Petrology and Geochemistry of MORB from 25?E to 46?E along the Southwest Indian Ridge: Evidence for Contrasting Styles of Mantle Enrichment

The 1984 PROTEA expedition, leg 5, to the central SouthwestIndian Ridge recovered basaltic lavas from fracture zones andridge segments between 25?E and 48?E. In terms of petrographyand major element variations the samples are unremarkable forocean ridge basalts and range from aphyric to highly plagioclasephyric and from primitive (mg-number = 70) to moderately evolved(mg-number = 40) in composition. Multiply saturated (i.e., olivine,plagioclase, and clinopyroxene) basalts are common within thisregion. There is no systematic difference in compositional characteristicsbetween basalts dredged from fracture zone walls and those dredgedfrom ridge segments, and fractional crystallization has playedan important role in controlling the overall range in lava compositionin both tectonic environments. Incompatible element abundance ratios in the basalts are morenotable and distinguish between geochemically depleted (N-type)MORB with high Zr/Nb (1668) and Y/Nb (4?723) ratios and low(La/Sm)^m, ratios (0-?76–1?00), and geochemically enriched(E-type) MORB with low Zr/Nb (3?4–15?8) and Y/Nb (0?5–8?8)and high (La/Sm). ratios (1?07–3?8). N-type MORB appearsto be absent in the immediate vicinity of Marion Island, butoccurs further along the ridge to the northeast and southwest.Geochemically enriched MORB occurs at scattered localities alongthe ridge but is particularly abundant along the section ofthe ridge closest to the Marion hotspot. In detail, two distinct varieties of E-type MORB can be recognized.The one type has incompatible element and isotopic ratios similarto, although slightly less enriched than, those characteristicof the Marion hotspot (Zr/Nb=5?8–8?6; Y/Nb=0?5–0?8;Ba/Nb=5?1–9?0). The second type can be distinguished byhaving high Ba/Nb ratios (9–22), unlike any lavas directlyassociated with the Marion hotspot, but similar to those characteristicof DUPAL ocean island basalts (OIB). A single sample from thisgroup for which there are isotopic data indicates derivationfrom an isotopically anomalous source region. A model is proposed whereby the sub-oceanic mantle below thisportion of the southwest Indian Ocean has experienced at leasttwo distinct enrichment events. The one is associated with theupwelling of the Marion mantle plume (geochemically characterizedby having low Ba/Nb ratios and normal OIB isotopic ratios).The other is associated with upwelling from a DUPAL source (characterizedby having high Ba/Nb ratio and unusual isotopic ratios) whichhas been proposed to exist beneath this portion of the southwestIndian Ocean (Hart, 1984). On the basis of Ba/Nb and Nb/U ratios,recycled oceanic lithosphere is favoured as a source for theMarion hotspot, while recycled oceanic lithosphere plus ancientpelagic sediment appears to be the most likely source for theDUPAL anomaly and the DUPAL E-type MORB in this region.     

Properties and origin of a very fine-grained kaolinitic lacustrine deposit

The Rosebrook Member of the Miocene Bunyan Formation is a highly kaolinitic clay-rock of lacustrine origin. It is ultra-fine grained, plastic and of high cation exchange capacity (CEC) of 20–33 c mol(+)kg^?1 of clay. Fabrics observed optically and by transmission electron microscopy (TEM) indicate significant post-depositional consolidation and localized shear failure. Sedimentation and TEM analyses confirm its very fine grain size which is consistent with the relatively high CEC. Tertiary soils and weathering profiles in the catchment of Lake Bunyan developed under relatively moist and cool conditions. Some were gibbsitic with kaolinite and smectite clay minerals. Highly weathered soils (oxisols) on basalt under modern high rainfall environments in the region are dominated by gibbsite and kaolinite. These and other highly weathered soils in the region, formed on a range of parent rocks, have high proportions of very fine grained kaolinite in their subsoils. Such materials are likely to have been abundant in the catchment of Lake Bunyan during the Miocene and would have contributed very fine grained kaolinite directly to the lake by sedimentation. However, the unusually high proportion of kaolinite in the Rosebrook Member and its euhedral crystal form suggest that some of its features developed diagenetically.     

