Reservoirs of atmospheric chlorine: Prospects for HOCl revisted

We have re-examined the prospects of HOCl as an inert reservoir for atmospheric chlorine in the light of new theoretical calculations and available experimental measurements of its photodissociation cross-sections. The theoretical calculations and most recent laboratory studies imply that the broad maxima 3200 Å observed in two other experimental spectra may not belong to HOCl. On the basis of this implication HOCl could have a long lifetime against photodissociation in the stratosphere, and could, thereby, become a reservoir for atmospheric chlorine comparable to ClONO₂ or even HCl. In this capacity HOCl could reduce the predicted ozone destruction due to any given level of total chlorine burden. We have also examined the difficulties in laboratory measurements of the HOCl absorption spectrum with particular emphasis on identifying the impurities which may be present in the experimental system. It appears that specialized new experiments are needed to clearly establish the nature and strength of HOCl absorption in the neighbourhood of 3200 Å. Some refinements in the theoretical calculations also seem desirable. In view of the difficulties involved in the laboratory determination of HOCl photodissociation cross-sections, it is suggested that a search for possible stratospheric HOCl by atmospheric spectroscopists would be worthwhile.     

On the dissociation of nitrogen by electron impact and by E.U.V. photo-absorption

The dissociation of N₂ by electron impact and by e.u.v. photo-absorption is studied, and it is shown that the forbidden predissociation of the numerous ¹Π_u and ¹Σ_u⁺ valence and Rydberg states of N₂ in the 11–24eV energy range is the dominant mechanism for N atom production. By measuring the absolute emission cross sections for the e.u.v. singlet bands of N₂ and by using the generalized oscillator strength data of Lassettre (1974), it has been possible to construct a detailed model of the total N₂ dissociation cross section which is in good agreement with the measurements of Winters (1966) and Niehaus (1967) and provides some insights into the maximum possible $\text{N(}{}^2\text{D)}$ yield from dissociative excitation. The total cross section for exciting N₂ e.u.v. radiation in the 800Å–1100Å wavelength range has been measured and found to have a value of 3.4 ×10^?17 cm² at 100 eV under optically thin conditions. Although this result implies that large fluxes of e.u.v. photons should be excited in auroral substorms and in the airglow, they are not observed, and we show that this development is a consequence of radiation entrapment and predissociation. The total cross section for dissociating N₂ by electron impact is given for optically thin and thick media. And some questions concerning the energy budget of a magnetospheric storm which are raised by these results, are discussed.     

Interhemispheric flow of thermal plasma in a closed magnetic flux tube at mid-latitudes under sunspot minimum conditions

The coupled H⁺ and O⁺ time-dependent continuity and momentum equations are solved within a region of the L = 3 magnetic flux tube lying between (and including) the F2-layers of conjugate hemispheres. The method of solution is an extended and modified version of the Murphy et al. (1976) method. The model is used to study the coupling between the F2-layers of conjugate hemispheres during magnetically quiet periods.The results of the calculations strongly indicate that the protonosphere acts as a reservoir, with variable H⁺ content, which prevents direct coupling between the F2-layers of conjugate hemispheres. However there is generally a significant interhemispheric flow of plasma. This flow is caused by conditions in the summer and winter topside ionospheres and it maintains continuity in the plasma concentration within the protonosphere. There are times when the direction of flow is from the winter hemisphere to the summer hemisphere. It is suggested that maintenance of the winter F2-layer at night is not assisted directly by the F2-layer of the conjugate summer hemisphere.It is shown that during the first few days of protonosphere replenishment after a magnetic storm there is an upflow of H⁺ in the topside ionosphere at all times in the summer hemisphere. There is also an upflow of H⁺ during the daytime in both hemispheres. A comparison with the results obtained when the interhemispheric H⁺ flux is held permanently at zero shows that both F2-layers are little affected by the interhemispheric H⁺ flux. Nevertheless both F2-layers are affected by the H⁺ tube content of the protonosphere. When the H⁺ flux at 1000 km in one hemisphere is much greater than the H⁺ flux at 1000 km in the conjugate hemisphere, there is a corresponding signature in the interhemispheric H⁺ flux.The results suggest that there is insufficient time between magnetic storms for complete replenishment of the protonosphere to occur.     

Solar micro-bursts at 22.2 GHz and their relationship to events observed at lower frequencies

Observations of McMath region 10433 at 22 GHz using a telescope with a 4 beam during July 1974 revealed the existence events or microbursts with intensities below the sensitivity limit of normal solar patrol instruments. Many of these events were simply the high frequency counterpart of more intense bursts observed at lower frequencies. This note considers the small number of events which suggest that the gyro-synchrotron mechanism alone is incapable of explaining the observations and indicates that a thermal mechanism is needed to explain the high frequency event.On leave of absence from Department of Physics, University of Surrey, Guildford, U.K.     

The spectral reflectivity of select areas on Europa

The July 12, 1973, occultation of Europa by Io was observed in 30 wavelength channels in the spectral region λλ3200-11, 000 Å with the 200-inch Hale telescope and a multichannel spectrometer. The data are presented in absolute units above the Earth's atmosphere. The data are analyzed to obtain the spectral reflectivity of seven localized areas on the disk of Europa centered on 324°W longitude. The equatorial material is confirmed to be darker than the eastward-skewed bright north polar cap and a hint is evident that the darker material as well may be somewhat redder than the cap material.     

