Ionic Liquid Modified Resin for the Adsorptive Removal of Dibutyl Phthalate: Equilibrium,Kinetic, and Thermodynamic Studies

This study evaluated the adsorptive properties of dibutyl phthalate (DBP) on room temperature ionic liquid (RTIL) modified XAD‐4 resin. The modified RTIL‐XAD 4 sorbent was characterized by FTIR. Effect of varying experimental conditions such as pH, contact time, temperature, shaking speed, concentrations, and interfering species were investigated by batch adsorption experiments. Adsorption was found to be most favorable at pH 6 within 30 min. Experimental data were evaluated in terms of kinetic, equilibrium, and thermodynamic modeling. Kinetics of the sorption was found to follow pseudo second order rate equation whereas Freundlich and D–R isotherms were the most suitable models to explain sorption phenomenon. Thermodynamically sorption was endothermic, irreversible, and spontaneous in nature.     

The CO2 absorption method as an alternative to benzene synthesis method forC dating

A fast and economical routine sample preparation system is described for direct counting of¹⁴C for hydrological purposes. The method employs commercially available CO₂ absorbers, such as Carbosorb, and liquid scintillation counters. The maximum error involved individual analyses is about ±4pmc (1 δ) on the Beckman counter and about ±2 pmc on the Quantulus counter with a resulting detection limit of 21,000–29,000 a for the Beckman LS7500 and 1220 Quantulus, respectively for a counting time of 1000 min. To avoid physical weighing procedures, an indirect method is presented to determine the grams of C absorbed in the counting solution by using the H-# quench monitor technique available in the Beckman liquid scintillation counters. On one sample preparation system at least five samples can be prepared per normal working day. The applicability of the CO₂-absorption method is discussed with reference to two field sites and with reference to comparisons with data obtained on the same samples measured with conventional techniques.     

EMEC instability based on kappa-Maxwellian distributed trapped electrons in auroral plasma

In space plasmas, particle distributions are often observed having high energy tails and are well fitted by kappa distribution function. However, in auroral region electrons are expected to be accelerated mainly along the magnetic field lines and one may expect Maxwellian behaviour in perpendicular direction. Therefore, in the present study propagation characteristics of electromagnetic electron cyclotron (EMEC) waves is studied by employing kappa-Maxwellian distribution function for energetic trapped electrons in auroral region. Real frequency and the growth rate expressions have been solved numerically for kappa-Maxwellian plasma and then analyzed by considering the effect of different plasma parameters for wide range of auroral altitudes. The numerical results obtained show that growth rate increases with the increase in ratio \({\omega_{pe}} / {\varOmega_{e}}\), plasma beta, temperature anisotropy \({T_{\bot}} / {T_{\parallel}}\) and trapped electron drift speed but decreases when superthermal electron population increases.     

Assessment of seismic hazard of roller compacted concrete dam site in Gilgit-Baltistan of northern Pakistan

The proposed site of the Diamer Bhasha Dam in northern Pakistan is situated in an active tectonic zone with intensive seismicity, which makes it necessary for seismic hazard analysis(SHA). Deterministic and probabilistic approaches have been used for SHA of the dam site. The Main Mantle Thrust(MMT), Main Karakaram Thrust(MKT), Raikot-Sassi Fault(RKSF) and Kohistan Fault(KF) have been considered as major seismic sources, all of which can create maximum ground shaking with maximum potential earthquake(MPE). Deterministically estimated MPE for magnitudes of 7.8, 7.7, 7.6, and 7.1 can be produced from MMT, MKT, RKSF and KF, respectively. The corresponding peak ground accelerations(PGA) of 0.07, 0.11, 0.13 and 0.05 g can also be generated from these earthquakes, respectively. The deterministic analysis predicts a so-called floating earthquake as a MPE of magnitude = 7.1 as close as 10 km away from the site. The corresponding PGA was computed as 0.38 g for a maximum design earthquake at the project site. However, the probabilistic analysis revealed that the PGA with 50% probability of exceedance in 100 years is 0.18 g. Thus, this PGA value related to the operational basis earthquake(OBE) is suggested for the design of this project with shear wave velocity(V_(s30)) equal to 760 m/s under dense soil and soft rock conditions.     

Parallel Proton Heating in Solar Wind Using Generalized (r, q) Distribution Function

Kinetic theory is used to calculate the power dissipated by obliquely propagating Alfvén waves to heat the solar wind protons, using the Generalized (r, q) distribution function. The evolution of power dissipation of protons with increasing heliocentric distance is subsequently determined. Comparison between theoretical and observational results with data shows good agreement, especially for the slow solar wind streams. Previous results where a Maxwellian distribution function was used to calculate the power dissipated did not match well with observations.     

