草簇状石墨烯片限域Pd纳米粒子及其催化应用(英文)

通过氨基离子液体改性石墨烯,并将其固载于堇青石表面,作为负载型Pd催化剂的载体.所制备的Pd催化剂经加氢老化后,表面石墨烯呈草簇状结构,将Pd纳米粒子限域于片层内,有效防止了Pd的流失和团聚.在重要的工业反应对羧基苯甲醛(4-CBA)加氢中,此结构催化剂与传统的钯碳催化剂相比,表现出很好的稳定性     

近1800年以来内蒙古达里湖浮游植物群落演变及驱动因素

湖泊是地质历史上区域生态环境演变的重要载体,其沉积物中包含了丰富的环境演变信息。达里湖是典型的草原内陆封闭型湖泊,位于东亚夏季风的北部边缘,地理位置关键。本研究基于在达里湖采集的约238 cm沉积物岩芯 (GDL-1),通过²¹⁰Pb和¹³⁷Cs (岩芯上部20 cm)、AMS¹⁴C测年,以及沉积物样品中甾醇等生物标志物含量分析,重建了近1800年以来达里湖硅藻、蓝藻等典型藻类含量的演化历史,并结合总氮(TN)、总磷(TP)、盐度(Sr/Ba)和温度(T)等环境代用指标,分析藻类群落的主要影响因素。结果显示达里湖典型藻类总量平均为2.03 ng/g(最高6.69 ng/g,最小0.53 ng/g),其中蓝藻占比平均为60%,绿藻和硅藻占比平均为20%;环境因子对硅藻、蓝藻和典型藻类生物量的解释率分别为47.7%、55.20%和48.10%,T、TN和Sr/Ba是影响浮游植物群落的主要影响因素;硅藻占比与温度呈显著负相关,小冰期硅藻占比最高,中世纪暖期占比最低;在达里湖的高盐环境下,湖泊营养盐浓度对藻类的影响受到限制,成为藻类等生长的限制因素;Sr/Ba小于0.9时,硅藻含量与典型藻类总量随着Sr/Ba值的升高而增加,Sr/Ba大于0.9时,典型藻类总量与Sr/Ba值呈负相关关系,而硅藻则表现出对盐度具有一定的耐受性;整体上,近1800年以来,区域或全球性气候事件通过改变达里湖盐度、营养元素浓度和温度来影响典型藻类群落结构。在暖期阶段,蒸发作用增强等导致的湖泊盐度增加成为达里湖典型藻类群落结构演变的主要影响因素;在冷期,营养元素浓度和温度的降低成为湖泊水体浮游植物生物量的主要影响因素。     

Fermat猜想的两个等价命题

对每个奇素数p,我们提出了关于p的两个命题:(I)不存在正整数m和n,使代数曲线f(y)=y~3-(2m+1)y-2n的三个零点同时为p方有理整数;(I)不存在正整数m,使不定方程x~2+3y~2=4(2m+1)具有三组正整数解x_i,y_i(i=1,2,3),满足x_1=x_2+x_3,x_1~2+x_2~2+x_3~2=6(2m+1)。本文旨在证明(I)及(I)都与关于素数p的Fermat猜想等价。     

Delineation of different phytoplankton communities in the East China Sea mackerel and carangoid fishing ground

Delineation of phytoplankton communities in this study was based on: 1) cluster analysis by Preston's Equation (1962) and 2) analysis of the number of individuals. Results obtained by these two methods were very similar to that obtained in a previous study (Fig. 1, Gu and Guo, 1982) based on analysis of the number of planktonic species of different ecological nature. Among these three methods, that based on cluster analysis (by which some subcommunities could be recognized) proved to be the best. Contribution No. 1841 from the Institute of Oceanology, Academia Sinica.     

