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41.
Helmut Kerndorff Stephan Kühn Thomas Minden Dagmar Orlikowski Thomas Struppe 《Environmental Geology》2008,55(2):291-301
The aim of this research project is to identify, characterize and quantify natural attenuation (NA) processes in groundwater
affected by emissions of abandoned waste disposal sites in Berlin-Kladow/Gatow, Germany. It is part of the funding priority
called KORA established by the Federal Ministry for Education and Research (BMBF) to explore the extent to which NA can be
used for remedial purposes for varied forms of soil and groundwater contamination. Information on the emission behaviour of
individual parameters is generated on the basis of hydrogeochemical comparison of 20 years old and new data. Using groundwater-modelling
and CFC-analysis, information on the transport and retention of pollutants in groundwater is compiled. The microbial colonization
of contaminated aquifers is characterized by molecular biological methods [polymerase chain reaction (PCR) and denaturing
gradient gel electrophoresis (DGGE)] to differentiate between contaminated and not contaminated zones. 相似文献
42.
Here we report iron (Fe) isotopic data of three pure Fe solution standards (IRMM-014, GSB Fe, and NIST 3126a) and five widely used geological reference materials (RMs) from the United States Geological Survey and Geological Survey of Japan obtained on a Neptune Plus multi-collector–inductively coupled plasma–mass spectrometer (MC-ICP-MS) in our laboratory over the past 3 years. The instrumental mass bias was corrected by three independent methods: sample-standard bracketing (SSB), Ni doping?+?SSB, and 57Fe–58Fe double spike?+?SSB. Measurements reveal that both the Ni doping and double spike methods helped calibrate short-term fluctuations in mass bias. Collectively, almost all measurements of RMs yielded δ56Fe within?±?0.05 of recommended values, provided that each sample was measured four times on MC-ICP-MS. For the first time, new recommended values for NIST SRM3126a are reported (δ56Fe?=?0.363?±?0.006, 2SE, 95% CI; and δ57Fe?=?0.534?±?0.010, 2SE). 相似文献
43.
Calcite was synthesized by four methods, and the luminescence decay-time was measured for nine samples before and after heating
hydrothermally in the temperature range 200–400°C. Decay-time data were collected between room temperature and approximately
15 K. The decay time at room temperature is approximately 50 ms, with little difference between a given calcite before and
after hydrothermal treatment. The decay time at 15 K is always greater than at room temperature as the effect of thermal quenching
diminishes. Differences in decay time before and after heating are more apparent at low temperature owing to this reduction
in thermal quenching. The decay time decreased significantly in two samples, and an increase in decay time was observed in
the remaining seven samples following heating. Among the latter group, the change in decay time was insignificant in three
samples. The results are compared with previous data in which it was shown that the effect of heating is to increase the intensity
of luminescence. 相似文献
44.
水溶液中草酸漂白高岭土细尾矿的研究 总被引:5,自引:0,他引:5
研究了用草酸在不同溶液中漂白高土细尾矿的反应动力学。考察了PH值,温度、浸出液初始浓度等因素对反应的影响。结果表明,PH值的降低、反应温度和浸出液浓度的提高有利于高岭土中氧化铁的浸出,该反应是草酸根与铁的摩尔比为3:1的络合反应,在草酸溶液中铁的溶出符合一级反应动力学。 相似文献
45.
Citizens as sensors: the world of volunteered geography 总被引:62,自引:0,他引:62
Michael F. Goodchild 《GeoJournal》2007,69(4):211-221
In recent months there has been an explosion of interest in using the Web to create, assemble, and disseminate geographic information provided voluntarily by individuals. Sites such as Wikimapia and OpenStreetMap are empowering citizens to create a global patchwork of geographic information, while Google Earth and other virtual globes are encouraging volunteers to develop interesting applications using their own data. I review this phenomenon, and examine associated issues: what drives people to do this, how accurate are the results, will they threaten individual privacy, and how can they augment more conventional sources? I compare this new phenomenon to more traditional citizen science and the role of the amateur in geographic observation. 相似文献
46.
湘黔地区震旦纪菌藻硅质岩特征及形成机理探讨 总被引:7,自引:0,他引:7
湘黔地区震旦纪菌藻硅质岩化学成分纯净,硅质矿物含量95%以上,几乎都为泥晶—微晶石英,石英结晶度平均为6.35。岩石具菌藻生物结构,以纹层状构造为主。其中丰富的菌藻生物化石,按形态可划分为三种类型。岩石属原生沉积成因,二氧化硅的聚沉一方面通过菌藻有机体的硅化作用,另一方面是菌藻生物化学作用引起微环境变化而导致二氧化硅的聚沉。 相似文献
47.