Solar-interplanetary modeling: 3-D solar wind solutions in prescribed non-radial magnetic field geometries

A model is presented which describes the 3-dimensional non-radial solar wind expansion between the Sun and the Earth in a specified magnetic field configuration subject to synoptically observed plasma properties at the coronal base. In this paper, the field is taken to be potential in the inner corona based upon the Mt. Wilson magnetograph observations and radial beyond a certain chosen surface. For plasma boundary conditions at the Sun, we use deconvoluted density profiles obtained from synopticK-coronameter brightness observations. The temperature is taken to be 2 × 10⁶ K at the base of closed field lines and 1.6 x 10⁶K at the base of open field lines. For a sample calculation, we employ data taken during the period of the 12 November 1966 eclipse. Although qualitative agreement with observations at 1 AU is obtained, important discrepancies emerge which are not apparent from spherically symmetric models or those models which do not incorporate actual observations in the lower corona. These discrepancies appear to be due to two primary difficulties - the rapid geometric divergence of the open field lines in the inner corona as well as the breakdown in the validity of the Spitzer heat conduction formula even closer to the Sun than predicted by radial flow models. These two effects combine to produce conductively dominated solutions and lower velocities, densities, and field strengths at the Earth than those observed. The traditional difficulty in solar wind theory in that unrealistically small densities must be assumed at the coronal base in order to obtain observed densities at 1 AU is more than compensated for here by the rapid divergence of field lines in the inner corona. For these base conditions, the value ofβ(ratio of gas pressure to magnetic pressure) is shown to be significantly greater than one over most of the lower corona - suggesting that, for the coronal boundary conditions used here, the use of a potential or force-free magnetic field configuration may not be justified. The calculations of this paper point to the directions where future research on solar-interplanetary modelling should receive priority:

1. better models for the coronal magnetic field structure
2. improved understanding of the thermal conductivity relevant for the solar wind plasma.

     

Geopotential harmonics of order 15 and odd degree from analysis of resonant orbits

We have analysed the variations of inclination in 13 satellite orbits as they pass slowly, under the action of air drag, through 15th-order resonance with the geopotential, when successive equatorial crossings are 24° apart and the ground track repeats after 15 rev. The size and form of the change in inclination are determined mainly by the values of the geopotential harmonics of 15th order and odd degree, $\text{C}\text{?}{}_{\mathrm{l,15}}$ and $\text{S}\text{?}{}_{\mathrm{l,15}}$ (with l = 15, 17, 19, …) in the usual notation. Our analysis gives values of these coefficients up to l = 33 as follows:

     

179.

Manganoan garnet rocks associated with the Broken Hill Pb–Zn–Ag orebody, Australia     

I. R. Plimer 《Mineralogy and Petrology》2006,88(3-4):443-478

Summary The Palaeoproterozoic Broken Hill Pb–Zn–Ag stratiform orebody is intimately associated with manganoan garnet-bearing rocks. On stratigraphic and chemical grounds it is argued that garnet-rich metasediments below, equivalent to and above massive sulphide were hydrothermal precipitates. Other manganoan garnet rocks formed during pre-metamorphic hydrothermal alteration, syn-metamorphic dehydration and reaction of manganese with prograde pelitic rocks, reaction between cataclastic manganese-bearing sulphide rocks injected along axial planes, shears and faults and pelitic wall rocks and reaction between dolerite dykes and sulphide rocks.     

180.

Tide model errors and GRACE gravimetry: towards a more realistic assessment   总被引：10，自引：1，他引：10  

R. D. Ray  S. B. Luthcke 《Geophysical Journal International》2006,167(3):1055-1059

     

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l	109C?l,15	109S?l,15
15	?23.5 ± 0.8	?7.7 ± 0.8
17	6.3 ± 1.5	5.6 ± 1.5
19	?25.1 ± 2.5	?7.3 ± 2.3
21	27.8 ± 3.6	?0.7 ± 3.4
23	17.1 ± 4.1	13.9 ± 4.8
25	?1.1 ± 3.0	8.5 ± 4.2
27	10.0 ± 3.3	6.7 ± 2.7
29	?9.4 ± 3.5	0.1 ± 4.7
31	10.1 ± 5.4	3.8 ± 5.6
33	1.1 ± 5.7	3.1 ± 5.8

Manganoan garnet rocks associated with the Broken Hill Pb–Zn–Ag orebody, Australia

Summary The Palaeoproterozoic Broken Hill Pb–Zn–Ag stratiform orebody is intimately associated with manganoan garnet-bearing rocks. On stratigraphic and chemical grounds it is argued that garnet-rich metasediments below, equivalent to and above massive sulphide were hydrothermal precipitates. Other manganoan garnet rocks formed during pre-metamorphic hydrothermal alteration, syn-metamorphic dehydration and reaction of manganese with prograde pelitic rocks, reaction between cataclastic manganese-bearing sulphide rocks injected along axial planes, shears and faults and pelitic wall rocks and reaction between dolerite dykes and sulphide rocks.