Sensitivity assessment of strontium isotope as indicator of polluted groundwater for hydraulic fracturing flowback fluids produced in the Dameigou Shale of Qaidam Basin

Hydrogeochemical processes that would occur in polluted groundwater and aquifer system, may reduce the sensitivity of Sr isotope being the indicator of hydraulic fracturing flowback fluids(HFFF) in groundwater. In this paper, the Dameigou shale gas field in the northern Qaidam Basin was taken as the study area, where the hydrogeochemical processes affecting Sr isotope was analysed. Then, the model for Sr isotope in HFFF-polluted groundwater was constructed to assess the sensitivity of Sr isotope as HFFF indicator. The results show that the dissolution can release little Sr to polluted groundwater and cannot affect the εSr(the deviation of the 87 Sr/86 Sr ratio) of polluted groundwater. In the meantime, cation exchange can considerably affect Sr composition in the polluted groundwater. The Sr with low εSr is constantly released to groundwater from the solid phase of aquifer media by cation exchange with pollution of Quaternary groundwater by the HFFF and it accounts for 4.6% and 11.0% of Sr in polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater, respectively. However, the Sr from cation exchange has limited impact on Sr isotope in polluted groundwater. Addition of Sr from cation exchange would only cause a 0.2% and 1.2% decrease in εSr of the polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater, respectively. These results demonstrate that hydrogeochemical processes have little effect on the sensitivity of Sr isotope being the HFFF indicator in groundwater of the study area. For the scenario of groundwater pollution by HFFF, when the HFFF accounts for 5%(in volume percentage) of the polluted groundwater, the HFFF can result in detectable shifts of εSr(ΔεSr=0.86) in natural groundwater. Therefore, after consideration of hydrogeochemical processes occurred in aquifer with input of the HFFF, Sr isotope is still a sensitive indicator of the Quaternary groundwater pollution by the HFFF produced in the Dameigou shale of Qaidam Basin.     

Lateral extrusion along the Altyn Tagh Fault,Qilian Shan (NE Tibet): insight from a 3D crustal budget

The lithospheric strike‐slip Altyn Tagh Fault has accommodated hundreds of kilometres of displacement between the Qaidam and Tarim blocks since its Eocene reactivation. However, the way the deformation is accommodated in the Qilian Shan and further east remains uncertain. Based on 360 km of north‐eastward migration of the relatively rigid Qaidam block along the Altyn Tagh Fault and 3D isovolumetric balancing of the crustal deformation within the Altyn Tagh Fault–Qilian Shan system, we demonstrate that 250 ± 28 km (43.8–49.4%) of N20E directed crustal shortening and an additional ~250–370 km of eastward motion of the Qilian Shan crust must be accounted for by strike‐slip faulting in the Qilian Shan and crustal thickening in the Qinling area, as well as by extension in the adjoining North China block graben systems.     

地磁干扰噪声的实验观测

为探查1988年3月前后在北京地磁台附近出现的较明显的地磁干扰噪声,我们在苏家坨—卧龙岗一带布设了8个测点,开展了专门的地磁干扰噪声实验观测。结果表明,该地磁干扰噪声主要是来自香山一带的电磁干扰,其次是北京市的地铁干扰。此地磁干扰噪声出现于每天06~h—23~h(北京时),其主要频谱成分在短周期(T=2—4 m)部分。另外本文的观测研究方法对于监测地磁台站(测点)的环境状况,改正受污染的地磁资料等方面具有实际应用价值。     

强震作用下陡倾顺层岩质边坡失稳机制研究

安县茶坪乡冷浸沟陡倾顺层岩质边坡在\     

公路路面热效应对环境气温的影响分析

为定量研究公路对气温观测的影响,本文使用2014年1—5月在陕西省开展的两组公路观测试验的逐分钟温度、风向、风速等气象资料,对比分析了合阳县国道和渭蒲高速公路在不同季节、不同天空状况以及不同背景风速条件下对周围环境气温观测的影响程度和影响距离。试验结果表明:公路对周围的环境温度有一定的增温影响,合阳国道对环境温度的增温影响至75m,增温效应达0.25~0.4℃。高速公路的增温影响至125m,增温效应达0.2~0.4℃。冬季,两条公路白天增温效应较夜间明显,春季,高速公路夜间增温更明显。晴天、多云天气比阴天、降雨天气增温程度大。公路对气温的增温影响存在风速阈值,当风速小于对应阈值时,增温效应明显。公路上来往车流量对气温有一定的叠加增温影响,合阳国道白天车流量150~350辆,叠加增温效应0.05~0.1℃,蒲渭高速白天车流量2000~3500辆,叠加增温效应0.16℃。