Intraplutonic Quench Zones in the Kap Edvard Holm Layered Gabbro Complex, East Greenland

The Kap Edvard Holm Layered Gabbro Complex is a large layeredgabbro intrusion (>300 km²) situated on the opposite sideof the Kangerdlugssuaq fjord from the Skaergaard Intrusion.It was emplaced in a continental margin ophiolite setting duringearly Tertiary rifting of the North Atlantic. Gabbroic cumulates, covering a total stratigraphic thicknessof >5 km, have a typical four-phase tholeiitic cumulus mineralogy:plagioclase, clinopyroxene, olivine, and Fe–Ti oxides.The cryptic variation is restricted (plagioclase An_81–51,olivine Fo_85–66, clinopyroxene Wo_43–41 En_46–37Fs_20–11) and there are several reversals in mineral chemistry.Crystallization took place in a low-pressure, continuously fractionatingmagma chamber system which was periodically replenished andtapped. Fine-grained (0•2–0•4 mm) equigranular, thin(0•5–3 m), laterally continuous basaltic zones occurwithin an {small tilde}1000 m thick layered sequence in theTaco Point area. Twelve such zones define the bases of individualmacrorhythmic units with an average thickness of {small tilde}80m. The fine-grained basaltic zones grade upwards, over a fewmetres, into medium-grained (>1 mm) poikilitic, olivine gabbrowith smallscale modal layering. Each fine-grained basaltic zoneis interpreted as an intraplutonic quench zone in which magmachilled against the underlying layered gabbros during influxalong the chamber floor. Supercooling by {small tilde}50C isbelieved to have caused nucleation of plagioclase, olivine,and clinopyroxene in the quench zone. The nucleation rate isbelieved to have been enhanced as the result of in situ crystallizationin a continuously flowing magma. The transition to the overlyingpoikilitic olivine gabbro reflects a decreasing degree of supercooling. Compositional variation in the Taco Point sequence is typicalfor an open magma chamber system: olivine (Fo_{77–68 5})and plagioclase cores (An_80–72) show a zig-zag crypticvariation pattern with no overall systematic trend. Olivinehas the most primitive compositions in the quench zones andmore evolved compositions in the olivine gabbro; plagioclasecores show the opposite trend. Although plagioclase cores arebelieved to retain their original compositions, olivines re-equilibratedby reaction with trapped liquid. Some plagioclase cores containrelatively sodic patches which retain quench compositions. Whole-rock compositions of nine different quench zones varyover a range from 10 to 18% MgO although the mg-number remainsconstant at {small tilde}0•78. The average composition(47•7% SiO₂, 13•3%MgO, 1•57% Na₂O+K₂O) is takenas a best estimate of the parental magma composition, and isequivalent to a high-magnesian olivine tholeiite. The compositionalvariation of the quench zones is believed to reflect burstsof nucleation and growth of olivine and plagioclase during quenching. Magma emplacement is believed to have taken place by separatetranquil influxes which flowed along the interface between alargely consolidated cumulus pile and the residual magma. Theresident magma was elevated with little or no mixing. At certainlevels in the layered sequence the magma drained back into thefeeder system; such a mechanism is referred to as a surge-typemagma chamber system.     

Glaciotectonic effects on a Middle-Wisconsin boreal fenland peat in Michigan, USA

A variety of glaciotectonic structueres are associated with a distinctive Middle- Wisconsin organic formation that is exposed at thirteen places along Michigan's Pine River. The carbonaceous material, with a ¹⁴C age of about 46,000 years BP, accumulated in an extensive, weakly geogenous, oligotrophic fen that was buried by sand before being deformed. Numerous faults and folds, the latter with observed amplitudes that may exceed 5 m, have a consistent sense of easterly structural vergence indicating glacial movement from the west. Gelogic relationships here and generally accepted regional chronology indicate that deformation was produced by Late Wisconsin ice that flowed from the Lake Michigan basin. This unequivocal marker bed provides detailed information on the topography, environment, and climate associated with an ice-free Middle-wisconsin landscape. Equally important and unprecedented for the area, it is an especially precise measure of multiple glaciotectonic effects upon an incompetent Pleistocene organic formation of considerable extent.     

