A modified EK method with an I<Superscript>−</Superscript>/I<Subscript>2</Subscript> lixiviant assisted and approaching cathodes to remedy mercury contaminated field soils

Wanshan mercury mine is the largest cinnabar deposit in Guizhou, China. Few effective methods had been achieved to remedy Hg heavily contaminated field soils. In this paper, a modified EK method with approaching cathodes (AC-EK) and an I⁻/I₂ lixiviant was described to remedy mercury-contaminated field soils near Wanshan mercury mine. Paddy Soil I and Paddy Soil II were sampled and contained 576.73 ± 45.50 and 491.35 ± 4.73 mg/kg Hg, respectively. Although they contained 6.9 and 9.4% organic matter respectively, more than 92 and 89% Hg were removed by AC-EK within 5 days. Removal ratio increased by 0.21 and 0.68 times using EK process with ACs over that with one single cathode (SC-EK). AC-EK method saved nearly 26.4–28.1% electric power as compared to SC-EK method. As an I⁻/I₂ lixiviant solution was used to solubilize HgS(HgO) during EK process, the bonding of Hg to organic functional S groups should be less important than the binding to inner sites of organic matter in soil. The relationship between EK remediation effect and soil organic matter content was fitted to a linear model. It turned out that when soil OM increased by 1.0%, EK removal ratio (%) of Hg would decrease by 2.63%.     

Re–Os Isotopic Age of the Hongqiling Cu–Ni Sulfide Deposit in Jilin Province,NE China and its Geological Significance

The Hongqiling Cu–Ni sulfide deposit in central Jilin Province is located in the eastern part of the Central Asian Orogenic Belt. Rhenium and osmium isotopes in sulfide minerals from the deposit are used to determine the timing of mineralization and the source of osmium, and ore metals. Sulfide ore samples have osmium and rhenium concentrations of 0.28–1.07 ppb and 2.39–13.17 ppb, respectively. Ten analyses yield an isochron age of 223 ± 9 Ma, indicating that the Cu–Ni sulfide deposit in the area formed in the Triassic. The initial ¹⁸⁷Os/¹⁸⁸Os ratio is around 0.295 ± 0.019 (MSWD = 1.14) and the δ³⁴S values of sulfide ores vary from ?1.50 to +3.00‰. These data indicate that the mineralizing materials were derived mainly from a mantle with some quantities of crustal components introduced into the rock‐forming and ore‐forming systems during mineralization and magmatic emplacement.     

大冶李德贵冶炼遗址矿冶遗物分析

采用X射线荧光光谱、X射线衍射等测试手段,对大冶李德贵冶炼遗址矿冶遗物进行了物理测试、成分分析和物相分析。物理测试结果表明,遗址炼渣的熔融温度高于1280℃;成分分析结果表明,李德贵炼渣中铜含量很低,远低于炼铜渣的铜含量;而其铁含量很高,与欧洲早期铁器时代和罗马时代的块炼铁渣相近;物相分析结果表明,李德贵炼渣的主要物相与炼铜渣没有区别,但炼铜渣中发现一些铜氧化矿和硫化矿。结合对其他冶炼遗物的分析,可以初步判断该冶炼遗址是一处炼铁遗址。工作台面上发现的炼渣与铁矿石的混合物,表明古人很可能已将炼渣回收利用,与铁矿石原料一起回炉冶炼。     

河东煤田杨家湾勘查区洁净煤等级划分

河东煤田杨家湾勘查区钻孔煤层煤质分析显示,太原组煤层以中硫、中灰、中高挥发分、中高发热量的气煤和1/3焦煤为主,山西组煤层主要为特低硫、中高灰、高挥发分、中发热量的气煤。利用工业分析、元素分析及工艺性能数据分析了各指标的变化规律,在此基础上,根据煤炭资源潜力评价洁净煤等级6级划分方案,对本区煤的洁净等级进行了划分:山西组原煤洁净等级为Ⅲ-Ⅳ级,以Ⅳ级为主,属中等-较好洁净煤,太原组原煤洁净等级为Ⅳ级,属于中等洁净煤;山西组和太原组浮煤洁净等级为Ⅱ-Ⅲ级,均属于较好-好洁净煤。     

