemantle. In contrast to basaltic rocks, the absence of amphibole(paragasitic hornblende) does not affect the silica-saturatednature of the liquids. Increasing K₂O content of the startingmaterial (up to 1 wt. per cent K₂O) results in increasing potassiumcontent of the amphibole (1 wt. per cent K₂O) as well as theappearance of phlogopite. The liquid under these conditionsis relatively K₂0-poor (less than 1 wt. per cent K₂O). Partial melts are olivine normative with X_H2O 0.5, and initialliquids contain normative ol and ne at X_H2O 0.4. The alkalinityof these liquids increases with decreasing X_H2O below valuesof 0.5. The (ol+opx)-normative liquids resemble oceanic basaltswhereas (ol+ne)-normative liquids resemble olivine nepheliniteand melilite basalt. Low aHlo and high a_Co2 conditions may bethose under which kimberlites and related rocks are formed inthe mantle.     

Holocene glacial variations in Sarek National Park, northern Sweden

Detailed mapping of well-preserved moraine systems fronting 17 small alpine glaciers in Sarek National Park in Swedish Lapland reveals two Holocene intervals of prolonged glacier expansion, each involving a complex of minor fluctuations. The younger interval, which corresponds to the Little Ice Age, experienced advances that culminated about A.D. 1916–1920, 1880–1890, 1850–1860, 1800–1810, 1780, 1700–1720, 1680, 1650, and 1590–1620. The older expansion interval, which probably centered around 2500 ¹⁴C yr B.P., experienced several minor fluctuations spread through about 600 years.
Lichen data collected on moraine systems in Sarek are internally consistent from glacier to glacier. Lichen measurements on surfaces of known age in Sarek and nearby Kebnekaise match closely, allowing moraine correlations between these areas. Several older expansion intervals are recorded in the Kebnekaise Mountains. Taken together, the two sequences suggest that a series of prolonged expansion intervals, each similar to the Little Ice Age, has characterized the Holocene in Lapland. Fluctuations of the Scandinavian Ice Sheet in Sweden suggest that this series of Little-Ice-Age events extends back into the late Weichsel in the form of the Younger Dryas and Oldest Dryas stadials.     

The relation between glacial ages and terrestrial magnetism

An attempt is made to show that the change of angular momentum of the earth, caused by glaciations, may compensate the slowing down effect from tidal friction forces and even reverse the polarity in the terrestrial magnetic field.     

SUMMER TEMPERATURE VARIABILITY IN CENTRAL SCANDINAVIA DURING THE LAST 3600 YEARS

ABSTRACT. A Scots pine ( Pinus sylvestris L.) tree-ring width chronology from Jämtland, in the central Scandinavian Mountains, built from living and sub-fossil wood, covering the period 1632 BC to AD 2002, with a minor gap during AD 887–907, is presented. This is the first multi-millennial tree-ring chronology from the central parts of Fennoscandia. Pine growth in this tree line environment is mainly limited by summer temperatures, and hence the record can be viewed as a temperature proxy. Using the regional curve standardization (RCS) technique, pine-growth variability on short and long time scales was retained and subsequently summer (June–August) temperatures were reconstructed yielding information on temperature variability during the last 3600 years. Several periods with anomalously warm or cold summers were found: 450–550 BC (warm), AD 300–400 (cold), AD 900–1000 (the Medieval Warm Period, warm) and AD 1550–1900 (Little Ice Age, cold). The coldest period was encountered in the fourth century AD and the warmest period 450 to 550 BC. However, the magnitude of these anomalies is uncertain since the replication of trees in the Jämtland record is low during those periods. The twentieth century warming does not stand out as an anomalous feature in the last 3600 years. Two multi-millennial tree-ring chronologies from Swedish and Finnish Lapland, which have previously been used as summer temperature proxies, agree well with the Jämtland record, indicating that the latter is a good proxy of local, but also regional, summer temperature variability.     

The Baltic Ice Lake in the southwestern Baltic: sequence-, chrono- and biostratigraphy

Jensen, J. B., Bennike, O., Witkowski, A., Lemke, W. & Kuijpers, A. 1997 (September): The Baltic Ice Lake in the southwestern Baltic: sequence-, chrono- and biostratigraphy. Boreas , Vol. 26, pp. 217–236. Oslo. ISSN 0300–9483.
This multidisciplinary study focuses on late-glacial deposits in the Mecklenburg Bay -Arkona Basin area. The sequence stratigraphical method has been used on shallow seismic and lithological data, in combination with biostratigraphical work and radiocarbon dating. Glacial-till deposits underlie sediments from two Baltic Ice Lake phases. Varved clay deposits from the initial phase cover the deepest parts of the basins. A prograding delta is observed at the western margin of the Arkona Basin, prograding from the Darss Sill area. The delta system is possibly related to a highstand dated at 12.8 ka. A maximum transgression level around 20 m below present sea level (b.s.l.) is inferred, followed by a drop in water level and formation of lowstand features. The final ice lake phase is characterized by a new transgression. The transgression maximum as observed in the Mecklenburg Bay is represented by transgressive and highstand deltaic deposits. These also indicate a maximum shore level of 20 m b.s.l. The deltaic sediments that contain macroscopic plant remains and diatoms have yielded Younger Dryas ages. Mapping of the late-glacial morphology of the Darss Sill area reveals a threshold at 23 to 24 m b.s.l. This means that the Baltic Ice Lake highstand phases inundated the Darss Sill, which implies that the westernmost extension of the Baltic Ice Lake reached as far as Kiel Bay. Forced regressive coastal deposits at the western margin of the Arkona Basin mark a lowstand level of around 40 m b.s.l. caused by the final drainage of the Baltic Ice Lake. The lowstand deposits predate lacustrine deposits from the Ancylus Lake, which date to approximately 9.6 ka BP.