Lake shoreline development, frost weathering and rock platform erosion in an alpine periglacial environment, Jotunheimen, southern Norway

Ice-dammed lake Boverbrevatnet existed for 75–125 years in the 'Little Ice Age'. After about A.D. 1826, glacier retreat led to a fall in lake level and to exposure of the former shoreline, which includes well-developed platforms cut in metamorphic bedrock. The rock platforms, up to 5.3 m wide and backed by cliffs up to 1.55 m high, are partially covered by large angular boulders which form pavements. Accurate levelling has permitted correlation of platform fragments, overflow cols and related features of the shoreline, such as benches eroded in moraines, ice-push ridges, a perched delta, vegetation trim-lines, lichen limits and a 'lichen-kill' zone. The evolution of the lake, the chronology of deglaciation and the period of formation of the rock platforms have been dated by lichenometry, supported by ¹⁴C dating, Schmidt hammer 'R'-values and historical data. The morphology of the rock platforms, together with estimates of their rate of erosion ranging from 1.4 to 7.1 cm/year, indicate the importance of frost shattering (frost riving, frost wedging or macrogelivation) at the lake margin under a periglacial climate, while the permanence of such platforms as landscape features suggests their use in the reconstruction of former periglacial environments. A semi-quantitative model is outlined for the development of rock platforms which emphasises deep penetration of the annual freeze-thaw cycle, the movement of unfrozen lake water towards the freezing plane, and the growth of segregation ice in fissures and cracks at the interface between lake ice and bedrock. Ice-push and ice-pull processes are involved primarily as transporting agents in the formation of boulder pavements and in the removal of debris from the platforms. Analogous processes may occur on polar coasts producing coastal rock platforms.     

链烷烃的热力学性质与分子拓扑指数的关系

定义了一种新的连接性指数^1Y=Σk1/m^2 n^2,研究了链烷烃的标准生成焓、标准熵、标准生成吉布斯自由能等三个热力学性质与碳原子个数N，^1Y之间的定量关系，相关系数为优，其计算值与实验值较为接近，对未参与回归的正癸烷的60个异构体的三个热力学性质进行了计算，计算值与实验值较一致。     

海洋真菌的化学研究

综述了从海洋真菌中分离出结构新奇、有特殊生物活性和有潜在实用意义的新化合物。     

Petrology of the Great Abitibi Dyke, Superior Province, Canada

The Great Abitibi Dyke (GAD) which can be traced northeast,for >> 700 km, across the Abitibi Belt in the southeasternSuperior Province of the Canadian Shield, is composed of olivinegabbro to monzodiorite, weakly saturated to undersaturated insilica. All rocks of the GAD can be derived by mainly plagioclase andolivine fractionation from a parental magma corresponding incomposition to chilled margin samples. Two units can be distinguished,a marginal unit (Unit 1) representing 0–50% crystallizationand a central unit (Unit 2), found over about half of the dykelength, representing 50–70% crystallization. Modelling,using Pearce elemental ratio analysis, quantifies the fractionationhistory and allows mass–balance calculations over thepresent exposure level of the dyke. The approximate balancebetween the amounts of cumulate and fractionated rocks suggeststhat Unit 1 differentiated essentially in situ as a closed system.In contrast, Unit 2 rocks were formed by loss of substantialplagioclase and olivine from the parental magma. This fractionatemust have either been lost to depth or left behind in an externalchamber. Unit 2 rocks show depletion in plagioclase and enrichmentin mafic minerals along strike towards the southwest (deeperexposure level?), a trend explained by density stratification.Regional variation in Unit 1 chemistry is interpreted in termsof lateral magma injection towards the northeast from the locusof Keweenawan rift volcanism. Feldspar, olivine, and augitecompositions are linearly correlated with equilibrium temperatureand extent of magma evolution. The parent magma had a trace element chemistry correspondingto a ‘within–plate’ setting and was probablyderived from an incompatible–element enriched mantle similarto the source for ocean island basalts (OIBs).