宝鸡剖面S5古土壤磁化率变化机制

运用岩石磁学和地球化学相结合的方法对宝鸡剖面S5和S3古土壤的磁性特征进行了详细对比分析,结果表明S5古土壤层 Rb/Sr 比值较高,S5古土壤形成期气候温暖湿润,成壤程度比S3时期强。S5层亚铁磁性矿物含量低于S3层,反铁磁性矿物主要为针铁矿; 而S3层的反铁磁性矿物主要为赤铁矿。S5层土体表面及土壤空隙中可见大量黑褐色的铁锰胶膜分布,由于沉积后土壤长时期处于偏干或偏湿的氧化、还原交替环境中,细粒的磁铁矿和/或磁赤铁矿、赤铁矿溶解转化成褐铁矿、针铁矿等弱磁性矿物,主要转化成在局域湿润环境下能够稳定存在的针铁矿,这种磁性矿物的转化可能导致了成壤强的S5古土壤超顺磁亚铁磁性矿物含量的减少和磁化率的降低。     

浙江建德岭后铜矿磁黄铁矿Re Os年代学 特征及成矿意义

浙江建德岭后铜矿床位于扬子板块与华夏板块之间的钦杭结合带的北东段,矿化主要发育于中石炭统黄龙组下段灰质白云岩中及花岗闪长斑岩侵入体与其接触带上。挑选块状铜矿体中的磁黄铁矿进行Re Os同位素年代学研究,获得等时线年龄为121±12Ma和122.5±8.7Ma。结合前人的研究成果及本次的年代学研究,认为岭后铜矿是在古生代海底喷流成矿作用的基础上受到中生代岩浆作用的改造、富集而形成的,是海底热水沉积—热液叠加改造型矿床。中生代的热液叠加成矿作用受到华南地区岩石圈伸展、减薄作用的影响,是中国东部燕山期第三次大规模成矿作用的结果。本次研究也为在浙江西部地区寻找与中生代岩浆活动有关的成矿作用提供了证据。     

河北省“长城式”金矿矿床地质特征简介

＂长城式＂金矿是产于中元古界长城系碳酸盐岩地层中的一种新类型金矿。含矿带长约50 km,宽4~5km,由多个矿区,几十个矿体构成,一般单个矿体规模较小,矿体厚度变化系数26%,品位变化系数74%,矿体产出受地层和构造控制明显。     

吉林省农安县徐家排陶粒页岩矿矿床特征

吉林省农安县徐家排陶粒页岩矿层长,厚度大,资源丰富,经济潜力巨大。矿石以泥质结构为主,并且主要呈块状构造,矿石主要由石英、长石及粘土矿物组成。陶粒页岩矿主要存在于下白垩统青山口组中、下部地层中,浅灰绿色含粉砂泥岩及青灰色泥岩为该类岩石即为直接找矿标志。     

Prediction on landslide displacement using a new combination model: a case study of Qinglong landslide in China

Prediction on landslide displacement plays an important role in landslide early warning. Many models have been proposed for this purpose. However, the accuracy of the prediction results by these models often varies under different conditions. Rational evaluation and comprehensive consideration of these results still remain a scientific challenge. A new comprehensive combination model is proposed to predict the landslides displacement. The elementary displacement prediction is made by the support vector machine model, the exponential smoothing model, and the gray model (GM)(1,1). The results of the models are comprehensively evaluated by combining the results and introducing the accuracy matrix. The optimal weight in the evaluation work is obtained. A rational prediction result can be attained based on the so-called combination model. The proposed method has been tested by the application of Qinglong landslides in Guizhou Province, China. The comparison between the prediction results and in situ measurement shows that the prediction precision of the proposed model is satisfactory. The root-mean-square error (RMSE) of the combination model can be reduced to 1.4316 (monitoring site JCK2), 1.2623 (monitoring site JCK4), 2.3758 (monitoring site JCK6), 2.2704 (monitoring site JCK8), 1.4247 (monitoring site JCK11), and 0.9449 (monitoring site JCK12), which is much lower than the RMSE of the individual models.

     

硬土-软岩的厘定及其判别分类

结合我国大量工程实践和作者的研究积累,证明在中国岩石和土两种工程类型之间,确实存在着难以"一刀切"的过渡类型(即硬土-软岩),并根据其地质成因和分布规律进行了初步分类.