François Farges 《Physics and Chemistry of Minerals》2009,36(8):463-481
Cr K-edge XANES spectra were obtained for a variety of Cr-bearing model compounds containing Cr(II), Cr(III), Cr(IV), Cr(V) and Cr(VI), in which the Cr-site symmetry is D4h, Oh and Td. The centroid position of the pre-edge feature is a better indicator of the Cr valence than the edge position. In Cr-rich oxides, higher-energy transitions must be excluded in order to refine a robust valence for Cr. The pre-edge for chromates is not unique and varies as a function of the CrO4 2? moiety distortion, which is often related to Cr-polymerization (monochromate vs. dichromate). Both the analogy with the Mn K-pre-edge information and ab initio FEFF calculations of the pre-edge feature for Cr(III) and Cr(VI) confirm the experimental trends. This methodology is applied to the Cr K-edge pre-edge feature collected in gems (emerald, spinel and ruby), the layered minerals fuchsite and kämmererite, two Cr-bearing aqueous solutions and a set of sodo-calcic silicate glasses used for bottling sparkling white wine. In emerald and fuchsite, the Cr-site is differently distorted than its ruby or spinel counterpart. In a Cr(III)-bearing aqueous solution and sodo-calcic glass, no evidence for Cr(III) with Td and C3v symmetry is detected. However, minor amounts of chromate moieties (most likely monomeric) are detected in a glass synthesized in air. Preliminary spectra for the wine bottle glass suggest that only trace amounts of chromates might possibly be present in these glasses. 相似文献
48.
Intrusion and its implication for subsidence: A case from the Baiyun Sag, on the northern margin of the South China Sea 总被引:12,自引:0,他引:12
We develop a series of simple numerical models to explain the anomalous subsidence and deposition phenomena on the northern continental margin of the South China Sea, in particular in the Baiyun Sag. The results suggest that a short-period high rate deposition of around 17 Ma is related to a rapid subsidence event, which may be due to episodic emplacement of a dense intrusion. Necking and gravity models indicate that in the basement of the Baiyun Sag, there is a dense zone that is 100–200 kg/m3 more dense than the surrounding country rock. Considering its high magnetic intensity and regional igneous activity, the dense zone is thought to be related to a phase of basalt intrusion that may have taken place around 17 Ma. Thermal and subsidence models indicate that a hot denser intrusion can cause significant subsidence immediately after the intrusion. The subsidence rate then slows down with cooling, thus becoming consistent with the observed subsidence curves at around 17 Ma. The results also indicate that the lithospheric strength under the Baiyun Sag is negligible, and that the high-velocity layer in the lowermost crust may be not an original part of the pre-rift crust. Instead, it is thought to be underplated intrusion emplaced at around 30 Ma when the continental margin broke up. 相似文献
49.
Despite a recent increase in the number of vulnerability analyses there has been relatively little discussion of vulnerability
assessment of social–environment system, especially when they face multiple hazards. In this study, we developed an applicable
and convenient method to assess vulnerability of social–environment system at a regional scale. Vulnerability is quantified
by measuring three critical elements (i.e. hazards, sensitivity, and resilience) through some key variables. The results showed
that vulnerability is high in Miaofeng Mountain in Mengtougou District, the hills of Pinggu County and the riparian zones
of the lower courses of the Beiyun and Yongding Rivers; but low in the city of Beijing and the southwestern part of the Fangshan
District. Areas of very high, high, medium, and low-vulnerability account for 6.19, 25.48, 33.06, and 35.27% of the total
area, respectively. The degree of vulnerability decreases in a northwest direction in mountainous areas and declines from
watercourses to riparian zones along a lateral direction in the plain. Some adaptive strategies are also proposed. 相似文献
50.
Mark Anglin Harris 《Environmental Geology》2009,56(8):1517-1522
Several years (7) after incidental lithification by added gypsum, the effect of crushing and phyto-organics on some physical
properties of red mud wastes (RMW) was examined under laboratory conditions. It was hypothesized that mechanically breaking
up the hardened masses would increase their permeability. However, on the contrary, crushing these rock-hard masses into <2-mm
particles did not increase permeability. A phyto-organic treatment on the other hand greatly improved permeability of the
crushed entities such that infiltration rates increased from 0 to 10 cm/h. After 24 weeks of incubation, the structure of
the newly formed phyto-organically treated gypsum-hardened RMW aggregates was also substantially improved over that of the
controls, as a >3-fold increase in resistance to disintegration during wet sieving was exhibited by the phyto-organically
treated samples. The increase in water infiltration by combining crushing with phyto-organic applications was ascribed to
a decrease in particle dispersion, creating more stable clay clusters, which in turn stabilized channels and pores. Conversely,
it was concluded that the singular crushing of gypsum-hardened bauxite waste in the waste dumps is potentially wasteful and
ineffective. 相似文献