Factors determining the economic value of groundwater

Increasing groundwater extraction threatens aquifer sustainability for future generations. Making the best use of limited groundwater resources requires knowledge of its alternative extractive and non-extractive values, as well as the cost of extraction and the hydrological interlinkages between alternative uses. Groundwater value is driven by a number of factors including its supply and demand and institutional and policy factors. These factors and how they affect value of groundwater are described. Also described are the various components relevant to the economic valuation of groundwater and there is discussion on the potential difficulties in their practical estimation. It is argued that groundwater management is essential when there are large potential spatial and temporal externalities related to groundwater pumping. Maintaining non-extractive and option values is likely to require trade-offs with current extractive uses. Well-informed management will be required to allocate groundwater efficiently between different users such as agriculture, industry and the environment, while also balancing the needs of current and future generations.     

From regulated access to transferable harvesting rights: Policy insights from New Zealand

The dramatic decline in yields from many of the world's fisheries has prompted an assessment of traditional regulatory approaches to management. Transferable harvesting rights provide an alternative institutional structure in fisheries management. This paper has two aims. First, it links outcomes in the fishery with institutional structure. Second, the paper identifies several important institutional variables if a transition is to be made to from command-and-control management to tradeable rights. In particular, the transition phase must deal with the expectations that attach to the status quo structure of rights in the fishery. The paper's empirical content is drawn from New Zealand's experience with the introduction of transferable harvesting rights.     

Estimation of climatic transition in Riyadh (Saudi Arabia) in global warming perspectives

The present exercise is a study to enquire into the recent climatic transition, if any in Riyadh, Saudi Arabia. Conventional climatic indicators such as rainfall distribution, temperature regime, relative humidity, sunshine duration, wind velocity and evaporation characteristics were examined over a period of twenty six years of available meteorological data. The analyses showed a remarkable mutual resemblance and unidirectional trend in all the temperature parameters like absolute monthly maximum, absolute monthly minimum, mean monthly maximum, mean monthly minimum and mean monthly temperatures and the mean monthly maximum and mean monthly minimum relative humidities. Similarly, the trends in sunshine duration, wind velocity and pan evaporation were also supportingly in accordance to the general trends of climatic transition. The analysis based on a smaller period climatic data shows a good deal of agreement with the trends of studies on global warming projections made by simulated models on the basis of CO₂ concentration changes in the atmosphere.     

云南个旧卡房铜矿床地质地球化学特征及其成因探讨

云南个旧是世界上最大的锡多金属矿田,卡房铜矿是个旧矿田主要的产铜区。卡房铜矿主要的矿床类型有两类:玄武岩层中或玄武岩与大理岩层间的似层状矿体以及花岗岩与围岩接触带矿体。围岩蚀变主要有夕卡岩化、阳起石化和金云母化。电子探针分析结果显示,卡房铜矿夕卡岩中的辉石主要为透辉石-钙铁辉石系列,石榴子石端元组分以钙铝榴石-钙铁榴石为主。流体包裹体及氢、氧同位素研究显示,从主成矿期到后成矿期,流体温度有显著降低(从260～360℃到160～280℃),而流体盐度则基本保持不变(从1.74%～12.51%到1.74%～11.93%)。氢、氧同位素组成表明,早期成矿流体主要以岩浆水为主,而晚期成矿流体可能在上升过程中与地层中的大气降水相混合。硫同位素分析结果表明,卡房铜矿似层状矿体中硫化物的硫来源于三叠系玄武岩,而燕山期花岗岩和三叠纪玄武岩共同为卡房铜矿接触带矿体提供了成矿所需的大部分的硫。铅同位素分析结果显示,卡房铜矿似层状矿体的成矿物质主要来源于三叠系玄武岩,而接触带矿体的铅可能主要来源于燕山期花岗岩。     

Novel Calix[4]arene‐based Amberlite XAD‐4 Modified Resin for As(III) Removal from Water

The present article describes As(III) sorption behavior of novel calix[4]arene appended TS‐4 resin. The sorption ability of TS‐4 resin has been evaluated at wide range of pH, i.e., pH 2–14. The maximum As(III) sorption efficiency (95%) was achieved at pH 2, which shows that the TS‐4 resin possesses greater affinity for As(III) at this pH. Column sorption mechanism was evaluated through various operating parameters, i.e., change in concentration, flow rate, bed heights, and pH. The experimental data were also tested against bed depth service time model and from the results; it has been observed that the data is in close agreement with the theoretically calculated values. Thus, from the data it has been revealed that TS‐4 resin has maximum column efficiency of 0.13 mmol g^?1. Application of TS‐4 to real samples indicates a slight decrease (2–3%) in extraction efficiency of TS‐4 because of high concentration of total dissolved salts. Thermal behavior was tested by differential scanning calorimetry and it has been observed that TS‐4 resin is stable up to 160°C. TS‐4 resin was found to be regenerable and best regeneration was achieved by using 4% solution of NaOH. It can be deduced from the study that the resin will find its applicability in small as well as industrial scale water purification plants.