The influence of underwater data transmission sounds on the displacement behaviour of captive harbour seals (Phoca vitulina)

To prevent grounding of ships and collisions between ships in shallow coastal waters, an underwater data collection and communication network (ACME) using underwater sounds to encode and transmit data is currently under development. Marine mammals might be affected by ACME sounds since they may use sound of a similar frequency (around 12 kHz) for communication, orientation, and prey location. If marine mammals tend to avoid the vicinity of the acoustic transmitters, they may be kept away from ecologically important areas by ACME sounds. One marine mammal species that may be affected in the North Sea is the harbour seal (Phoca vitulina). No information is available on the effects of ACME-like sounds on harbour seals, so this study was carried out as part of an environmental impact assessment program. Nine captive harbour seals were subjected to four sound types, three of which may be used in the underwater acoustic data communication network. The effect of each sound was judged by comparing the animals' location in a pool during test periods to that during baseline periods, during which no sound was produced. Each of the four sounds could be made into a deterrent by increasing its amplitude. The seals reacted by swimming away from the sound source. The sound pressure level (SPL) at the acoustic discomfort threshold was established for each of the four sounds. The acoustic discomfort threshold is defined as the boundary between the areas that the animals generally occupied during the transmission of the sounds and the areas that they generally did not enter during transmission. The SPLs at the acoustic discomfort thresholds were similar for each of the sounds (107 dB re 1 microPa). Based on this discomfort threshold SPL, discomfort zones at sea for several source levels (130-180 dB re 1 microPa) of the sounds were calculated, using a guideline sound propagation model for shallow water. The discomfort zone is defined as the area around a sound source that harbour seals are expected to avoid. The definition of the discomfort zone is based on behavioural discomfort, and does not necessarily coincide with the physical discomfort zone. Based on these results, source levels can be selected that have an acceptable effect on harbour seals in particular areas. The discomfort zone of a communication sound depends on the sound, the source level, and the propagation characteristics of the area in which the sound system is operational. The source level of the communication system should be adapted to each area (taking into account the width of a sea arm, the local sound propagation, and the importance of an area to the affected species). The discomfort zone should not coincide with ecologically important areas (for instance resting, breeding, suckling, and feeding areas), or routes between these areas.     

土壤中铁的氧化物和氢氧化物对砷的吸附

测定了加钠Ａｓｈａｎｔｉ矿区土壤中天然铁氧化物和氢氧化物的砷浓度，发现其变化范围为２￣３５ ６００ｍｇ／ｋｇ。在ｐＨ值中中性的 富氧化粘土的土壤中以及尾矿的表面氧化部分，砷在这两相中的浓度最高，达３５ ６００ｍｇ／ｋｇ。在高酸性土壤或处于还原条件的地方，缺氧化物和氢氧化物中砷的浓度较低（最高为４３３ｍｇ／ｋｇ）。还观测到富有机制土壤的矿物中这两个相的砷浓度更低。在所研究的样品中非晶质铁的氢氧化物中     

Are Models Too Simple? Arguments for Increased Parameterization

The idea that models should be as simple as possible is often accepted without question. However, too much simplification and parsimony may degrade a model's utility. Models are often constructed to make predictions; yet, they are commonly parameterized with a focus on calibration, regardless of whether (1) the calibration data can constrain simulated predictions or (2) the number and type of calibration parameters are commensurate with the hydraulic property details on which key predictions may depend. Parameterization estimated through the calibration process is commonly limited by the necessity that the number of calibration parameters be smaller than the number of observations. This limitation largely stems from historical restrictions in calibration and computing capability; we argue here that better methods and computing capabilities are now available and should become more widely used. To make this case, two approaches to model calibration are contrasted: (1) a traditional approach based on a small number of homogeneous parameter zones defined by the modeler a priori and (2) regularized inversion, which includes many more parameters than the traditional approach. We discuss some advantages of regularized inversion, focusing on the increased insight that can be gained from calibration data. We present these issues using reasoning that we believe has a common sense appeal to modelers; knowledge of mathematics is not required to follow our arguments. We present equations in an Appendix, however, to illustrate the fundamental differences between traditional model calibration and a regularized inversion approach.     

Stable isotope and trace element status of subsistence-hunted bowhead and beluga whales in Alaska and gray whales in Chukotka

Tissues of bowhead, beluga, and gray whales were analyzed for Ag, Cd, Cu, Se, Zn, THg and MeHg (belugas only). Delta15N and delta13C in muscle were used to estimate trophic position and feeding habitat, respectively. Trace element concentrations in tissues were significantly different among whale species. Hepatic Ag was higher in belugas than bowheads and gray whales. Gray whales had lower Cd concentrations in liver and kidney than bowhead and belugas and a sigmoid correlation of Cd with length was noted for all whales. Renal and hepatic Se and THg were higher in belugas than in baleen whales. The hepatic molar ratio of Se:THg exceeded 1:1 in all species and was negatively correlated to body length. Hepatic and renal Zn in subsistence-harvested gray whales was lower than concentrations for stranded whales. Se:THg molar ratios and tissue concentrations of Zn may show promise as potential indicators of immune status and animal health.     

The nature of scour development and scour protection at offshore windfarm foundations

Analysis and interpretation of monitoring data for the seabed bathymetry local to offshore windfarm foundations has shown how the scour develops in time and highlighted variations between sites with different seabed sediment characteristics, i.e. sands and clays. Results from European offshore windfarms have generated a unique dataset for comparison with previously published data. Where surficial sediment is underlain by a marine clay the scour (to date) has been limited, whilst those with unconstrained depths of sandy sediments show scour as deep as 1.38 times the monopile diameter. Scour protection has been installed at some sites for structural stability of the foundation or for cable protection. The flow interaction with the protection causes edge scour or secondary scour in the seabed around the protection. In some cases this scour is deeper than the unprotected case. The analysis has resulted in an improved evidence base for scour in the marine environment.     

离子色谱法测定臭氧化饮用水中的痕量溴酸盐

溴酸盐是饮用水臭氧化反应产生的副产品之一。美国环保机构认为溴酸盐的量应限制在低至μｇ／Ｌ水平。利用本试验开发的离子色谱技术可定量分析此含量范围的溴酸盐，甚至在高含量的阴离子（如氯化物和硫酸盐）共存的情况下也受干扰。